1,344 research outputs found
Methanation of CO over Ni catalyst: A theoretical study
Theoretical methods (generalized valence‐bond calculations) were used to examine the bond energies and geometries of numerous species chemisorbed onto Ni clusters representing Ni surface. These results were used to obtain thermochemical information and to examine various mechanisms for the methanation of CO over Ni: CO+3H^(→)_(2(Ni)) CH_4+H_2O. It is found that chemisorbed formyl radicals (Ni–CHO) lead to a favorably appearing chain reaction that is consistent with current experimental results. In addition, we find a chemisorbed C_2 species that may be the catalytically active C_(ad) formed from dissociation of CO
Theoretical studies of nickel clusters and chemisorption of hydrogen
First principles calculations of high- and low-symmetry clusters (up to Ni87) are reported. Macroscopic properties [ionization potential (IP), electron affinity (EA), and bandwidth] are not sensitive to cluster symmetry and, except for EA, are converged to bulk values by Ni87. Even for Ni87 the EA is over 2.5 eV smaller than the IP; the origin of this effect is discussed. The chemisorption of hydrogen is considered on the low-symmetry clusters, where it is found that threefold and fourfold sites are most favored with bond energies of [angle]3 eV for both types of sites. Geometries are not cluster sensitive with R (NiH) values of 1.57, 1.62, and 1.78 Å for twofold, threefold, and fourfold sites, respectively. Vibrational frequencies for these sites are 1420, 1212, and 592 cm^–1, respectively
Surface effects on the orbital order in the single layered manganite La0.5Sr1.5MnO4
We report the first observation of `orbital truncation rods' -- the
scattering arising from the termination of bulk orbital order at the surface of
a crystal. The x-ray measurements, performed on a cleaved, single-layered
perovskite, La0.5Sr1.5MnO4, reveal that while the crystallographic surface is
atomically smooth, the orbital `surface' is much rougher, with an r.m.s.
deviation from the average `surface' of ~0.7nm. The temperature dependence of
this scattering shows evidence of a surface-induced second order transition.Comment: 13 pages, 4 figure
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Interacting crumpled manifolds
In this article we study the effect of a delta-interaction on a polymerized
membrane of arbitrary internal dimension D. Depending on the dimensionality of
membrane and embedding space, different physical scenarios are observed. We
emphasize on the difference of polymers from membranes. For the latter,
non-trivial contributions appear at the 2-loop level. We also exploit a
``massive scheme'' inspired by calculations in fixed dimensions for scalar
field theories. Despite the fact that these calculations are only amenable
numerically, we found that in the limit of D to 2 each diagram can be evaluated
analytically. This property extends in fact to any order in perturbation
theory, allowing for a summation of all orders. This is a novel and quite
surprising result. Finally, an attempt to go beyond D=2 is presented.
Applications to the case of self-avoiding membranes are mentioned
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