Properties and Catalytic Effects of Nanoparticles Synthesized by Levitational Gas Condensation

One of the gas-phased methods of the levitational gas condensation (LGC) process was developed to obtain nanopowders with high purity. The instrument designed by unique concept using magnetically levitated melted droplet of metal is easily operated to synthesize nanopowder with highly defected surface. The complex compounds are also easily prepared using micron powder feeding (MPF) system in the instrument. The metals, ceramics, and carbon-coated metal nanoparticles prepared using the LGC are introduced in this chapter. Various applications such as magnetic and catalytic properties are also introduced. Nanoparticles prepared using LGC showed significantly enhanced catalytic activities during chemical reaction due to the high level of defects on their surface structure. The new heterogeneous catalysts of the solid nanoparticles were introduced in this chapter

Analyses of Ferrous and Ferric State in Dynabi Tab

Antianemic medicament ferrous gluconate, ferrous fumarate, and a Dynabi tablet with a basic iron bearing ingredient were studied with the use of Mössbauer spectroscopy. Room temperature spectra of ferrous gluconate gave clear evidence that the two phases of iron were present: ferrous (Fe2+) as a major one with a contribution at and above 91 a.u.% and ferric (Fe3+) whose contribution was found to be ~9 a.u.%. In the case of ferrous fumarate, a single phase was measured corresponding to ferrous (Fe2+) state. A Dynabi tablet consists of ferrous fumarate and ferrous fumarate. The ferric phase in ferrous gluconate is able to be reached about ~3.6 a.u.% in a tablet

Dissociating stable nitrogen molecules under mild conditions by cyclic strain engineering

All quiet on the nitrogen front. The dissociation of stable diatomic nitrogen molecules (N-2) is one of the most challenging tasks in the scientific community and currently requires both high pressure and high temperature. Here, we demonstrate that N-2 can be dissociated under mild conditions by cyclic strain engineering. The method can be performed at a critical reaction pressure of less than 1 bar, and the temperature of the reaction container is only 40 degrees C. When graphite was used as a dissociated N* receptor, the normalized loading of N to C reached as high as 16.3 at/at %. Such efficient nitrogen dissociation is induced by the cyclic loading and unloading mechanical strain, which has the effect of altering the binding energy of N, facilitating adsorption in the strain-free stage and desorption in the compressive strain stage. Our finding may lead to opportunities for the direct synthesis of N-containing compounds from N-2

Synthesis of the SUS 316L Powders with a Nano-Meso Bi-Modal Structure

Pure stainless steel (SUS 316L) powders with both a nano-grain and micro-structure were prepared using a mechanical milling process. The bimodal microstructure consists of a nano-grain with a size of 50 nm in the surface region and microstructure in the core of the particle. The nano-grain with a bcc structure at the surface and the microstructure of fcc in the core of the particles were prepared by milling at 150rpm for 9h, and those compositions were 14.39% for the nano structure and 85.61% for the micro structure, respectively. Spark plasma sintering (SPS) was carried out for the compaction of the powders. The compacts forming powders with a bi-modal structure have a mesoscopic structure

Synthesis and Magnetic Properties of Ni and Carbon Coated Ni by Levitational Gas Condensation (LGC)

The nickel (Ni), and carbon coated nickel (Ni@C) nanoparticles were synthesized by levitaional gas condensation (LGC) methods using a micron powder feeding (MPF) system. Both metal and carbon coated metal nano powders include a magnetic ordered phase. The synthesis by LGC yields spherical particles with a large coercivity. The abnormal initial magnetization curve for Ni indicates a non-collinear magnetic structure between the core and surface layer of the particles. The carbon coated particles had a core structure diameter at and below 10 nm and were covered by 2-3 nm thin carbon layers. The hysteresis loop of the as-prepared Ni@Cs materials with unsaturated magnetization shows a superparamagnetic state at room temperature

SYNTHESIS FOR NANOFLOWER AND ROD OF ZnO BY A SURFACTANT FREE AND LOW TEMPERATURE METHOD

ZnO with 2D flower-like and 1D rod shape were obtained from simple and rapid hydrolysis of Zn nanopowder. The Zn nanopowders were incorporated into distilled water with acetic acid and then the solution was stirred at 60°C for 8 h. The nanoflower-like and rod shape were formed without any surfactant. It seems that the acetic acid played a role of controlling PH and etching the oxide layer on the surface of metal nanopowders to enhance rapid reaction with distilled water. X-ray diffraction patterns for all samples exhibited that the resultant precipitates were completely transformed to ZnO powder. It is clearly observed that the morphological changes of ZnO with reaction time in aqueous solution follows chestnut bur → flower → tetrahedron → rod sequences during the hydrolysis reaction.ZnO, nanorod, hydrolysis

Photocatalytic Characterization of Fe- and Cu-Doped ZnO Nanorods Synthesized by Cohydrolysis

Fe- and Cu-doped ZnO nanorods have been synthesized by a novel process employing a hydrolysis of metal powders. Zn, Fe, and Cu nanopowders were used as starting materials and incorporated into distilled water. The solution was refluxed at 60°C for 24 h to obtain the precipitates from the hydrolysis of Zn and dopants (Cu and Fe). The TEM results for ZnO with and without metal doping showed that the produced powders had a rod-like shape. The rod shape was attributable to the zinc oxide from the hydrolysis of Zn. With an increasing doping content, the UV-vis spectra were shifted to a long wavelength and this result indicates that the band gap was changed by the metal doping. The values of phenol degrading Fe- and Cu-doped ZnO by a solar simulator were measured to be 60 and 75%, respectively