729 research outputs found
Surface electronic properties of undoped InAlN alloys
The variation in surface electronic properties of undoped c-plane InxAl1−xN alloys has been investigated across the composition range using a combination of high-resolution x-ray photoemission spectroscopy and single-field Hall effect measurements. For the In-rich alloys, electron accumulation layers, accompanied by a downward band bending, are present at the surface, with a decrease to approximately flatband conditions with increasing Al composition. However, for the Al-rich alloys, the undoped samples were found to be insulating with approximate midgap pinning of the surface Fermi level observed
Influence of oxygen ordering kinetics on Raman and optical response in YBa_2Cu_3O_{6.4}
Kinetics of the optical and Raman response in YBa_2Cu_3O_{6.4} were studied
during room temperature annealing following heat treatment. The superconducting
T_c, dc resistivity, and low-energy optical conductivity recover slowly,
implying a long relaxation time for the carrier density. Short relaxation times
are observed for the B_{1g} Raman scattering -- magnetic, continuum, and phonon
-- and the charge transfer band. Monte Carlo simulations suggest that these two
relaxation rates are related to two length scales corresponding to local oxygen
ordering (fast) and long chain and twin formation (slow).Comment: REVTeX, 3 pages + 4 PostScript (compressed) figure
Layering transitions for adsorbing polymers in poor solvents
An infinite hierarchy of layering transitions exists for model polymers in
solution under poor solvent or low temperatures and near an attractive surface.
A flat histogram stochastic growth algorithm known as FlatPERM has been used on
a self- and surface interacting self-avoiding walk model for lengths up to 256.
The associated phases exist as stable equilibria for large though not infinite
length polymers and break the conjectured Surface Attached Globule phase into a
series of phases where a polymer exists in specified layer close to a surface.
We provide a scaling theory for these phases and the first-order transitions
between them.Comment: 4 pages, 4 figure
Force-induced desorption of a linear polymer chain adsorbed on an attractive surface
We consider a model of self-avoiding walk on a lattice with on-site repulsion
and an attraction for every vertex of the walk visited on the surface to study
force-induced desorption of a linear polymer chain adsorbed on an attractive
surface and use the exact enumeration technique for analyzing how the critical
force for desorption depends on the temperature. The curve
gives the boundary separating the adsorbed phase from the desorbed phase. Our
results show that in two dimensions where surface is a line the force
increases monotonically as temperature is lowered and becomes almost constant
at very low temperatures. In case of three-dimensions we, however, find
re-entrance, i. e. goes through a maximum as temperature is lowered.
The behaviour of the polymer chain at different values of temperature and force
is examined by calculating the probability distribution of the height from the
surface of the vertex at which external force is applied.Comment: Preprint 15 pages with 8figures and two tables. The file table-2d.ps
and table-3d.ps lists C_N(Ns,h) for given N with all possible Ns and h in two
and three dimension
X-ray photoemission spectroscopy determination of the InN/yttria stabilized cubic-zirconia valence band offset
The valence band offset of wurtzite InN(0001)/yttria stabilized cubic-zirconia (YSZ)(111) heterojunctions is determined by x-ray photoemission spectroscopy to be 1.19±0.17 eV giving a conduction band offset of 3.06±0.20 eV. Consequently, a type-I heterojunction forms between InN and YSZ in the straddling arrangement. The low lattice mismatch and high band offsets suggest potential for use of YSZ as a gate dielectric in high-frequency InN-based electronic devices
Magnetotransport Mechanisms in Strongly Underdoped YBa_2Cu_3O_x Single Crystals
We report magnetoresistivity measurements on strongly underdoped YBa_2Cu_3O_x
(x=6.25, 6.36) single crystals in applied magnetic fields H || c-axis. We
identify two different contributions to both in-plane and out-of-plane
magnetoresistivities. The first contribution has the same sign as the
temperature coefficient of the resistivity \partial ln(\rho_i)/\partial T
(i={c,ab}). This contribution reflects the incoherent nature of the
out-of-plane transport. The second contribution is positive, quadratic in
field, with an onset temperature that correlates to the antiferromagnetic
ordering.Comment: 4 pages, 3 figure
Valence band offset of the ZnO/AlN heterojunction determined by X-ray photoemission spectroscopy
The valence band offset of ZnO/AlN heterojunctions is determined by high resolution x-ray photoemission spectroscopy. The valence band of ZnO is found to be 0.43±0.17 eV below that of AlN. Together with the resulting conduction band offset of 3.29±0.20 eV, this indicates that a type-II (staggered) band line up exists at the ZnO/AlN heterojunction. Using the III-nitride band offsets and the transitivity rule, the valence band offsets for ZnO/GaN and ZnO/InN heterojunctions are derived as 1.37 and 1.95 eV, respectively, significantly higher than the previously determined values
Pulling absorbing and collapsing polymers from a surface
A self-interacting polymer with one end attached to a sticky surface has been
studied by means of a flat-histogram stochastic growth algorithm known as
FlatPERM. We examined the four-dimensional parameter space of the number of
monomers up to 91, self-attraction, surface attraction and force applied to an
end of the polymer. Using this powerful algorithm the \emph{complete} parameter
space of interactions and force has been considered. Recently it has been
conjectured that a hierarchy of states appears at low temperature/poor solvent
conditions where a polymer exists in a finite number of layers close to a
surface. We find re-entrant behaviour from a stretched phase into these
layering phases when an appropriate force is applied to the polymer. We also
find that, contrary to what may be expected, the polymer desorbs from the
surface when a sufficiently strong critical force is applied and does
\emph{not} transcend through either a series of de-layering transitions or
monomer-by-monomer transitions.Comment: 4 pages, 4 figure
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