Van der Waals interactions across stratified media

Working at the Lifshitz level, we investigate the van der Waals interactions across a series of layers with a periodic motif. We derive the complete form of the van der Waals interaction as an explicit function of the number of periodic layers. We then compare our result with an approximation based on an anisotropic-continuum representation of the stratified medium. Satisfactory agreement between discrete-layer and continuum models is reached only for thicknesses of ten or more layers.Comment: 9 pages and 4 figure

Charge Fluctuation Forces Between Stiff Polyelectrolytes in Salt Solution: Pairwise Summability Re-examined

We formulate low-frequency charge-fluctuation forces between charged cylinders - parallel or skewed - in salt solution: forces from dipolar van der Waals fluctuations and those from the correlated monopolar fluctuations of mobile ions. At high salt concentrations forces are exponentially screened. In low-salt solutions dipolar energies go as $R^{-5}$ or $R^{-4}$; monopolar energies vary as $R^{-1}$ or $\ln{R}$, where $R$ is the minimal separation between cylinders. However, pairwise summability of rod-rod forces is easily violated in low-salt conditions. Perhaps the most important result is not the derivation of pair potentials but rather the demonstration that some of these expressions may not be used for the very problems that originally motivated their derivation.Comment: 8 pages and 1 fig in ps forma

Three-body Casimir effects and non-monotonic forces

Casimir interactions are not pair-wise additive. This property leads to collective effects that we study for a pair of objects near a conducting wall. We employ a scattering approach to compute the interaction in terms of fluctuating multipoles. The wall can lead to a non-monotonic force between the objects. For two atoms with anisotropic electric and magnetic dipole polarizabilities we demonstrate that this non-monotonic effect results from a competition between two- and three body interactions. By including higher order multipoles we obtain the force between two macroscopic metallic spheres for a wide range of sphere separations and distances to the wall.Comment: 4 pages, 4 figure

Recursion relations for generalized Fresnel coefficients: Casimir force in a planar cavity

We emphasize and demonstrate that, besides using the usual recursion relations involving successive layers, generalized Fresnel coefficients of a multilayer can equivalently be calculated using the recursion relations involving stacks of layers, as introduced some time ago [M. S. Tomas, Phys. Rev. A 51, 2545 (1995)]. Moreover, since the definition of the generalized Fresnel coefficients employed does not imply properties of the stacks, these nonstandard recursion relations can be used to calculate Fresnel coefficients not only for local systems but also for a general multilayer consisting of various types (local, nonlocal, inhomogeneous etc.) of layers. Their utility is illustrated by deriving a few simple algorithms for calculating the reflectivity of a Bragg mirror and extending the formula for the Casimir force in a planar cavity to arbitrary media.Comment: 5 pages, 2 figures, slightly expande

Bond Orientational Order, Molecular Motion and Free Energy of High Density DNA Mesophases

By equilibrating condensed DNA arrays against reservoirs of known osmotic stress and examining them with several structural probes, it has been possible to achieve a detailed thermodynamic and structural characterization of the change between two distinct regions on the liquid crystalline phase digram: a higher-density hexagonally packed region with long-range bond orientational order in the plane perpendicular to the average molecular direction; and a lower-density cholesteric region with fluid-like positional order. X-rays scattering on highly ordered DNA arrays at high density and with the helical axis oriented parallel to the incoming beam showed a six-fold azimuthal modulation of the first order diffraction peak that reflects the macroscopic bond-orientational order. Transition to the less-dense cholesteric phase through osmotically controlled swelling shows the loss of this bond orientational order that had been expected from the change in optical birefringence patterns and that is consistent with a rapid onset of molecular positional disorder. This change in motion was previously inferred from intermolecular force measurements and is now confirmed by $\rm ^{31}P$ NMR. Controlled reversible swelling and compaction under osmotic stress, spanning a range of densities between $\sim 120$ mg/ml to $\sim 600$ mg/ml, allows measurement of the free energy changes throughout each phase and at the phase transition, essential information for theories of liquid-crystalline states.Comment: 14 pages, 3 figures in gif format available at http://abulafia.mgsl.dcrt.nih.gov/pics.html E-mail: [email protected]

Thermal Casimir-Polder interaction of different atoms with graphene

The thermal correction to the energy of Casimir-Polder interaction of atoms with a suspended graphene membrane described by the Dirac model is investigated. We show that a major impact on the thermal correction is made by the size of the gap in the energy spectrum of graphene quasiparticles. Specifically, if the temperature is much smaller than the gap parameter (alternatively, larger or of the order of the gap parameter), the thermal correction is shown to be relatively small (alternatively, large). We have calculated the free energy of the thermal Casimir-Polder interaction of atoms of He, Na, Rb, and Cs with graphene described by both the hydrodynamic and Dirac models. It is shown that in exact computations using the Dirac model, one should use the polarization operator at nonzero temperature. The computational results for the Casimir-Polder free energy obtained in the framework of hydrodynamic model of graphene are several times larger than in the Dirac model within the separation region below 2$\mu$m. We conclude that the theoretical predictions following from the two models can be reliably discriminated in experiments on quantum reflection of different atoms on graphene.Comment: 19 pages, 6 figures, to appear in Phys. Rev.

Comment on ``Precision measurement of the Casimir-Lifshitz force in a fluid''

Recently J.N. Munday and F. Capasso [Phys. Rev. A {\bf 75}, 060102(R) (2007); arXiv:0705.3793] claimed that they have performed a precision measurement of the Casimir force between a sphere and a plate coated with Au, both immersed in ethanol. The measurement results were claimed to be consistent with the Lifshitz theory. We demonstrate that the calculation of the Casimir force between the smooth bodies following the authors prescription has a discrepancy up to 25% with respect to authors result. We show also that the attractive electrostatic force only due to the surface potential differences was underestimated by a factor of 590 and the charge double layer interaction was not taken into account. All this leads to the conclusion that the results of this experiment are in fact uncertain.Comment: 5 pages, 1 figure, submitted to Physical Review A; corrections are made in accordance to referee's suggestion

Dispersion Interactions between Optically Anisotropic Cylinders at all Separations: Retardation Effects for Insulating and Semiconducting Single Wall Carbon Nanotubes

We derive the complete form of the van der Waals dispersion interaction between two infinitely long anisotropic semiconducting/insulating thin cylinders at all separations. The derivation is based on the general theory of dispersion interactions between anisotropic media as formulated in [J. N. Munday, D. Iannuzzi, Yu. S. Barash and F. Capasso, {\sl Phys. Rev. A} {\bf 71}, 042102 (2005)]. This formulation is then used to calculate the dispersion interactions between a pair of single walled carbon nanotubes at all separations and all angles. Non-retarded and retarded forms of the interactions are developed separately. The possibility of repulsive dispersion interactions and non-monotonic dispersion interactions is discussed within the framework of the new formulation

Measurements of the Casimir-Lifshitz force in fluids: the effect of electrostatic forces and Debye screening

In this work, we present detailed measurements of the Casimir-Lifshitz force between two gold surfaces (a sphere and a plate) immersed in ethanol and study the effect of residual electrostatic forces, which are dominated by static fields within the apparatus and can be reduced with proper shielding. Electrostatic forces are further reduced by Debye screening through the addition of salt ions to the liquid. Additionally, the salt leads to a reduction of the Casimir-Lifshitz force by screening the zero-frequency contribution to the force; however, the effect is small between gold surfaces at the measured separations and within experimental error. An improved calibration procedure is described and compared to previous methods. Finally, the experimental results are compared to Lifshitz's theory and found to be consistent for the materials used in the experiment.Comment: 11 figures. PRA in pres

Comparison of the hydrodynamic and Dirac models of the dispersion interaction between graphene and H, He∗{}^{\ast}, or Na atoms

The van der Waals and Casimir-Polder interaction of different atoms with graphene is investigated using the Dirac model which assumes that the energy of quasiparticles is linear with respect to the momentum. The obtained results for the van der Waals coefficients of hydrogen atoms and molecules and atoms of metastable He${}^{\ast}$ and Na as a function of separation are compared with respective results found using the hydrodynamic model of graphene. It is shown that, regardless of the value of the gap parameter, the Dirac model leads to much smaller values of the van der Waals coefficients than the hydrodynamic model. The experiment on quantum reflection of metastable He${}^{\ast}$ and Na atoms on graphene is proposed which is capable to discriminate between the two models of the electronic structure of graphene. In this respect the parameters of the phenomenological potential for both these atoms interacting with graphene described by different models are determined.Comment: 15 pages, 4 figure