Hydrochars as Emerging Biofuels: Recent Advances and Application of Artificial Neural Networks for the Prediction of Heating Values

In this study, the growing scientific field of alternative biofuels was examined, with respect to hydrochars produced from renewable biomasses. Hydrochars are the solid products of hydrothermal carbonization (HTC) and their properties depend on the initial biomass and the temperature and duration of treatment. The basic (Scopus) and advanced (Citespace) analysis of literature showed that this is a dynamic research area, with several sub-fields of intense activity. The focus of researchers on sewage sludge and food waste as hydrochar precursors was highlighted and reviewed. It was established that hydrochars have improved behavior as fuels compared to these feedstocks. Food waste can be particularly useful in co-hydrothermal carbonization with ash-rich materials. In the case of sewage sludge, simultaneous P recovery from the HTC wastewater may add more value to the process. For both feedstocks, results from large-scale HTC are practically non-existent. Following the review, related data from the years 2014–2020 were retrieved and fitted into four different artificial neural networks (ANNs). Based on the elemental content, HTC temperature and time (as inputs), the higher heating values (HHVs) and yields (as outputs) could be successfully predicted, regardless of original biomass used for hydrochar production. ANN3 (based on C, O, H content, and HTC temperature) showed the optimum HHV predicting performance (R2 0.917, root mean square error 1.124), however, hydrochars’ HHVs could also be satisfactorily predicted by the C content alone (ANN1, R2 0.897, root mean square error 1.289)

Design and Implementation of Single-Layer 4 × 4 and 8 × 8 Butler Matrices for Multibeam Antenna Arrays

Single-layer 4 × 4 and 8 × 8 Butler matrices (BMs) that operate in the L and S bands are implemented in this paper. Easy-to-fabricate microstrip layout topologies are designed and constructed; the final arrangement of the BMs allows realization without any crossovers. The performance of the networks is evaluated by measuring their frequency response. The return loss (RL) and the isolation are below -15 dB over the operation bandwidth for all structures, whereas the average insertion loss is less than 1 dB for the 4 × 4 BM and does not exceed 3 dB for the 8 × 8 BM. The amplitude imbalance is at most 0.5 dB and 1.5 dB, for the 4 × 4 and the 8 × 8 BMs, respectively. Moreover, multibeam antenna arrays fed by the BMs are constructed. The radiation patterns are measured and compared with theoretical data; a good agreement is achieved. The side lobes are sufficiently low, compared to the theoretical predictions, whereas they are further reduced by applying appropriate excitation schemes to the input ports of the BMs

Wearable Textile Antenna with a Graphene Sheet or Conductive Fabric Patch for the 2.45 GHz Band

Textile patch antennas of simple rectangular, triangular, and circular shape, for operation in the 2.4–2.5 GHz free industrial, scientific, and medical (ISM) band, are designed in this paper. Thirty-six patch antenna prototypes have been fabricated by engaging different patch geometries, patch materials, and substrate materials. Each patch antenna is designed after optimization by a genetic algorithm, which evolves the initial dimensions and feeding position of the prototype’s microstrip counterpart to the final optimal geometrical characteristics of the wearable prototype (with the originally selected shape and materials). The impact of the design and fabrication details on antenna performance were thoroughly investigated. Graphene sheet patches were tested against conductive fabric and copper sheet ones, while denim and felt textile substrates were competing. The comparative study between a large number of different graphene, all, and copper textile prototypes, which revealed the excellent suitability of graphene for wearable applications, is the main contribution of this paper. Additional novelty elements are the compact, flexible, and easy-to-fabricate structure of the proposed antennas, as well as the use of state-of-the-art conductive materials and commercially available fabrics and the extensive investigation of many prototypes in various bending conditions. Simulations and measurements of the proposed antennas are in very good agreement. All fabricated prototypes are characterized by flexibility, light weight, mechanical stability, resistance to shock, bending and vibrations, unhindered integration to clothes, low-cost implementation, simple, time-saving, and industry-compatible fabrication process, and low specific absorption rate (SAR) values (computed using rectangular and voxel models); the graphene prototypes are additionally resistant to corrosion, and the circular ones have very good performance under bending conditions. Many antenna prototypes demonstrate interesting characteristics, such as relatively wide bandwidth, adequate gain, firm radiation patterns, coverage of the ISM band even under bending, and very low SAR values. For example, the circular graphene patch (with 55.3 mm diameter attached upon a 165.9 × 165.9 mm) felt substrate CGsF1 prototype accomplishes 109 MHz measured bandwidth, 5.45 dBi gain, 56% efficiency, full coverage of the ISM band under bending, and SAR less than 0.003 W/Kg