Study of the thermal conductivity of natural carbonates

The thermal conductivity of natural monoliths of calcite, dolomite marble, and limestone from various deposits was measured using the absolute stationary method of longitudinal heat flow in the temperature range of 50–300 K and the dynamic method in the range of 323–573 K. A majority of calcite marbles were inferior in thermal conductivity to dolomite marbles. At room temperature, the thermal conductivity coefficients of all studied samples were lower k = 5 W/(m K). The obtained data were compared with the literature data. The diversity of experimental data from different authors on the thermal conductivity of carbonates is associated with qualitative differences in the samples studie

Comparative assessment of the operation quality of shovel-truck systems at open-pit coal mines in the summer and transitional seasons

The operation quality of shovel-truck systems (STSs) at open-pit coal mines in the summer and transitional autumn-spring periods differs markedly. This is due to a decrease in the speed of haul trucks during the transitional season compared to the summer season. This leads to an increase in the travel time of trucks. Shovels and trucks must work longer to ensure the planned volumes of loading and transportation and the required number of hauls. Consequently, the duration of the working shift (or day) increases. This leads to deterioration in the STS performance in the autumn-spring period. A quantitative assessment of changes in the STS operation quality will reveal the directions of its improvement

THE TRAINING OF HIGHLY QUALIFIED PERSONNEL IN THE DISCOURSE OF THE BOLOGNA PROCESS: HIGHWAY VERSUS ROADSIDE

Introduction: in the conditions of post-reform Russia the questions of training personnel of higher qualification has been repeatedly raised in the scientific community and one of the main issues was the question about graduate school. Especially this question became more urgent after Russia’s accession to the Bologna agreement in 2003. Materials and Methods: the article examines the problematic aspects of the scientific, organizational and pedagogical factors, procedures and criteria. In the conditions of post-reform Russia the questions of training personnel of higher qualification has been repeatedly raised in the scientific community and one of the main issues was the question about graduate school. Especially this question became more urgent after Russia’s accession to the Bologna agreement in 2003. The article explores the meaningful aspects of the scientific, organizational and pedagogical factors, procedures and criteria for the development and efficiency of the Institute of doctoral (Ph.D. in Russia) compared with similar – in the European Union (doctorate) on the example of its functioning in Latvia. Results: discusses specific aspects of individual factors, procedures and criteria for the development of the Institute of postgraduate studies in Russia. On the example of the European experience, it becomes better understood form of innovation, and in fact, largely a destructive program (in relation to the preservation and development of schools in the reproduction of scientific-pedagogical personnel of higher qualification) have been actively conducted for 2015-the year of the reform of the Institute of postgraduate studies in Russia. Discussion and Conclusions: according to the research results the conclusions about the directions of improvement of training of highly qualified personnel in Russia, taking into account the European experience in this field. To revert to the old functionality targeted Russian postgraduate – training of the teaching and research staff of higher qualification with doctoral degree, with the prospect of official recognition of this degree at the Ph.D. level (branches of science). “Unload” the educational program of the graduate school, primarily through the disciplines which were studied in master’s and specialist degrees. In preparation for the thesis and the procedure of its protection to use foreign experience and promotion of scientific promotion in the spirit of the Bologna process while maintaining the best national traditions and stimulate the reproduction of the leading Russian scientific schools to address major fundamental and applied problems of achieving the world’s priorities

The Influence of Concentrations of Sensitizers and Activators on Luminescence Kinetics Parameters of Up-Conversion Nanocomplexes NaYF₄:Yb³⁺/Tm³⁺

For colloids of NaYF4:Yb3+/Tm3+ nanoparticles in DMSO, by the method of time-resolved luminescence spectroscopy with nanosecond pulsed excitation at a wavelength of 975 nm, the photophysical processes that determine the course of kinetic curves have been revealed. It has been found that the luminescence rise time decreases with an increase in the concentration of activators and sensitizers due to the increase in the efficiency of energy transfer from sensitizers to activators. The cross-relaxation of the excited states of activators provides a decrease in the luminescence decay time with an increase in the concentration of activators and a constant concentration of the sensitizer. There is no correlation between the time of luminescence decay with the change in the concentration of sensitizers and the constant concentration of activators due to the competition of the processes of energy back transfer from activators to sensitizers and the “feeding” of activators by excitations coming from remote sensitizer ions

The Melt of Sodium Nitrate as a Medium for the Synthesis of Fluorides

The preparation of NaLnF4 complexes, LnF3 (Ln = La, Ce, Y) rare earth binary fluorides, CaF2 and SrF2 alkali earth fluorides, as well as mixtures of these compounds from their nitrates dissolved in molten NaNO3 has been studied in order to select the ideal solvent for fluoride synthesis by spontaneous crystallization from flux. Sodium fluoride (NaF) was used as a fluorinating agent. The results of our experiments have confirmed that NaNO3 melt is one of the most promising media for precipitating said inorganic fluoride materials within a broad temperature range (300–500 °С). Also, in contrast with precipitation/co-precipitation from aqueous solutions, our syntheses have resulted in obtaining equilibrium phases only

Structural and Spectroscopic Features of the Bixbyite-Type Yttrium Scandate Doped by Rare-Earth Ions

Yttrium scandate crystal fiber has been obtained through laser-heated pedestal growth. The crystal belongs to a bixbyite crystal structure and crystallizes in Ia3¯ space group. X-ray diffraction method shows a lattice parameter of a = 10.228(1) Å. Factor-group analysis of YScO3 Raman spectra points to high degree of disorder in crystal structure of the new compound. Spectral-kinetic investigation of the crystal fibers doped by rare-earth ions points to the presence of two independent active optical centers of rare-earth ions. Moreover, the character of rare-earth impurities’ distribution is independent on a rare-earth ionic radius size

Structural and Spectroscopic Features of the Bixbyite-Type Yttrium Scandate Doped by Rare-Earth Ions

Yttrium scandate crystal fiber has been obtained through laser-heated pedestal growth. The crystal belongs to a bixbyite crystal structure and crystallizes in Ia3¯ space group. X-ray diffraction method shows a lattice parameter of a = 10.228(1) Å. Factor-group analysis of YScO3 Raman spectra points to high degree of disorder in crystal structure of the new compound. Spectral-kinetic investigation of the crystal fibers doped by rare-earth ions points to the presence of two independent active optical centers of rare-earth ions. Moreover, the character of rare-earth impurities’ distribution is independent on a rare-earth ionic radius size

Annealing process and temperature effects on silicon-vacancy and germanium-vacancy centers in CVD grown polycrystalline diamond

The annealing treatment plays a crucial role in tailoring the properties of synthetic diamond materials, especially those doped with various elements in order to form specific color centers like nitrogen-vacancy (NV), silicon-vacancy (Si-V), germanium-vacancy (Ge-V), etc. This study delves into the annealing of 175 μm-thick Ge-doped polycrystalline diamond (PCD) films grown by microwave plasma-assisted chemical vapor deposition (MPCVD). Large-area PCD plate was cut into smaller equivalent 5 × 5 mm2 pieces, which were separately subjected to annealing in microwave plasma in H2 atmosphere, to annealing in vacuum or to annealing under high-pressure high-temperature conditions (HPHT, 5.9 GPa, 2000 °C). The structure, phase composition and photoluminescence (PL) of samples before and after various annealing processes were investigated. All applied types of annealing enhance both the Si-V and Ge-V lines in PL at room temperature. Increasing annealing temperature leads to gradual decrease of full widths at half-maxima (FWHM) of diamond Raman peak (1332.5 cm−1), as well as Si-V (738 nm) and Ge-V (602 nm) PL peaks. In addition, the limitations for each type of annealing are established. The obtained results are crucial for the design of CVD-grown Ge-doped and Si-doped PCD materials that can be used for applications in photonics such as single photon sources, biomarkers, as well as for the fabrication of optical diamond thermometers

Hall Effect Anisotropy in the Paramagnetic Phase of Ho_0.8Lu_0.2B₁₂ Induced by Dynamic Charge Stripes

A detailed study of charge transport in the paramagnetic phase of the cage-cluster dodecaboride Ho0.8Lu0.2B12 with an instability both of the fcc lattice (cooperative Jahn–Teller effect) and the electronic structure (dynamic charge stripes) was carried out at temperatures 1.9–300 K in magnetic fields up to 80 kOe. Four mono-domain single crystals of Ho0.8Lu0.2B12 samples with different crystal axis orientation were investigated in order to establish the singularities of Hall effect, which develop due to (i) the electronic phase separation (stripes) and (ii) formation of the disordered cage-glass state below T*~60 K. It was demonstrated that a considerable intrinsic anisotropic positive component ρanxy appears at low temperatures in addition to the ordinary negative Hall resistivity contribution in magnetic fields above 40 kOe applied along the [001] and [110] axes. A relation between anomalous components of the resistivity tensor ρanxy~ρanxx1.7 was found for H||[001] below T*~60 K, and a power law ρanxy~ρanxx0.83 for the orientation H||[110] at temperatures T S~15 K. It is argued that below characteristic temperature TS~15 K the anomalous odd ρanxy(T) and even ρanxx(T) parts of the resistivity tensor may be interpreted in terms of formation of long chains in the filamentary structure of fluctuating charges (stripes). We assume that these ρanxy(H||[001]) and ρanxy(H||[110]) components represent the intrinsic (Berry phase contribution) and extrinsic (skew scattering) mechanism, respectively. Apart from them, an additional ferromagnetic contribution to both isotropic and anisotropic components in the Hall signal was registered and attributed to the effect of magnetic polarization of 5d states (ferromagnetic nano-domains) in the conduction band of Ho0.8Lu0.2B12

Effect of extended defects on phonon confinement in polycrystalline Si and Ge films

We present Raman spectroscopy of the polycrystalline Si and Ge films deposited by molecular beam deposition on a dielectric substrate. The Raman study has been made using lasers with different wavelengths. Structural properties of the poly-films have been studied by XRD and TEM. The Raman spectra are characterized by appearance of the additional wide peaks around 500 cm–1 and 290 cm–1 in the main vibrational bands of TO(c-Si) and TO(c-Ge) phonons, respectively. It is shown that these peaks correspond to scattering in grain boundary area. For the poly–Si films, both a downward shift and an asymmetrical broadening of the vibrational band of TO(c-Si) near 520 cm–1 are observed, whereas there is only a symmetric broadening in the spectra of poly-Ge. The Raman line shape has been modeled within the framework of the phonon confinement theory taking into account the sizes of coherent scattering domains obtained using XRD. The model includes a symmetrical band broadening observed in polycrystalline films. It is shown that confinement of phonon propagation might be in the poly–Si films. The phonon dispersion and the density of phonon states have been simulated using density functional theory. It has been found that phonon confinement relates to grain boundaries rather than other extended defects such as twins (multiple twins, twin boundaries), the appearance of which does not lead to significant changes in phonon dispersion and density of phonon states