A stochastic design rainfall generator based on copulas and mass curves

The use of design storms can be very useful in many hydrological and hydraulic practices. In this study, the concept of a copula-based secondary return period in combination with the concept of mass curves is used to generate point-scale design storms. The analysis is based on storms selected from the 105 year rainfall time series with a 10 min resolution, measured at Uccle, Belgium. In first instance, bivariate copulas and secondary return periods are explained, together with a focus on which couple of storm variables is of highest interest for the analysis and a discussion of how the results might be affected by the goodness-of-fit of the copula. Subsequently, the fitted copula is used to sample storms with a predefined secondary return period for which characteristic variables such as storm duration and total storm depth can be derived. In order to construct design storms with a realistic storm structure, mass curves of 1st, 2nd, 3rd and 4th quartile storms are developed. An analysis shows that the assumption of independence between the secondary return period and the internal storm structure could be made. Based on the mass curves, a technique is developed to randomly generate an intrastorm structure. The coupling of both techniques eventually results in a methodology for stochastic design storm generation. Finally, its practical usefulness for design studies is illustrated based on the generation of a set of statistically identical design storm and rainfall-runoff modelling

Fe/Co Alloys for the Catalytic Chemical Vapor Deposition Synthesis of Single- and Double-Walled Carbon Nanotubes (CNTs). 2. The CNT−Fe/Co−MgAl2O4 System

A detailed 57Fe Mössbauer study of the Mg(0.8)Fe(0.2-y)Co(y)Al2O4 (y = 0, 0.05, 0.1, 0.15, 0.2) solid solutions and of the CNT-Fe/Co-MgAl2O4 nanocomposite powders prepared by reduction in H2-CH4 has allowed characterization of the different iron phases involved in the catalytic process of carbon nanotube (CNT) formation and to correlate these results with the carbon and CNT contents. The oxide precursors consist of defective spinels of general formulas (Mg(1-x-y)(2+)Fe(x-3alpha)(2+)Fe(2alpha)(3+)[symbol: see text](alpha)Co(y)(2+)Al2(3+))O4(2-) . The metallic phase in the CNT-Fe/Co-MgAl2O4 nanocomposite powders is mostly in the form of the ferromagnetic alpha-Fe/Co alloy with the desired composition. For high iron initial proportions, the additional formation of Fe3C and gamma-Fe-C is observed while for high cobalt initial proportions, the additional formation of a gamma-Fe/Co-C phase is favored. The higher yield of CNTs is observed for postreaction alpha-Fe(0.50)Co(0.50) catalytic particles, which form no carbide and have a narrow size distribution. Alloying is beneficial for this system with respect to the formation of CNTs

The boundary between the middle Eocene Brussel sand and the Lede sand formations in the Zaventem-Nederokkerzeel area (northeast of Brussels, Belgium)

In the Zaventem airport railway cutting, to the north-east of Brussels, the upper part of the Brussel Sand Formation consists of two major units, both attributable to calcareous nannofossil zone NP14a. The lower predomi­nantly sandy unit ZB1 (including subunits A, B and C, belonging to NP14al) is built up of sparsely glauconitic, relatively coarse tidal current deposits with nodule levels cemented by carbonate and silica, of which one shows slump­ing structures and is interpreted as a seismite. The uppermost unit ZB2 (also labelled D, belonging to NP14a2), com­posed of alternating thin fine sandstone bands and silty marls, represents the fill of a large channel. In the Berg-Nederokkerzeel sandpit the carbonate-rich Brussel Sand Formation is finer grained and more homogeneous. Here, the basal sand (unit A) is attributable to NP14a3 and consequently, younger than the section exposed at Zaventem. It is incised at its the top by a rather narrow erosive gully, filled in with well-sorted fine sand rich in washed-in molluscs (unit B), some of which seem to point to a brackish influence. The extreme top is made up of half a meter of sand with abundant Callianassa burrows and echinid fragments (unit C). From the nannofossil data it appears that, east of Brus­sels, at least two generations of tidal channel systems seem to have occurred within the Brussel Sand Formation, followed by a partial emersion at the end of the filling of the uppermost channel (Nederokkerzeel B). This was suc­ceeded by a relative sea-level rise, as shown by unit C and the remains of a completely eroded fully marine deposit, reworked in the base of the overlying Lede Sand Formation. The lowest relative sea level, with at least partial emer­gence of the Brussels area, occurred during middle to late Biochron NP14b. In both outcrops the Lede Sand Formation displays its characteristic pale grey relatively fine-grained homogeneous nature with a stone layer near its base. It can be concluded that, at the beginning of the "Lede transgression", an erosion of older deposits, containing already lifhified stone layers, occurred. This was, apparently, at least locally, caused by storms, which could redistribute, imbricate and turn over the stones, explaining their bio-perforation on both sides. Afterwards the stones have been above water for a relatively long time, enough to allow the dissolution of the perforating organisms and consequently an important oxidation of their surfaces. These stones have subsequently been colonised by a new marine fauna. Part of the shark teeth and calcareous nannofossil assemblages found in the coarse base of the Lede Sand is definitely older than the taxa normally found in the Lede Sand Formation. These fossils are the remains of a sediment package, believed to represent the formerly "Laekenian" stage

Stable oxygen isotope record of the Eocene-Oligocene transition in the southern North Sea Basin: positioning the Oi-1 event

Preliminary stable oxygen isotope data are presented from the southern North Sea Basin successions, ranging from the Lutetian to Rupelian. Analyses were performed on fish otoliths, nuculid bivalves and benthic foraminifera and are presented as bulk delta(18)O values relative to a well established regional sequence stratigraphic framework. The most significant positive shift in delta(18)O values clearly falls at the top of the regionally recognised Bassevelde 3 sequence, which base corresponds to the Eocene-Oligocene GSSP boundary. The here documented delta(18)O shift is closely associated with the base of the traditional Rupelian unit-stratotype and is tentatively correlated to the globally recognised Oi-1 event

Re-assessment of the new geological map of Belgium: earliest Oligocene dinoflagellate cyst-based ages in the Leuven area (sheet 24 Aarschot)

The dinoflagellate cyst (dinocyst) assemblages of two samples from a temporary outcrop in the vicinity of Haacht (Leuven) have been analysed. The co-occurrence of Areosphaeridium diktyoplokum, Cerebrocysta bartonensis, Glaphyrocysta semitecta, Rombodinium perforatum and Thalassiphora reticulata allows correlation with the North Sea Oligocene-1 zone. As a consequence, the considered unit has a latest Eocene to earliest Oligocene age, equivalent to the age of the marine Tongrian. Comparison of the studied area with the recent 1:50 000 geological map (sheet 24 Aarschot) shows that the current lithostratigraphic interpretation of the analysed section, i.e. the Middle Eocene Maldegem Formation, can no longer be uphold

Catch comparison of pulse trawls vessels and a tickler chain beam trawler

Comparative fishing trials were conducted in May 2011 (week 19) on commercial beam trawlers fishing with conventional tickler chain beam trawls (on MFV GO4), pulse wings made by HFK-Engineering of Baarn, the Netherlands (MFV TX36), and pulse trawls produced by the DELMECO-Group of Goes, the Netherlands (version used on MFV TX68). The three vessels fished side-by-side as much as possible. Landings and discards of these vessels were monitored. Special emphasis was given on cod and whiting, that were dissected to study possible spinal damage. Result for TX36 and TX68 are expressed in terms of percentages of GO4. The pulse characteristics were as follows: TX36: voltage 45 V0 to peak, pulse frequency: 45 Hz, pulse duration 380 μs; electric power on single gear: 7.0 kW; TX68: voltage 50 V0 to peak, pulse frequency: 50 Hz, pulse duration 220 μs; electric power on single gear: 8.5 kW. The fuel consumption recorded over the whole week was considerably lower for the pulse trawls, i.e. on TX36 (40%) and on TX68 (54%), than for the tickler chain beam trawls used on the GO4. The net earnings (taken as gross earnings minus fuel costs) for the TX36 were almost twice as large at 186%, and for the TX68 also considerably higher at 155%. The vessels with pulse trawls caught fewer (65-69%) target species, but also less (30-50%) immature and non-target fish ('discards'), and benthic species (48-73%) than the vessel with tickler chains on these fishing grounds and in this period. The pulse gears caught fewer (19-42%) kg per hour cod than the tickler chain beam trawls, but the catches of cod on all three vessels were very small. For plaice and dab these differences were statistically proven, for brill, turbot and cod this was not the case. There was no marked difference between both pulse trawl vessels in total landings. The TX68 caught less marketable sole, but not significantly less undersized sole than the GO4. The TX36 caught less undersized sole, but here the difference in marketable fish was not significant. Catches of brill and turbot were so small that no statistically substantiated conclusion could be drawn. Only for undersized turbot the TX36 caught less. For whiting we found a demonstrable reduction in both marketable and undersized fish in both pulse fishing vessels. The TX36 caught less whiting in number per hour. The CPUEs found from the auction data and the sampled hauls correlated reasonably well for the most abundant species, such as plaice and sole. However, for less abundant species the results did not match very well, and care should be taken to increase the sampling rate in future comparative fishing studies. Spinal fracture in cod occurred under pulse stimulation but to a limited extent in both marketable and undersized fish. There is an indication that this happens slightly more on TX68 (11%) than on TX36 (7%). Whiting hardly seems to suffer any damage

Improved quantum algorithms for the ordered search problem via semidefinite programming

One of the most basic computational problems is the task of finding a desired item in an ordered list of N items. While the best classical algorithm for this problem uses log_2 N queries to the list, a quantum computer can solve the problem using a constant factor fewer queries. However, the precise value of this constant is unknown. By characterizing a class of quantum query algorithms for ordered search in terms of a semidefinite program, we find new quantum algorithms for small instances of the ordered search problem. Extending these algorithms to arbitrarily large instances using recursion, we show that there is an exact quantum ordered search algorithm using 4 log_{605} N \approx 0.433 log_2 N queries, which improves upon the previously best known exact algorithm.Comment: 8 pages, 4 figure

Effect of spin-orbit coupling on the excitation spectrum of Andreev billiards

We consider the effect of spin-orbit coupling on the low energy excitation spectrum of an Andreev billiard (a quantum dot weakly coupled to a superconductor), using a dynamical numerical model (the spin Andreev map). Three effects of spin-orbit coupling are obtained in our simulations: In zero magnetic field: (1) the narrowing of the distribution of the excitation gap; (2) the appearance of oscillations in the average density of states. In strong magnetic field: (3) the appearance of a peak in the average density of states at zero energy. All three effects have been predicted by random-matrix theory.Comment: 5 pages, 4 figure