First Data on PAE Levels in Surface Water in Lakes of the Eastern Coast of Baikal

The increasing consumption of phthalates (PAEs), along with their high toxicity and high mobility, poses a threat to the environment. This study presents initial data on the contents of six priority PAEs in the water of lakes located on the eastern shore of Lake Baikal-Arangatui, Bormashevoe, Dukhovoe, Kotokel, and Shchuchye. The mean total concentrations of the six PAEs in lakes Arangatui and Bormashevoe (low anthropogenic load) were comparable to those in Kotokel (medium anthropogenic load, 17.34 µg/L) but were significantly higher (p < 0.05) than in Dukhovoe and Shchuchye (high anthropogenic load, 10.49 and 2.30 µg/L, respectively). DBP and DEHP were the main PAEs in all samples. The DEHP content in lakes Arangatui and Bormashevoe was quite high, and at some sampling sites it exceeded the MACs established by Russian, U.S. EPA, and WHO regulations. The assessment showed that there is no potential risk to humans associated with the presence of PAEs in drinking water. However, the levels of DEHP, DBP, and DnOP in the water pose a potential threat to sensitive aquatic organisms, as shown by the calculated risk quotients (RQs). It is assumed that the origin of the phthalates in the studied lakes is both anthropogenic and biogenic

Trend Analysis of Precipitation, Runoff and Major Ions for the Russian Part of the Selenga River Basin

At present, the problem of climate change is becoming increasingly acute. This is especially pressing for Lake Baikal, a World Natural Heritage site. The Russian part of the Selenga watershed is a suitable site for climate change research. The study of changes in precipitation, runoff, and chemical runoff is important for sustainable water resources management. This study presents a trend analysis of precipitation and runoff at hydrological stations and weather stations in the Russian part of the Selenga River basin. A comparative analysis of the concentrations of major ions in the surface water of the Selenga River depending on water levels was also carried out. Analysis of the data series on precipitation revealed a slight negative trend at the Novoselenginsk, Ulan-Ude, and Kabansk stations, and a weak positive trend—at the Kyakhta station. Runoff analysis revealed negative trends at the two used stations (Novoselenginsk and Mostovoi). The hydrochemical regime of the Selenga River is characterized by an increase in major ions and salinity during winter low-water periods, and a decrease during high-water periods. Mineralization and major ion content are lower in the high-water period (2019–2021) than in the low-water period (2015–2017)

Phthalates in Surface Waters of the Selenga River (Main Tributary of Lake Baikal) and Its Delta: Spatial-Temporal Distribution and Environmental Risk Assessment

The Selenga River provides about half of the water and chemical runoff into Lake Baikal and plays an important role in the sustainability of the ecosystem of this large natural freshwater lake. Phthalate esters (PAEs) are organic compounds that can disrupt reproductive and endocrine systems. This study focused on investigating the distribution of six priority phthalates in the Selenga River and its delta utilizing SPE-GC/MS. The study found that the highest levels of Σ6PAE were observed during the high-water years, 2021 and 2023, and were evenly distributed along the river from the sampling sites upstream of Ulan-Ude to the delta channels. In contrast, the mean annual Σ6PAE content was relatively low in the low water period of 2022. Dibutyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DEHP) are the two dominant phthalates found in the surface waters of the Selenga River and delta channels. In 2021, the average total concentration of six phthalates (Σ6PAE) ranged from 8.84 to 25.19 µg/L, while in 2022 it ranged from 0.45 to 4.01 µg/L, and in 2023 it ranged from 5.40 to 21.08 µg/L. The maximum level for the sum of phthalates was 61.64 µg/L in 2021, 13.57 µg/L in 2022, and 30.19 µg/L in 2023. The wastewater treatment facilities in Ulan-Ude were identified as a stable local source of phthalates. In some cases, PAE concentrations exceeded maximum allowable concentrations, particularly for DEHP. This could have adverse effects on aquatic organisms