Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative

The new homochiral 1D metal–organic coordination polymer [Cu2(EDPB)•H2O]n was synthesized starting from the original 3,3′-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H4EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [Cu2(EDPB)•H2O]n system shows catalytic activity and enantioselectivity in a Henry reaction of p-nitrobenzaldehyde with nitromethane

Facile Synthesis of Micro-Mesoporous Copper Phyllosilicate Supported on a Commercial Carrier and Its Application for Catalytic Hydrogenation of Nitro-Group in Trinitrobenzene

Development of novel Cu-based catalysts has become one of the frontiers in the catalytic production of platform chemicals and in environment protection. However, the known methods of their synthesis are too complicated and result in materials that cannot be used instantly as commercial catalysts. In the present work, a novel material has been synthesized by the facile method of deposition–precipitation using thermal hydrolysis of urea. The conditions for Cu phyllosilicate formation have been revealed (molar ratio urea:copper = 10, 92 °C, 8–11 h). The prepared Cu-based materials were studied by TG–DTA, SEM, TEM, XRD, N2 adsorption and TPR-H2 methods, and it was found that the material involves nanoparticles of micro-mesoporous copper phyllosilicate phase with a chrysocolla-like structure inside the pores of a commercial meso-macroporous silica carrier. The chrysocolla-like phase is first shown to be catalytically active in the selective reduction of the nitro-group in trinitrobenzene to an amino-group with molecular hydrogen. Complete conversion of trinitrobenzene with a high yield of amines has been achieved in short time under relatively mild conditions (170 °C, 1.3 MPa) of nitroarene hydrogenation over a copper catalyst

Modifying HKUST-1 Crystals for Selective Ethane Adsorption Using Ionic Liquids as Synthesis Media

Novel adsorbents for methane and ethane based on HKUST-1 metal-organic framework were synthesized by microwave (MW) assisted technique using ionic liquids (ILs) as synthesis media. It was found that the MW synthesis time remarkably impacts both the product yield and the physico-chemical characteristics of the produced HKUST-1 material. The crystalline phase purity, crystallite size/dispersion and textural properties of the synthesized HKUST-1 matrices determine their performance in methane and ethane adsorption. Therefore, the HKUST-1 material produced in MW fields for 3 min only shows the highest phase purity and the largest surface area (BET) and porosity, along with a rather small crystallite size (below ~300 nm), demonstrating high methane and ethane adsorption capacity in the pressure range 1–30 atm

Modifying HKUST-1 Crystals for Selective Ethane Adsorption Using Ionic Liquids as Synthesis Media

Novel adsorbents for methane and ethane based on HKUST-1 metal-organic framework were synthesized by microwave (MW) assisted technique using ionic liquids (ILs) as synthesis media. It was found that the MW synthesis time remarkably impacts both the product yield and the physico-chemical characteristics of the produced HKUST-1 material. The crystalline phase purity, crystallite size/dispersion and textural properties of the synthesized HKUST-1 matrices determine their performance in methane and ethane adsorption. Therefore, the HKUST-1 material produced in MW fields for 3 min only shows the highest phase purity and the largest surface area (BET) and porosity, along with a rather small crystallite size (below ~300 nm), demonstrating high methane and ethane adsorption capacity in the pressure range 1–30 atm

Novel Fe−Pd/SiO2\mathrm{Fe-Pd/SiO_{2}} catalytic materials for degradation of Chlorinated organic compounds in water

Novel reactive materials for catalytic degradation of chlorinated organic compounds in water at ambient conditions have been prepared on the basis of silica-supported Pd-Fe nanoparticles. Nanoscale Fe-Pd particles were synthesized inside porous silica supports using (NH4)3[Fe(C2O4)3] and [Pd(NH3)4]Cl2 or Pd acetate as reaction precursors. According to temperature programmed reduction (TPR) studies, Pd introduction decreased the reduction temperature of the supported Fen+ species and nearly complete reduction with H2 was observed at 400 °C. The successful surface loading with Pd was confirmed by X-ray photoelectron spectroscopy (XPS) analysis. Characterization of the samples by X-ray diffraction (XRD) and X-ray absorption near-edge structure + extended X-ray absorption fine structure (XANES + EXAFS) verified the presence of highly dispersed Pd0, Pdx Fe1–x and Fe0 phases. Reduction of the supported precursors in hydrogen resulted in materials that were highly active in perchloroethene (PCE) degradation and 2-chlorobiphenyl (2-ClBP) dechlorination. It was found that highly dispersed amorphous Fe-Pd bimetallic nanoparticles on silica support showed superior catalytic activity against PCE dechlorination in comparison to the free-standing Fe-Pd nanoparticles. For the samples with the same Fe content, the conversion of chlorinated organics as well as the stability increased with the Pd loading, e.g., the most effective degradation of PCEs and 2-ClBP was achieved at a Pd loading of 2.3–3.2 wt. %