Strong Light-Matter Coupling in Carbon Nanotubes as a Route to Exciton Brightening

We show that strong light-matter coupling can be used to overcome a long standing problem that has prevented efficient optical emission from carbon nanotubes. The luminescence from the nominally bright exciton states of carbon nanotubes is quenched due to the fast nonradiative scattering to the dark exciton state having a lower energy. We present a theoretical analysis to show that by placing carbon nanotubes in an optical microcavity the bright exctonic state may be split into two hybrid exciton-polariton states, while the dark state remains unaltered. For sufficiently strong coupling between the bright exciton and the cavity, we show that the energy of the lower polariton may be pushed below that of the dark exciton. This overturning of the relative energies of the bright and dark excitons prevents the dark exciton from quenching the emission. Our resutls pave the way for a new approach to band-engineering the properties of the nanoscale optoelectronic devices.Comment: 35 pages, 5 figures, 6 pages of supplementary materials, 1 supplementary figur

Crystal Structure of a Hidden Protein, YcaC, a Putative Cysteine Hydrolase from Pseudomonas aeruginosa, with and without an Acrylamide Adduct

As part of the ongoing effort to functionally and structurally characterize virulence factors in the opportunistic pathogen Pseudomonas aeruginosa, we determined the crystal structure of YcaC co-purified with the target protein at resolutions of 2.34 and 2.56 Å without a priori knowledge of the protein identity or experimental phases. The three-dimensional structure of YcaC adopts a well-known cysteine hydrolase fold with the putative active site residues conserved. The active site cysteine is covalently bound to propionamide in one crystal form, whereas the second form contains an S-mercaptocysteine. The precise biological function of YcaC is unknown; however, related prokaryotic proteins have functions in antibacterial resistance, siderophore production and NADH biosynthesis. Here, we show that YcaC is exceptionally well conserved across both bacterial and fungal species despite being non-ubiquitous. This suggests that whilst YcaC may not be part of an integral pathway, the function could confer a significant evolutionary advantage to microbial life

Generation linewidth of an auto-oscillator with a nonlinear frequency shift: Spin-torque nano-oscillator

It is shown that the generation linewidth of an auto-oscillator with a nonlinear frequency shift (i.e. an auto-oscillator in which frequency depends on the oscillation amplitude) is substantially larger than the linewidth of a conventional quasi-linear auto-oscillator due to the renormalization of the phase noise caused by the nonlinearity of the oscillation frequency. The developed theory, when applied to a spin-torque nano-contact auto-oscillator, predicts a minimum of the generation linewidth when the nano-contact is magnetized at a critical angle to its plane, corresponding to the minimum nonlinear frequency shift, in good agreement with recent experiments.Comment: 4 pages, 2 figure

Study Of Oxidation Processes In Duck Meat With Application Of Rosemary And Grape Seed Extracts

The substantiation of the expedience of using antioxidants of a natural origin to decelerate oxidation processes in different meat products is an urgent direction of these studies. The prospective way of a solution of the problem of meat products oxidation spoilage is the use of vegetable extracts. The experimental studies of the effective use of the composition of rosemary and grape seed extracts in Peking duck forcemeat at the long storage were realized. Their influence on the dynamics of hydrolytic and peroxide oxidation of forcemeat lipids was studied. The analysis of oxidation secondary products accumulation was realized at the same time.The positive effect of the combined use of rosemary and grape seeds extracts on frozen Peking duck forcemeat was established, the optimal concentration of offered preparations was determined

Oscillatory transient regime in the forced dynamics of a spin torque nano-oscillator

We demonstrate that the transient non-autonomous dynamics of a spin torque nano-oscillator (STNO) under a radio-frequency (rf) driving signal is qualitatively different from the dynamics described by the Adler model. If the external rf current $I_{rf}$ is larger than a certain critical value $I_{cr}$ (determined by the STNO bias current and damping) strong oscillations of the STNO power and phase develop in the transient regime. The frequency of these oscillations increases with $I_{rf}$ as $\propto\sqrt{I_{rf} - I_{cr}}$ and can reach several GHz, whereas the damping rate of the oscillations is almost independent of $I_{rf}$. This oscillatory transient dynamics is caused by the strong STNO nonlinearity and should be taken into account in most STNO rf applications.Comment: 4 page, 3 figure

A nonlinear model for rotationally constrained convection with Ekman pumping

It is a well established result of linear theory that the influence of differing mechanical boundary conditions, i.e., stress-free or no-slip, on the primary instability in rotating convection becomes asymptotically small in the limit of rapid rotation. This is accounted for by the diminishing impact of the viscous stresses exerted within Ekman boundary layers and the associated vertical momentum transport by Ekman pumping. By contrast, in the nonlinear regime recent experiments and supporting simulations are now providing evidence that the efficiency of heat transport remains strongly influenced by Ekman pumping in the rapidly rotating limit. In this paper, a reduced model is developed for the case of low Rossby number convection in a plane layer geometry with no-slip upper and lower boundaries held at fixed temperatures. A complete description of the dynamics requires the existence of three distinct regions within the fluid layer: a geostrophically balanced interior where fluid motions are predominately aligned with the axis of rotation, Ekman boundary layers immediately adjacent to the bounding plates, and thermal wind layers driven by Ekman pumping in between. The reduced model uses a classical Ekman pumping parameterization to alleviate the need for spatially resolving the Ekman boundary layers. Results are presented for both linear stability theory and a special class of nonlinear solutions described by a single horizontal spatial wavenumber. It is shown that Ekman pumping allows for significant enhancement in the heat transport relative to that observed in simulations with stress-free boundaries. Without the intermediate thermal wind layer the nonlinear feedback from Ekman pumping would be able to generate a heat transport that diverges to infinity. This layer arrests this blowup resulting in finite heat transport at a significantly enhanced value.Comment: 38 pages, 14 figure