Glassy dynamics near zero temperature

We numerically study finite-dimensional spin glasses at low and zero temperature, finding evidences for (i) strong time/space heterogeneities, (ii) spontaneous time scale separation and (iii) power law distributions of flipping times. Using zero temperature dynamics we study blocking, clustering and persistence phenomena

Anticipating Future Risks of Climate-Driven Wildfires in Boreal Forests

Extreme forest fires have historically been a significant concern in Canada, the Russian Federation, the USA, and now pose an increasing threat in boreal Europe. This paper deals with application of the wildFire cLimate impacts and Adaptation Model (FLAM) in boreal forests. FLAM operates on a daily time step and utilizes mechanistic algorithms to quantify the impact of climate, human activities, and fuel availability on wildfire probabilities, frequencies, and burned areas. In our paper, we calibrate the model using historical remote sensing data and explore future projections of burned areas under different climate change scenarios. The study consists of the following steps: (i) analysis of the historical burned areas over 2001–2020; (ii) analysis of temperature and precipitation changes in the future projections as compared to the historical period; (iii) analysis of the future burned areas projected by FLAM and driven by climate change scenarios until the year 2100; (iv) simulation of adaptation options under the worst-case scenario. The modeling results show an increase in burned areas under all Representative Concentration Pathway (RCP) scenarios. Maintaining current temperatures (RCP 2.6) will still result in an increase in burned area (total and forest), but in the worst-case scenario (RCP 8.5), projected burned forest area will more than triple by 2100. Based on FLAM calibration, we identify hotspots for wildland fires in the boreal forest and suggest adaptation options such as increasing suppression efficiency at the hotspots. We model two scenarios of improved reaction times—stopping a fire within 4 days and within 24 h—which could reduce average burned forest areas by 48.6% and 79.2%, respectively, compared to projected burned areas without adaptation from 2021–2099

Improvement in the synthesis of (Z)-organylthioenynes via hydrothiolation of buta-1,3-diynes: a comparative study using NaOH or TBAOH as base

AbstractHydrothiolation of symmetrical and unsymmetrical buta-1,3-diynes with sodium organylthiolate anions in reflux, generated in situ by reacting C4H9SH with NaOH, afforded (Z)-organylthioenynes in low to good yields (25–80%). By using tetrabutylammonium hydroxide (TBAOH) as base instead of NaOH, the hydrothiolation of buta-1,3-diynes was more rapid and efficient, providing (Z)-organylthioenynes in good to excellent yields (70–95%)

Colossal dielectric constants in transition-metal oxides

Many transition-metal oxides show very large ("colossal") magnitudes of the dielectric constant and thus have immense potential for applications in modern microelectronics and for the development of new capacitance-based energy-storage devices. In the present work, we thoroughly discuss the mechanisms that can lead to colossal values of the dielectric constant, especially emphasising effects generated by external and internal interfaces, including electronic phase separation. In addition, we provide a detailed overview and discussion of the dielectric properties of CaCu3Ti4O12 and related systems, which is today's most investigated material with colossal dielectric constant. Also a variety of further transition-metal oxides with large dielectric constants are treated in detail, among them the system La2-xSrxNiO4 where electronic phase separation may play a role in the generation of a colossal dielectric constant.Comment: 31 pages, 18 figures, submitted to Eur. Phys. J. for publication in the Special Topics volume "Cooperative Phenomena in Solids: Metal-Insulator Transitions and Ordering of Microscopic Degrees of Freedom

Tracking Extended Quintessence

We study the cosmological role of a Tracking Field $\phi$ in Extended Quintessence scenarios (TEQ), where the dynamical vacuum energy driving the acceleration of the universe today is coupled with the Ricci scalar, $R$, with a term of the form $F(\phi)R/2$, where $F(\phi) = 1/8\pi G+\xi(\phi^{2}-\phi_{0}^{2})$. Tracker solutions for these NMC models, with inverse power-law potentials, possess an initial enhancement of the scalar field dynamics, named $R$-boost, caused by the Ricci scalar in the Klein-Gordon equation. During this phase the field performs a "gravitational" slow rolling which we model analytically, with energy density scaling as $(1+z)^{2}$. We evolve linear perturbations in TEQ models assuming Gaussian scale-invariant initial spectrum. We obtain significant changes in the Integrated Sachs Wolfe effect and in the acoustic peaks locations on the Cosmic Microwave Background, as well as in the turnover on the matter power spectrum. All these corrections may assume positive as well as negative values, depending on the sign of the NMC parameter $\xi$. We give analytical formulas describing all these effects. We show that they can be as large as $10 - 30$ with respect to equivalent cosmological constant and ordinary tracking Quintessence models, respecting all the existing experimental constraints on scalar-tensor theories of gravity. These results demonstrate that the next decade data will provide deep constraints on the nature of the dark energy in the Universe, as well as the structure of the theory of gravity.Comment: 24 pages including 8 figures, final version to be published in Phys.Rev.