Increase of Miscanthus Cultivation with New Roles in Materials Production—A Review

Recent changes in the EU green aims can help to overcome economic obstacles in the slow upscaling of Miscanthus cultivation. Using Miscanthus can permanently fix CO 2 within building materials thereby aiding the EU climate goals with the increased use of regrowing materials, as well as carbon fixation. Economic obstacles in the slow upscaling of Miscanthus cultivation are targeted by recent changes in the greening aims in the EU. Miscanthus can fulfill a valuable dual function in aiding the EU climate goals by achieving permanent CO 2 fixation within building materials. In contrast to energetic use, persistent applications create stable markets allowing for a reduced risk in the establishment of long term cultured perennial crops. However, the development of different building materials requires an understanding of the combination of the biological and technical aspects. This work presents an overview of the development of the general aspects for the agricultural product Miscanthus and the scientifically reported developments of Miscanthus used as feedstock in polymers, particle boards, and cementitious materials. While the product performance can be evaluated, the understanding of the influence by the input biomass as a main contributor to the product performance needs to be reinforced to be successful with a goal-oriented development of Miscanthus based products. The key feedstock parameters governing the technical performance of the materials are identified and the knowledge gaps are described

Cup Plant (Silphium perfoliatum L.) Biomass as Substitute for Expanded Polystyrene in Bonded Leveling Compounds

Biomass for non-food applications is considered as a substitute for petro-based materials such as expanded polystyrene (EPS). This research analyzes physical properties of an EPS containing commercial bonded leveling compound (BLC) which was substituted with cup plant (Silphium perfoliatum L.) biomass. Cup plant is a high-yielding biomass plant with several ecological benefits that is yet mainly used for biogas production. Furthermore, the high amount of parenchyma in senescent biomass with its EPS-like structure could be a possible substitute for petrochemical foams in lightweight aggregates. The natural variation in parenchyma content of several European cup plant accessions is promising, regarding the development of cultivars with suitable biomass properties for the proposed material use. Two binders with different proportions of cup plant and EPS were used to produce samples of BLC for thermal conductivity and compression strength tests. The compression strength of 0.92 N mm−2 and a thermal conductivity of 84 mW m−1 K−1 were analyzed and comparable to the commercial BLC. The thermal conductivity within the tested borders appears nearly independent of the biomass content. With increasing cup plant content, the shape characteristics of the lightweight aggregate mix changes towards more elongated aggregates. The mechanical strength and thermal conductivity are highly sensitive to the water demand of the biomass. Direct partial substitution of EPS by cup plant appears feasible and could be a part of the decarbonization of the construction sector

Lignins Isolated via Catalyst-Free Organosolv Pulping from Miscanthus x giganteus, M. sinensis, M. robustus and M. nagara: A Comparative Study

As a low-input crop, Miscanthus offers numerous advantages that, in addition to agricultural applications, permits its exploitation for energy, fuel, and material production. Depending on the Miscanthus genotype, season, and harvest time as well as plant component (leaf versus stem), correlations between structure and properties of the corresponding isolated lignins differ. Here, a comparative study is presented between lignins isolated from M. x giganteus, M. sinensis, M. robustus and M. nagara using a catalyst-free organosolv pulping process. The lignins from different plant constituents are also compared regarding their similarities and differences regarding monolignol ratio and important linkages. Results showed that the plant genotype has the weakest influence on monolignol content and interunit linkages. In contrast, structural differences are more significant among lignins of different harvest time and/or season. Analyses were performed using fast and simple methods such as nuclear magnetic resonance (NMR) spectroscopy. Data was assigned to four different linkages (A: β-O-4 linkage, B: phenylcoumaran, C: resinol, D: β-unsaturated ester). In conclusion, A content is particularly high in leaf-derived lignins at just under 70% and significantly lower in stem and mixture lignins at around 60% and almost 65%. The second most common linkage pattern is D in all isolated lignins, the proportion of which is also strongly dependent on the crop portion. Both stem and mixture lignins, have a relatively high share of approximately 20% or more (maximum is M. sinensis Sin2 with over 30%). In the leaf-derived lignins, the proportions are significantly lower on average. Stem samples should be chosen if the highest possible lignin content is desired, specifically from the M. x giganteus genotype, which revealed lignin contents up to 27%. Due to the better frost resistance and higher stem stability, M. nagara offers some advantages compared to M. x giganteus. Miscanthus crops are shown to be very attractive lignocellulose feedstock (LCF) for second generation biorefineries and lignin generation in Europe

Miscanthus x giganteus Stem Versus Leaf-Derived Lignins Differing in Monolignol Ratio and Linkage

As a renewable, Miscanthus offers numerous advantages such as high photosynthesis activity (as a C4 plant) and an exceptional CO2 fixation rate. These properties make Miscanthus very attractive for industrial exploitation, such as lignin generation. In this paper, we present a systematic study analyzing the correlation of the lignin structure with the Miscanthus genotype and plant portion (stem versus leaf). Specifically, the ratio of the three monolignols and corresponding building blocks as well as the linkages formed between the units have been studied. The lignin amount has been determined for M. x giganteus (Gig17, Gig34, Gig35), M. nagara (NagG10), M. sinensis (Sin2), and M. robustus (Rob4) harvested at different time points (September, December, and April). The influence of the Miscanthus genotype and plant component (leaf vs. stem) has been studied to develop corresponding structure-property relationships (i.e., correlations in molecular weight, polydispersity, and decomposition temperature). Lignin isolation was performed using non-catalyzed organosolv pulping and the structure analysis includes compositional analysis, Fourier transform infradred (FTIR), ultraviolet/visible (UV-Vis), hetero-nuclear single quantum correlation nuclear magnetic resonsnce (HSQC-NMR), thermogravimetric analysis (TGA), and pyrolysis gaschromatography/mass spectrometry (GC/MS). Structural differences were found for stem and leaf-derived lignins. Compared to beech wood lignins, Miscanthus lignins possess lower molecular weight and narrow polydispersities (<1.5 Miscanthus vs. >2.5 beech) corresponding to improved homogeneity. In addition to conventional univariate analysis of FTIR spectra, multivariate chemometrics revealed distinct differences for aromatic in-plane deformations of stem versus leaf-derived lignins. These results emphasize the potential of Miscanthus as a low-input resource and a Miscanthus-derived lignin as promising agricultural feedstock

Comparing chemical composition and lignin structure of Miscanthus x giganteus and Miscanthus nagara harvested in autumn and spring and separated into stems and leaves

Miscanthus crops possess very attractive properties such as high photosynthesis yield and carbon fixation rate. Because of these properties, it is currently considered for use in second-generation biorefineries. Here we analyze the differences in chemical composition between M. x giganteus, a commonly studied Miscanthus genotype, and M. nagara, which is relatively understudied but has useful properties such as increased frost resistance and higher stem stability. Samples of M. x giganteus (Gig35) and M. nagara (NagG10) have been separated by plant portion (leaves and stems) in order to isolate the corresponding lignins. The organosolv process was used for biomass pulping (80% ethanol solution, 170 °C, 15 bar). Biomass composition and lignin structure analysis were performed using composition analysis, Fourier-transform infrared (FTIR), ultraviolet-visible (UV-Vis) and nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis (TGA), size exclusion chromatography (SEC) and pyrolysis gas-chromatography/mass spectrometry (Py-GC/MS) to determine the 3D structure of the isolated lignins, monolignol ratio and most abundant linkages depending on genotype and harvesting season. SEC data showed significant differences in the molecular weight and polydispersity indices for stem versus leaf-derived lignins. Py-GC/MS and hetero-nuclear single quantum correlation (HSQC) NMR revealed different monolignol compositions for the two genotypes (Gig35, NagG10). The monolignol ratio is slightly influenced by the time of harvest: stem-derived lignins of M. nagara showed increasing H and decreasing G unit content over the studied harvesting period (December–April)