Canonical Discretization. I. Discrete faces of (an)harmonic oscillator

A certain notion of canonical equivalence in quantum mechanics is proposed. It is used to relate quantal systems with discrete ones. Discrete systems canonically equivalent to the celebrated harmonic oscillator as well as the quartic and the quasi-exactly-solvable anharmonic oscillators are found. They can be viewed as a translation-covariant discretization of the (an)harmonic oscillator preserving isospectrality. The notion of the $q-$deformation of the canonical equivalence leading to a dilatation-covariant discretization preserving polynomiality of eigenfunctions is also presented.Comment: 29 pages, LaTe

One-electron atomic-molecular ions containing Lithium in a strong magnetic field

The one-electron Li-containing Coulomb systems of atomic type $(li, e)$ and molecular type $(li, li, e)$, $(li, \alpha, e)$ and $(li, p, e)$ are studied in the presence of a strong magnetic field $B \leq 10^{7}$ a.u. in the non-relativistic framework. They are considered at the Born-Oppenheimer approximation of zero order (infinitely massive centers) within the parallel configuration (molecular axis parallel to the magnetic field). The variational and Lagrange-mesh methods are employed in complement to each other. It is demonstrated that the molecular systems ${\rm LiH}^{3+}$, ${\rm LiHe}^{4+}$ and ${\rm Li}_{2}^{5+}$ can exist for sufficiently strong magnetic fields $B \gtrsim 10^{4}$ a.u. and that ${\rm Li}_{2}^{5+}$ can even be stable at magnetic fields typical of magnetars.Comment: 22 pages, 9 figures, 4 table

Particular Integrability and (Quasi)-exact-solvability

A notion of a particular integrability is introduced when two operators commute on a subspace of the space where they act. Particular integrals for one-dimensional (quasi)-exactly-solvable Schroedinger operators and Calogero-Sutherland Hamiltonians for all roots are found. In the classical case some special trajectories for which the corresponding particular constants of motion appear are indicated.Comment: 13 pages, typos correcte

The HeH+HeH^+ molecular ion in a magnetic field

A detailed study of the low-lying electronic states {}^1\Si,{}^3\Si,{}^3\Pi,{}^3\De of the $\rm{HeH}^+$ molecular ion in parallel to a magnetic field configuration (when \al-particle and proton are situated on the same magnetic line) is carried out for $B=0-4.414\times 10^{13}$ G in the Born-Oppenheimer approximation. The variational method is employed using a physically adequate trial function. It is shown that the parallel configuration is stable with respect to small deviations for \Si-states. The quantum numbers of the ground state depend on the magnetic field strength. The ground state evolves from the spin-singlet {}^1\Si state for small magnetic fields $B\lesssim 0.5$ a.u. to the spin-triplet {}^3\Si unbound state for intermediate fields and to the spin-triplet strongly bound $^3\Pi$ state for $B \gtrsim 15$ a.u. When the $\rm{HeH}^+$ molecular ion exists, it is stable with respect to a dissociation.Comment: 13 pages, 5 figures, 4 table

A note about the ground state of the H3+{\rm H}_3^+ hydrogen molecular ion

Three simple $7-, (7+3)-, 10-$parametric trial functions for the ${\rm H}_3^+$ molecular ion are presented. Each of them provides subsequently the most accurate approximation for the Born-Oppenheimer ground state energy among several-parametric trial functions. These trial functions are chosen following a criterion of physical adequacy and includes the electronic correlation in the exponential form $\sim\exp{(\gamma r_{12})}$, where $\gamma$ is a variational parameter. The Born-Oppenheimer energy is found to be $E=-1.340 34, -1.340 73, -1.341 59$\,a.u., respectively, for optimal equilateral triangular configuration of protons with the equilibrium interproton distance $R=1.65$\,a.u. The variational energy agrees in three significant digits (s.d.) with most accurate results available at present as well as for major expectation values.Comment: 12 pages, 1 figure, 3 table

H3++H_3^{++} molecular ions can exist in strong magnetic fields

Using the variational method it is shown that for magnetic fields $B\geq 10^{11}$ G there can exist a molecular ion $H_3^{++}$.Comment: LaTeX, 7 pp, 1 table, 4 figures. Title modified. Consideration of the longitudinal size of the system was adde

The H2+_2^+ molecular ion: a solution

Combining the WKB expansion at large distances and Perturbation Theory at small distances it is constructed a compact uniform approximation for eigenfunctions. For lowest states 1s\si_{g} and 2p\si_{u} this approximation provides the relative accuracy $\lesssim 10^{-5}$ (5 s.d.) for any real $x$ in eigenfunctions and for total energy $E(R)$ it gives 10-11 s.d. for internuclear distances $R \in [0,50]$. Corrections to proposed approximations are evaluated. Separation constants and the oscillator strength for the transition 1s\si_{g} \rar 2p\si_{u} are calculated and compared with existing data.Comment: 16 pages, 4 figures, 6 tables, typos are corrected and small additions are inserted, to be published at JPB (fast track comm

Charged Hydrogenic, Helium and Helium-Hydrogenic Molecular Chains in a Strong Magnetic Field

A non-relativistic classification of charged molecular hydrogenic, helium and mixed helium-hydrogenic chains with one or two electrons which can exist in a strong magnetic field $B \lesssim 10^{16}$G is given. It is shown that for both $1e-2e$ cases at the strongest studied magnetic fields the longest hydrogenic chain contains at most five protons indicating to the existence of the $\rm{H}_5^{4+}$ and $\rm{H}_5^{3+}$ ions, respectively. In the case of the helium chains the longest chains can exist at the strongest studied magnetic fields with three and four \al-particles for $1e-2e$ cases, respectively. For mixed helium-hydrogenic chains the number of heavy centers can reach five for highest magnetic fields studied. In general, for a fixed magnetic field two-electron chains are more bound than one-electron ones.Comment: 32 pages, 2 figures, 9 table

The H2+_2^+ ion in a strong magnetic field. Lowest excited states

As a continuation of our previous work ({\it Phys. Rev. A68, 012504 (2003)}) an accurate study of the lowest 1\si_g and the low-lying excited 1\si_u, 2\si_g, $1\pi_{u,g}$, 1\de_{g,u} electronic states of the molecular ion $H_2^+$ is made. Since the parallel configuration where the molecular axis coincides with the magnetic field direction is optimal, this is the only configuration which is considered. The variational method is applied and the {\it same} trial function is used for different magnetic fields. The magnetic field ranges from $10^9 G$ to $4.414 \times 10^{13} G$ where non-relativistic considerations are justified. Particular attention is paid to the 1\si_u state which was studied for an arbitrary inclination. For this state a one-parameter vector potential is used which is then variationally optimized.Comment: 25 pages, 2 figure

Hydrogen atom in a magnetic field: The quadrupole moment

The quadrupole moment of a hydrogen atom in a magnetic field for field strengths from 0 to 4.414e13 G is calculated by two different methods. The first method is variational, and based on a single trial function. The second method deals with a solution of the Schroedinger equation in the form of a linear combination of Landau orbitals.Comment: 4 pages, 1 figure, 1 table; RevTeX. Final (proofs-stage) version of the text; corrected numbers in Table 1 and in Eq.(15