Thermodynamic rarity and the loss of mineralwealth

The second law of thermodynamics and, specifically, exergy analysis have been traditionally used for the assessment and optimization of energy systems. Nevertheless, as shown in this paper, exergy could also constitute a powerful tool for the evaluation of mineral commodities. That said, new or re-defined exergy-based concepts need to be developed. This paper presents Thanatia as a baseline for evaluating the exergy of any mineral in the crust and opens the door to discuss the “thermodynamic rarity” concept as a basis for exergy analyses for mineral systems. Thermodynamic rarity is understood as the amount of exergy needed to obtain a given mineral from a completely degraded state, denoted as Thanatia. The rarer the mineral, the greater the associated exergy costs. It quantifies value, as it relates to concentration, chemical composition and cohesion, key aspects that determine whether a mine is exploitable. The theory further allows one to quantify the gradual loss of mineral capital on Earth as a consequence of “rarefaction processes” that occur at a mineral’s end-of-life, when a commodity is wasted, and at its beginning-of-life, where mining ore grades decline after extraction

The ATLAS TileCal Read-Out Drivers Signal Reconstruction

TileCal is the hadronic calorimeter of the ATLAS experiment at the LHC collider at CERN. The Read-Out Drivers (ROD) are the core of the off-detector electronics. The main components of the RODs are the Digital Signal Processor (DSP) placed on the Processing Unit (PU) dautherboards. This paper describes the DSP code and its performance with calibration and real data. The code is divided into two different parts: the first part contains the core functionalities and the second one the reconstruction algorithms. The core acts as an operating system and it controls the configuration, the data reception, transmission, online monitoring and the synchronization between front-end data and the Trigger information. The reconstruction algorithms implemented on the DSP are the Optimal Filtering (OF), Muon Tagging (MTag) and Total Transverse Energy (ET) calculation. The OF algorithm reconstructs the deposited energy and the arrival time of the data on every calorimeter cell within a front-end module. This reconstructed energy is used by the MTag algorithm to tag low transverse momentum muons that may escape the ATLAS muon spectrometer Level 1 trigger whereas the ET algorithm computes the total transverse energy and the projection on X and Y for the entire module that will be used by the Level 2 trigger system. The DSP code performance is being validated with comparisons with offline reconstruction. The DSP performance is evaluated using cali bration data from Charge Injection System

Exergy assessment of topsoil fertility

Soil degradation, affecting around 38% of the world''s cropland, threatens the global food supply. Due to the soil''s complexity, the measure of soil degradation that involves the loss of soil fertility due to crop system management processes represents an unsolved problem. Exergy is a property with the potential to be used in soil fertility and/or degradation analysis. A methodology to determine the exergy value fenced in a fertile soil due to its inorganic and organic components is established in this study and will be applied to evaluate soil fertility, degradation, and quality. As a first step, the exergy of perfect topsoil with optimum characteristics called "OptSOIL" is determined. The "OptSOIL" is established by agronomic expertise and will allow establishing a general theoretical reference suitable to execute exergy assessments of soils and compare the degradation grade of any soil concerning the best possible. Consequently, we introduce a perfect fertile planetary crust made of “OptNUT” and “OptSOM” invariant and independent of the different local textures, but not independent of their water content and aeration. We call this imaginary crust -copiously fertile- Pristinia as opposed to Thanatia, a dead state referring to abiotic resources. Thus, any real agricultural soil will be an intermediate soil between Pristinia and Thanatia. This idea might serve to quantitatively diagnose an assessment of all the concepts by which soil is degraded. The methodology has been validated through laboratory agronomic tests for different soils, concluding that exergy is a rigorous indicator to measure topsoil fertility. © 2021 The Author

Exergoecology assessment of mineral exports from Latin America: Beyond a tonnage perspective

Latin America has traditionally been a raw material supplier since colonial times. In this paper, we analyze mineral exports from an exergoecology perspective from twenty countries in Latin American (LA-20). We apply material flow analysis (MFA) principles along with the concept of the exergy replacement cost (ERC), which considers both quantity and thermodynamic quality of minerals, reflecting their scarcity in the crust. ERC determines the energy that would be required to recover minerals to their original conditions in the mines once they have been totally dispersed into the Earth''s crust, with prevailing technology. Using ERC has helped us identify the importance of certain traded minerals that could be overlooked in a traditional MFA based on a mass basis only. Our method has enabled us to determine mineral balance, both in mass (tonnes) and in ERC terms (Mtoe). Using indicators, both in mass and ERC, we have assessed the self-sufficiency and dependency of the region. We have also analyzed the mineral exports flows from Latin America for 2013. Results show that half of the mineral production from LA-20 was mainly exported. High-quality minerals, such as, gold, silver, and aluminum were largely exported to China and the United States. Extraction of high-quality minerals also implies higher losses of natural stock and environmental overburdens in the region

Mining energy consumption as a function of ore grade decline: the case of lead and zinc

Demand for raw materials is increasing exponentially. To satisfy that demand, more minerals need to be mined from the Earth’s crust. As a result, minerals are being exhausted, and ore grades decline. Lower ore grade mines also mean more energy, which in turn entails fossil fuel emissions and more climate change. This paper estimates the specific energy for the beneficiation process of metals lead and zinc as case studies. The evaluation is performed with specialized software, HSC Chemistry which assesses the specific energy for every stage: comminution, flotation, and refining. Different scenarios have been established to simulate the behavior of a mine when it approaches depletion. Preliminary results show that energy consumption for lead would increase by five times when compared to the current situation if ore grades decrease until the level of tailings, while for zinc by almost two

Exergy-based assessment of polymers production and recycling: An application to the automotive sector

In the last century, the economic growth has been accompanied by a worldwide diffusion of polymers for multiple applications. However, there is a growing attention to the environmental pollution and energy consumption linked to the unconditional use of plastic. In the present work, exergy is used as a measure of the resource consumption during the life cycle of polymers. Nine commercially diffused polymers are chosen, and their production chains are identified according to the “grave to cradle” approach. The global Embodied Exergy (EE) is calculated as the sum of the contribution of each step of the chain, including the production process and the Exergy Replacement Cost (ERC) of the fossil fuel. Then, recycling routes and the associated exergy consumption are analysed. Thermodynamic recycling indexes are developed depending on the final product, namely the crude polymeric material and the oil derivatives or structural molecules. The main results show that some commonly used polymers have a considerable impact in terms of EE (e.g., PET). Recycling indexes encourage the recycling processes, which are always energetically convenient (from 10% to 60% of exergy savings) compared with the production from virgin raw material. Results from EE calculation are used for the thermodynamic assessment of the plastic content of vehicle components, to obtain useful information for recycling practices development. Copyright

Transforming AdaPT to Ada

This paper describes how the main features of the proposed Ada language extensions intended to support distribution, and offered as possible solutions for Ada9X can be implemented by transformation into standard Ada83. We start by summarizing the features proposed in a paper (Gargaro et al, 1990) which constitutes the definition of the extensions. For convenience we have called the language in its modified form AdaPT which might be interpreted as Ada with partitions. These features were carefully chosen to provide support for the construction of executable modules for execution in nodes of a network of loosely coupled computers, but flexibly configurable for different network architectures and for recovery following failure, or adapting to mode changes. The intention in their design was to provide extensions which would not impact adversely on the normal use of Ada, and would fit well in style and feel with the existing standard. We begin by summarizing the features introduced in AdaPT

Programming in a proposed 9X distributed Ada

The studies of the proposed Ada 9X constructs for distribution, now referred to as AdaPT are reported. The goals for this time period were to revise the chosen example scenario and to begin studying about how the proposed constructs might be implemented. The example scenario chosen is the Submarine Combat Information Center (CIC) developed by IBM for the Navy. The specification provided by IBM was preliminary and had several deficiencies. To address these problems, some changes to the scenario specification were made. Some of the more important changes include: (1) addition of a system database management function; (2) addition of a fourth processing unit to the standard resources; (3) addition of an operator console interface function; and (4) removal of the time synchronization function. To implement the CIC scenario in AdaPT, the decided strategy were publics, partitions, and nodes. The principle purpose for implementing the CIC scenario was to demonstrate how the AdaPT constructs interact with the program structure. While considering ways that the AdaPt constructs might be translated to Ada 83, it was observed that the partition construct could reasonably be modeled as an abstract data type. Although this gives a useful method of modeling partitions, it does not at all address the configuration aspects on the node construct