Dielectric properties of Li2O-3B2O3 glasses

The frequency and temperature dependence of the dielectric constant and the electrical conductivity of the transparent glasses in the composition Li2O-3B2O3 (LBO) were investigated in the 100 Hz- 10 MHz frequency range. The dielectric constant and the loss in the low frequency regime were electrode material dependent. Dielectric and electrical relaxations were respectively analyzed using the Cole-Cole and electric modulus formalisms. The dielectric relaxation mechanism was discussed in the framework of electrode and charge carrier (hopping of the ions) related polarization using generalized Cole-Cole expression. The frequency dependent electrical conductivity was rationalized using Jonscher's power law. The activation energy associated with the dc conductivity was 0.80 \pm 0.02 eV, which was ascribed to the motion of Li+ ions in the glass matrix. The activation energy associated with dielectric relaxation was almost equal to that of the dc conductivity, indicating that the same species took part in both the processes. Temperature dependent behavior of the frequency exponent (n) suggested that the correlated barrier hopping model was the most apposite to rationalize the electrical transport phenomenon in Li2O-3B2O3 glasses. These glasses on heating at 933 K/10h resulted in the known non-linear optical phase LiB3O5.Comment: 32 pages, 13 figure

Collective Modes in the Loop Current Ordered Phase of Cuprates

Recently two branches of weakly dispersive collective modes have been discovered in under-doped cuprates by inelastic neutron scattering. Polarization analysis reveals that the modes are magnetic excitations. They are only visible for temperatures below the transition temperature to a broken symmetry phase which was discovered earlier and their intensity increases as temperature is further decreased. The broken symmetry phase itself has symmetries consistent with ordering of orbital current loops within a unit-cell without breaking translational symmetry. In order to calculate the collective modes of such a state we add quantum terms to the Ashkin-Teller (AT) model with which the classical loop current order has been described. We derive that the mean field ground state of the quantum model is a product over all unit-cells of linear combination of the four possible classical configurations of the loop current order in each unit-cell. The collective modes are calculated by using a generalized Holstein-Primakoff boson representation of orbital moment operators and lead to three branches of gapped weakly dispersive collective modes. The experimental results are consistent with the two lower energy branches; the third mode is at a higher energy than looked for by present neutron scattering experiments and might also be over-damped. Implications of the discovery of the collective modes are discussed.Comment: 16 pages, 6 figure