Universal amplitude in density-force relations for polymer chains in confined geometries: Massive field theory approach

The universal density-force relation is analyzed and the correspondent universal amplitude ratio $B_{real}$ is obtained using the massive field theory approach in fixed space dimensions d=3 up to one-loop order. The layer monomer density profiles of ideal chains and real polymer chains with excluded volume interaction in a good solvent between two parallel repulsive walls, one repulsive and one inert wall are obtained. Besides, taking into account the Derjaguin approximation the layer monomer density profiles for dilute polymer solution confined in semi-infinite space containing mesoscopic spherical particle of big radius are calculated. The last mentioned situation is analyzed for both cases when wall and particle are repulsive and for the mixed case of repulsive wall and inert particle. The obtained results are in good agreement with previous theoretical results and with the results of Monte Carlo simulations.Comment: 11 pages, 3 figure

Surface critical behavior of random systems at the special transition

We study the surface critical behavior of semi-infinite quenched random Ising-like systems at the special transition using three dimensional massive field theory up to the two-loop approximation. Besides, we extend up to the next-to leading order, the previous first-order results of the $\sqrt{\epsilon}$ expansion obtained by Ohno and Okabe [Phys. Rev. B 46, 5917 (1992)]. The numerical estimates for surface critical exponents in both cases are computed by means of the Pade analysis. Moreover, in the case of the massive field theory we perform Pade-Borel resummation of the resulting two-loop series expansions for surface critical exponents. The obtained results confirm that in a system with quenched bulk randomness the plane boundary is characterized by a new set of surface critical exponents.Comment: 14 pages, 10 figure

Non-additive properties of finite 1D Ising chains with long-range interactions

We study the statistical properties of Ising spin chains with finite (although arbitrary large) range of interaction between the elements. We examine mesoscopic subsystems (fragments of an Ising chain) with the lengths comparable with the interaction range. The equivalence of the Ising chains and the multi-step Markov sequences is used for calculating different non-additive statistical quantities of a chain and its fragments. In particular, we study the variance of fluctuating magnetization of fragments, magnetization of the chain in the external magnetic field, etc. Asymptotical expressions for the non-additive energy and entropy of the mesoscopic fragments are derived in the limiting cases of weak and strong interactions.Comment: 20 pages, 4 figure

Field theoretical analysis of adsorption of polymer chains at surfaces: Critical exponents and Scaling

The process of adsorption on a planar repulsive, "marginal" and attractive wall of long-flexible polymer chains with excluded volume interactions is investigated. The performed scaling analysis is based on formal analogy between the polymer adsorption problem and the equivalent problem of critical phenomena in the semi-infinite $|\phi|^4$ n-vector model (in the limit $n\to 0$) with a planar boundary. The whole set of surface critical exponents characterizing the process of adsorption of long-flexible polymer chains at the surface is obtained. The polymer linear dimensions parallel and perpendicular to the surface and the corresponding partition functions as well as the behavior of monomer density profiles and the fraction of adsorbed monomers at the surface and in the interior are studied on the basis of renormalization group field theoretical approach directly in d=3 dimensions up to two-loop order for the semi-infinite $|\phi|^4$ n-vector model. The obtained field- theoretical results at fixed dimensions d=3 are in good agreement with recent Monte Carlo calculations. Besides, we have performed the scaling analysis of center-adsorbed star polymer chains with $f$ arms of the same length and we have obtained the set of critical exponents for such system at fixed d=3 dimensions up to two-loop order.Comment: 22 pages, 12 figures, 4 table