41 research outputs found
Quantum-Dot and Polychalcone Mixed Nanocomposites for Polymer Light-Emitting Diodes
The present work is aimed at improving the efficiency of light-emitting diodes (LEDs) through the amalgamation of polymeric materials and quantum dots (QDs) in nanocomposites. Herein, we report on the polytriphenylamine-based chalcone (PTpC) or polycarbazole-based chalcone- (PCzC-) QDs mixture nanocomposites as emissive layers for polymer LEDs (PLEDs). QDs were evenly dispersed in the polymer matrix and the synthesized PTpC-QDs and PCzC-QDs nanocomposites were able to form smooth thin films. The luminance characteristics of PTpC-QDs and PCzC-QDs nanocomposites were better than those of the pristine QD, PTpC, and PCzC materials, owing to the high charge-carrier transport ability of polymer-QDs nanocomposites. These results indicate that the proposed polymer-QDs nanocomposites could be potential candidates for application in PLEDs
The Role of Optimal Electron Transfer Layers for Highly Efficient Perovskite Solar Cells—A Systematic Review
Perovskite solar cells (PSCs), which are constructed using organic–inorganic combination resources, represent an upcoming technology that offers a competitor to silicon-based solar cells. Electron transport materials (ETMs), which are essential to PSCs, are attracting a lot of interest. In this section, we begin by discussing the development of the PSC framework, which would form the foundation for the requirements of the ETM. Because of their exceptional electronic characteristics and low manufacturing costs, perovskite solar cells (PSCs) have emerged as a promising proposal for future generations of thin-film solar energy. However, PSCs with a compact layer (CL) exhibit subpar long-term reliability and efficacy. The quality of the substrate beneath a layer of perovskite has a major impact on how quickly it grows. Therefore, there has been interest in substrate modification using electron transfer layers to create very stable and efficient PSCs. This paper examines the systemic alteration of electron transport layers (ETLs) based on electron transfer layers that are employed in PSCs. Also covered are the functions of ETLs in the creation of reliable and efficient PSCs. Achieving larger-sized particles, greater crystallization, and a more homogenous morphology within perovskite films, all of which are correlated with a more stable PSC performance, will be guided by this review when they are developed further. To increase PSCs’ sustainability and enable them to produce clean energy at levels previously unheard of, the difficulties and potential paths for future research with compact ETLs are also discussed
Advancements in Metal-Ion Capacitors: Bridging Energy and Power Density for Next-Generation Energy Storage
Metal-ion capacitors (MICs) have emerged as advanced hybrid energy storage devices that combine the high energy density of batteries with the superior power density and long cycle life of supercapacitors. By leveraging a unique configuration of faradaic and non-faradaic energy storage mechanisms, MICs offer a balanced performance that meets the diverse requirements of modern applications, including renewable energy systems, electric vehicles, and portable electronics. MICs employ diverse ions such as lithium, sodium, and potassium, which provide flexibility in material selection, scalability, and cost-effectiveness. For instance, lithium-ion capacitors (LICs) excel in compact and high-performance applications, while sodium-ion (NICs) and potassium-ion capacitors (KICs) provide sustainable and affordable solutions for large-scale energy storage. This review highlights the advancements in electrode materials, including carbon-based materials, transition metal oxides, and emerging candidates like MXenes and metal–organic frameworks (MOFs), which enhance MIC performance. The role of electrolytes, ranging from organic and aqueous to hybrid and solid-state systems, is also examined, emphasizing their influence on energy density, safety, and operating voltage. Additionally, the article discusses the environmental and economic benefits of MICs, including the use of earth-abundant materials and bio-derived carbons, which align with global sustainability goals. The review concludes with an analysis of practical applications, commercialization challenges, and future research directions, including AI-driven material discovery and integration into decentralized energy systems. As versatile and transformative energy storage devices, MICs are poised to play a critical role in advancing sustainable and efficient energy solutions for the future
Reduced Graphene Oxide Decorated Au Nanoparticles as an Efficient Electrode for the Determination of Hydroquinone
Highly active and reducing agent-free preparation of cost-effective NiO-based carbon nanocomposite and its application in reduction reactions under mild conditions
A Review on Sustainable Upcycling of Plastic Waste Through Depolymerization into High-Value Monomer
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular approach that converts plastic waste back into valuable monomers and chemical feedstocks. This article provides an in-depth narrative review of recent progress in the upcycling of major plastic types such as PET, PU, PS, and engineering plastics through thermal, chemical, catalytic, biological, and mechanochemical depolymerization methods. Each method is critically assessed in terms of efficiency, scalability, energy input, and environmental impact. Special attention is given to innovative catalyst systems, such as microsized MgO/SiO2 and Co/CaO composites, and emerging enzymatic systems like engineered PETases and whole-cell biocatalysts that enable low-temperature, selective depolymerization. Furthermore, the conversion pathways of depolymerized products into high-purity monomers such as BHET, TPA, vanillin, and bisphenols are discussed with supporting case studies. The review also examines life cycle assessment (LCA) data, techno-economic analyses, and policy frameworks supporting the adoption of depolymerization-based recycling systems. Collectively, this work outlines the technical viability and sustainability benefits of depolymerization as a core pillar of plastic circularity and monomer recovery, offering a path forward for high-value material recirculation and waste minimization
Convolvulus microphyllus Extract as a Green, Effective, and Affordable Corrosion Inhibitor: Theoretical Calculations and Experimental Studies
This study demonstrates the ability of Convolvulus microphyllus extract to prevent low-carbon steel corrosion (LCS) by varying inhibitor concentration. The effectiveness of the corrosion reaction was examined using gravimetric techniques and electrochemical procedures in a corrosive 0.5 M sulfuric acid medium. The results of polarization show a mixed adsorption nature on the LCS surface. C. microphyllus-derived film (extract) had an inhibition efficiency (IE) of 92.47% at an inhibitor concentration of 600 mg/L and a temperature 298 K. To examine the morphology, a scanning electron microscope (SEM) and atomic force microscope (AFM) were used to analyze the external films that protect LCS from sulfuric acid. A thin protective coat of inhibitor outside the LCS substrate follows the Langmuir adsorption isotherm. Additionally, computational exploration provided vital insights. The results of these experimental inhibitory outcomes are consistent with those of molecular dynamic simulations
Upgrading the Strategy of Multistage Torrefaction Liquid by the Selective Oxidation Reaction Route Using a Reusable MgO-Based Au/Al<sub>2</sub>O<sub>3</sub>Catalyst
A Systematic Review of the Applications of Electronic Nose and Electronic Tongue in Food Quality Assessment and Safety
Food quality assessment is a critical aspect of food production and safety, ensuring that products meet both regulatory and consumer standards. Traditional methods such as sensory evaluation, chromatography, and spectrophotometry are widely used but often suffer from limitations, including subjectivity, high costs, and time-consuming procedures. In recent years, the development of electronic nose (e-nose) and electronic tongue (e-tongue) technologies has provided rapid, objective, and reliable alternatives for food quality monitoring. These bio-inspired sensing systems mimic human olfactory and gustatory functions through sensor arrays and advanced data processing techniques, including artificial intelligence and pattern recognition algorithms. The e-nose is primarily used for detecting volatile organic compounds (VOCs) in food, making it effective for freshness evaluation, spoilage detection, aroma profiling, and adulteration identification. Meanwhile, the e-tongue analyzes liquid-phase components and is widely applied in taste assessment, beverage authentication, fermentation monitoring, and contaminant detection. Both technologies are extensively used in the quality control of dairy products, meat, seafood, fruits, beverages, and processed foods. Their ability to provide real-time, non-destructive, and high-throughput analysis makes them valuable tools in the food industry. This review explores the principles, advantages, and applications of e-nose and e-tongue systems in food quality assessment. Additionally, it discusses emerging trends, including IoT-based smart sensing, advances in nanotechnology, and AI-driven data analysis, which are expected to further enhance their efficiency and accuracy. With continuous innovation, these technologies are poised to revolutionize food safety and quality control, ensuring consumer satisfaction and compliance with global standards
