5 research outputs found

    Anomalous magnetic ordering in PrBa_2Cu_3O_{7-y} single crystals: Evidence for magnetic coupling between the Cu and Pr sublattices

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    In Al-free PrBa_2Cu_3O_{7-y} single crystals the kink in the temperature dependence of magnetic susceptibility chi_{ab}(T), connected with Pr antiferromagnetic ordering, disappears after field cooling (FC) in a field H || ab-plane. The kink in chi_c(T) remains unchanged after FC in H || c-axis. As a possible explanation, freezing of the Cu magnetic moments, lying in the ab-plane, caused by FC in H || ab, hinders their reorientation and, due to coupling between the Pr and Cu(2) sublattices, ordering of the Pr^{3+} moments. A field induced phase transition and a field dependence of the Pr^{3+} ordering temperature have been found for both H || c and H || ab.Comment: 11 pages (LaTex with elsart.sty), 5 EPS figs. Accepted to Physica

    Дисбаланс Ρ†ΠΈΠ½ΠΊΠ° ΠΈ ΠΌΠ΅Π΄ΠΈ Ρƒ Π΄Π΅Ρ‚Π΅ΠΉ с синдромом Π΄Π΅Ρ„ΠΈΡ†ΠΈΡ‚Π° внимания ΠΈ гипСрактивности

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    The objective of the study was investigation of serum zinc (Zn) and copper (Cu) levels in blood serum, urine, and hair of preschool and primary school aged children with attention deficit/hyperactivity (ADHD) syndrome. A total of 50 children aged 4-9 y.o. with ADHD as well as 50 neurotypical controls were involved in the study. Assessment of serum Zn and Cu levels was performed using ICP-MS. It is demonstrated that children with ADHD are characterized by a significant 8% ( p = 0.001) decrease in serum Zn levels. In the case of hair, copper levels were 16% ( p = 0.039) lower than the control values. Urinary metal concentrations were relatively stable. Serum Cu/Zn ratio in ADHD exceeded the control values by 12% ( p = 0.003). The observed 15% decrease in urinary Cu/Zn ratio was nearly significant ( p = 0.080), being indicative of predominant increase in zinc excretion in comparison to copper. In regression models adjusted for age, gender, body weight and height, hair Zn ( Ξ² = -0.277; p = 0.027) and Cu/Zn ratio ( Ξ² = -0.536; p = 0.008), as well as urinary Zn levels ( Ξ² = 0.418; p = 0.049) were significantly associated with ADHD. Therefore, the obtained data indicate the potential role of zinc deficiency in ADHD, with increased zinc loss being considered as the potential factor leading to reduced Zn status.ЦСлью настоящСго исслСдования явилось ΠΎΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½ΠΈΠ΅ уровня Ρ†ΠΈΠ½ΠΊΠ° ΠΈ ΠΌΠ΅Π΄ΠΈ Π² сывороткС ΠΊΡ€ΠΎΠ²ΠΈ, ΠΌΠΎΡ‡Π΅ ΠΈ волосах Π΄Π΅Ρ‚Π΅ΠΉ с синдромом Π΄Π΅Ρ„ΠΈΡ†ΠΈΡ‚Π° внимания ΠΈ гипСрактивности (Π‘Π”Π’Π“) дошкольного ΠΈ Ρ€Π°Π½Π½Π΅Π³ΠΎ школьного возраста. Π’ исслСдовании приняли участиС 50 Π΄Π΅Ρ‚Π΅ΠΉ с Π‘Π”Π’Π“ (4-9 Π»Π΅Ρ‚), Π° Ρ‚Π°ΠΊΠΆΠ΅ 50 Π·Π΄ΠΎΡ€ΠΎΠ²Ρ‹Ρ… Π΄Π΅Ρ‚Π΅ΠΉ. ΠšΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠΈ Ρ†ΠΈΠ½ΠΊΠ° ΠΈ ΠΌΠ΅Π΄ΠΈ Π² сывороткС ΠΊΡ€ΠΎΠ²ΠΈ, ΠΌΠΎΡ‡Π΅ ΠΈ волосах опрСдСляли ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠΌ масс-спСктромСтрии с ΠΈΠ½Π΄ΡƒΠΊΡ‚ΠΈΠ²Π½ΠΎ-связанной ΠΏΠ»Π°Π·ΠΌΠΎΠΉ. УстановлСно, Ρ‡Ρ‚ΠΎ Π΄Π΅Ρ‚ΠΈ, ΡΡ‚Ρ€Π°Π΄Π°ΡŽΡ‰ΠΈΠ΅ Π‘Π”Π’Π“, Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€ΠΈΠ·ΡƒΡŽΡ‚ΡΡ достовСрным 8% ( p = 0,001) сниТСниСм уровня Ρ†ΠΈΠ½ΠΊΠ° Π² сывороткС ΠΊΡ€ΠΎΠ²ΠΈ. Π£Ρ€ΠΎΠ²Π΅Π½ΡŒ ΠΌΠ΅Π΄ΠΈ Π² волосах Π΄Π΅Ρ‚Π΅ΠΉ с Π‘Π”Π’Π“ характСризовался достовСрным 16% ( p = 0,039) сниТСниСм ΠΏΠΎ ΡΡ€Π°Π²Π½Π΅Π½ΠΈΡŽ с ΠΊΠΎΠ½Ρ‚Ρ€ΠΎΠ»ΡŒΠ½Ρ‹ΠΌΠΈ показатСлями. Π‘ΠΎΠ΄Π΅Ρ€ΠΆΠ°Π½ΠΈΠ΅ ΠΌΠ΅Ρ‚Π°Π»Π»ΠΎΠ² Π² ΠΌΠΎΡ‡Π΅ являлось ΠΎΡ‚Π½ΠΎΡΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ ΡΡ‚Π°Π±ΠΈΠ»ΡŒΠ½Ρ‹ΠΌ. ЗначСния ΡΠΎΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΡ Cu/Zn Π² сывороткС ΠΊΡ€ΠΎΠ²ΠΈ ΠΏΠ°Ρ†ΠΈΠ΅Π½Ρ‚ΠΎΠ² с Π‘Π”Π’Π“ ΠΏΡ€Π΅Π²Ρ‹ΡˆΠ°Π»ΠΈ ΠΊΠΎΠ½Ρ‚Ρ€ΠΎΠ»ΡŒΠ½Ρ‹Π΅ ΠΏΠΎΠΊΠ°Π·Π°Ρ‚Π΅Π»ΠΈ Π½Π° 12% ( p = 0,003). НаблюдаСмоС 15%-Π½ΠΎΠ΅ сниТСниС Π·Π½Π°Ρ‡Π΅Π½ΠΈΠΉ ΡΠΎΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΡ Cu/Zn Π² ΠΌΠΎΡ‡Π΅ ΠΏΡ€ΠΈΠ±Π»ΠΈΠΆΠ°Π»ΠΎΡΡŒ ΠΊ достовСрному ( p = 0,080), Ρ‡Ρ‚ΠΎ ΠΌΠΎΠΆΠ΅Ρ‚ ΡΠ²Π»ΡΡ‚ΡŒΡΡ ΠΎΡ‚Ρ€Π°ΠΆΠ΅Π½ΠΈΠ΅ΠΌ прСимущСствСнной экскрСции Ρ†ΠΈΠ½ΠΊΠ° ΠΏΠΎ ΡΡ€Π°Π²Π½Π΅Π½ΠΈΡŽ с мСдью. Π’ рСгрСссионной ΠΌΠΎΠ΄Π΅Π»ΠΈ послС ΠΏΠΎΠΏΡ€Π°Π²ΠΊΠΈ Π½Π° Π²Π°Ρ€ΠΈΠ°Π±Π΅Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ ΠΏΠΎΠ»Π°, возраста, массы Ρ‚Π΅Π»Π° ΠΈ роста Π΄Π΅Ρ‚Π΅ΠΉ содСрТаниС Ρ†ΠΈΠ½ΠΊΠ° ( Ξ² = -0,277; p = 0,027) ΠΈ ΡΠΎΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΠ΅ Cu/Zn ( Ξ² = -0,536; p = 0,008) Π² волосах, Π° Ρ‚Π°ΠΊΠΆΠ΅ ΡƒΡ€ΠΎΠ²Π΅Π½ΡŒ Zn Π² ΠΌΠΎΡ‡Π΅ ( Ξ² = 0,418; p = 0,049) Π±Ρ‹Π»ΠΈ достовСрно связаны с Π½Π°Π»ΠΈΡ‡ΠΈΠ΅ΠΌ Π‘Π”Π’Π“. Π Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½Π½ΠΎΠ³ΠΎ исслСдования ΡƒΠΊΠ°Π·Ρ‹Π²Π°ΡŽΡ‚ Π½Π° Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΡƒΡŽ Ρ€ΠΎΠ»ΡŒ Π΄Π΅Ρ„ΠΈΡ†ΠΈΡ‚Π° Ρ†ΠΈΠ½ΠΊΠ° Π² Ρ€Π°Π·Π²ΠΈΡ‚ΠΈΠΈ Π‘Π”Π’Π“, ΠΏΡ€ΠΈΡ‡Π΅ΠΌ Π² качСствС ΠΎΠ΄Π½ΠΎΠΉ ΠΈΠ· ΠΏΡ€ΠΈΡ‡ΠΈΠ½ Π΄Π΅Ρ„ΠΈΡ†ΠΈΡ‚Π° ΠΌΠΎΠΆΠ΅Ρ‚ Ρ€Π°ΡΡΠΌΠ°Ρ‚Ρ€ΠΈΠ²Π°Ρ‚ΡŒΡΡ интСнсификация экскрСции ΠΌΠ΅Ρ‚Π°Π»Π»Π°

    SOLVENT EXTRACTION AND SPECTROPHOTOMETRIC METHODS FOR THE DETERMINATION OF SOME TOXIC METAL IONS

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