153 research outputs found
3-Phenyl-1-[2-(3-phenylisoquinolin-1-yl)diselanyl]isoquinoline
The complete molecule of the title compound, C30H20N2Se2, is generated by a crystallographic inversion centre at the mid-point of the Se—Se bond. The dihedral angle between the isoquinoline-1-selenol group and the phenyl ring is 14.92 (2)°. The herringbone-like packing of the structure is supported by intermolecular π–π stacking interactions with a shortest perpendicular distance between isoquinoline groups of 3.514 Å; the slippage between these ring systems is 0.972 Å, and the distance between the centroids of the six-membered carbon rings is 3.645 (3) Å
1-(4-Chlorophenyl)-2-[(3-phenylisoquinolin-1-yl)sulfanyl]ethanone
The title compound, C23H16ClNOS, exhibits dihedral angles of 11.73 (1) and 66.07 (1)°, respectively, between the mean plane of the isoquinoline system and the attached phenyl ring, and between the isoquinoline system and the chlorophenyl ring. The dihedral angle between the phenyl and chlorophenyl rings is 54.66 (1)°
2-Chloro-8-methoxyquinoline-3-carbaldehyde
In the title compound, C11H8ClNO2, the quinoline fused-ring system is almost planar (r.m.s. deviation = 0.020 Å). The formyl group is slightly bent out of the quinoline plane [deviation of the O atom = 0.371 (2) Å]
Ethyl 6-chloro-2-methyl-4-phenylquinoline-3-carboxylate
In the title compound, C19H16ClNO2, the quinoline ring system is planar (r.m.s. deviation = 0.008 Å). The phenyl group and the –CO2 fragment of the ester unit form dihedral angles of 60.0 (1) and 60.5 (1)°, respectively, with the quinoline ring system
1,3,6-Trimethylpyrano[4,3-b]pyrrol-4(1H)-one
All the non-H atoms of the title compound, C10H11NO2, are almost coplanar [maximum deviation = 0.040 (3) Å]. The crystal structure is stabilized by C—H⋯O hydrogen bonds
2-Chloroquinoline-3-carbaldehyde
The quinolinyl fused ring system of the title compound, C10H6ClNO, is planar (r.m.s. deviation = 0.018 Å); the formyl group is slightly bent out of the plane of the fused ring system [C—C—C—O torsion angle = 8.2 (3)°]
1-(3,5-Dimethyl-1H-pyrazol-1-yl)-3-phenylisoquinoline
The molecular conformation of the title compound, C20H17N3, is stabilized by an intramolecular C—H⋯N interaction. The crystal structure shows intermolecular C—H⋯π interactions. The dihedral angle between the isoquinoline unit and the phenyl ring is 11.42 (1)° whereas the isoquinoline unit and the pendent dimethyl pryrazole unit form a dihedral angle of 50.1 (4)°. Furthermore, the angle between the mean plane of the phenyl ring and the dimethyl pyrazole unit is 47.3 (6)°
2-[2-(Cyclohexylcarbonyl)phenyl]-1-phenylethanone
The title diketone, C21H22O2, features a phenylene ring having benzoylmethyl and cyclohexanoyl substituents ortho to each other. The cyclohexyl ring adopts a chair conformation with the ketonic group occupying an equatorial position; the four-atom –C(O)–C ketonic unit is twisted out of the plane of the phenylene ring by 34.9 (1)°
2-Chloro-7,8-dimethylquinoline-3-carbaldehyde
All the non-H atoms of the title compound, C12H10ClNO, lie on a crystallographic mirror plane orientated perpendicular to the crystallographic b axis
5-Phenyl-3-(2-thienyl)-1,2,4-triazolo[3,4-a]isoquinoline
In the title molecule, C20H13N3S, the triazoloisoquinoline ring system is approximately planar, with an r.m.s. deviation of 0.045 Å and a maximum deviation of 0.090 (2) Å from the mean plane for the triazole ring C atom which is bonded to the thiophene ring. The phenyl ring is twisted by 52.0 (1)° with respect to the mean plane of the triazoloisoquinoline ring system. The thiophene ring is rotationally disordered by approximately 180° over two sites, the ratio of refined occupancies being 0.73 (1):0.27 (1)
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