3,780 research outputs found
Origin of superconducting carriers in "non-doped" T'- (La,RE)2CuO4 (RE = Sm, Eu, Gd, Tb, Lu, and Y) prepared by molecular beam epitaxy
We have performed a systematic investigation of the variations of the lattice
constants with substituent rare-earth element concentration x in the nominally
undoped superconductors T'-(La3+)2-x(RE3+)xCuO4 (RE = Sm, Eu, Gd, Tb, Lu, and
Y), which we have recently discovered using MBE. The results show both the
in-plane and out-of-plane lattice constants (a0 and c0) linearly decrease with
x, whose extrapolation to x = 2 agrees well with the reported a0 and c0 values
for each T'-RE2CuO4. This behavior is what one would expect simply from the
ionic size difference between La3+ and RE3+. The absence of the Cu-O bond
stretching due to electron-doping, which is commonly observed in electron-doped
T' and infinite-layer superconductors, implies that electron doping via oxygen
deficiencies is, at least, not a main source of charge carriers.Comment: proceedings of ISS 200
Superconductivity in undoped T' cuprates with Tc over 30 K
Undoped cuprates have long been considered to be antiferromagnetic
insulators. In this article, however, we report that superconductivity is
achieved in undoped T'-RE2CuO4 (RE = Pr, Nd, Sm, Eu, and Gd). Our discovery was
performed by using metal-organic decomposition (MOD), an inexpensive and
easy-to-implement thin-film process. The keys to prepare the superconducting
films are firing with low partial-pressure of oxygen and reduction at low
temperatures. The highest Tc of undoped T'-RE2CuO4 is over 30 K, substantially
higher than "electron-doped" analogs. Remarkably, Gd2CuO4, even the derivatives
of which have not shown superconductivity so far, gets superconducting with
Tconset as high as ~ 20 K. The implication of our discovery is briefly
discussed.Comment: 22 pages, 5 figures, submitted to Physical Review Letter
Generic phase diagram of "electron-doped" T' cuprates
We investigated the generic phase diagram of the electron doped
superconductor, Nd2-xCexCuO4, using films prepared by metal organic
decomposition. After careful oxygen reduction treatment to remove interstitial
Oap atoms, we found that the Tc increases monotonically from 24 K to 29 K with
decreasing x from 0.15 to 0.00, demonstrating a quite different phase diagram
from the previous bulk one. The implication of our results is discussed on the
basis of tremendous influence of Oap "impurities" on superconductivity and also
magnetism in T' cuprates. Then we conclude that our result represents the
generic phase diagram for oxygen-stoichiometric Nd2-xCexCuO4.Comment: 12 pages, 4 figures; International Symposium on Superconductivity
(ISS) 200
Two-probe theory of scanning tunneling microscopy of single molecules: Zn(II)-etioporphyrin on alumina
We explore theoretically the scanning tunneling microscopy of single
molecules on substrates using a framework of two local probes. This framework
is appropriate for studying electron flow in tip/molecule/substrate systems
where a thin insulating layer between the molecule and a conducting substrate
transmits electrons non-uniformly and thus confines electron transmission
between the molecule and substrate laterally to a nanoscale region
significantly smaller in size than the molecule. The tip-molecule coupling and
molecule-substrate coupling are treated on the same footing, as local probes to
the molecule, with electron flow modelled using the Lippmann-Schwinger Green
function scattering technique. STM images are simulated for various positions
of the stationary (substrate) probe below a Zn(II)-etioporphyrin I molecule. We
find that these images have a strong dependence on the substrate probe
position, indicating that electron flow can depend strongly on both tip
position and the location of the dominant molecule-substrate coupling.
Differences in the STM images are explained in terms of the molecular orbitals
that mediate electron flow in each case. Recent experimental results, showing
STM topographs of Zn(II)-etioporphyrin I on alumina/NiAl(110) to be strongly
dependent on which individual molecule on the substrate is being probed, are
explained using this model. A further experimental test of the model is also
proposed.Comment: Physical Review B, in pres
Photon-assisted electron transport through a three-terminal quantum dot system with nonresonant tunneling channels
We have studied the electron transport through a quantum dot coupled to three
leads in the presence of external microwave fields supplied to different parts
of the considered mesoscopic system. Additionally, we introduced a possible
nonresonant tunneling channels between leads. The quantum dot charge and
currents were determined in terms of the appropriate evolution operator matrix
elements and under the wide band limit the analytical formulas for
time-averaged currents and differential conductance were obtained. We have also
examined the response of the considered system on the rectangular-pulse
modulation imposed on different quantum dot-leads barriers as well as the
time-dependence of currents flowing in response to suddenly removed (or
included) connection of a quantum dot with one of the leads.Comment: 34 pages, 12 figure
Doping evolution of the electronic specific heat coefficient in slightly-doped La2-xSrxCuO4 single crystals
Detailed doping dependence of the electronic specific heat coefficient gamma
is studied for La2-xSrxCuO4 (LSCO) single crystals in the slightly-doped
regime. We find that gamma systematically increases with doping, and
furthermore, even for the samples in the antiferromagnetic (AF) regime, gamma
already acquires finite value and grows with x. This suggests that finite
electronic density of states (DOS) is created in the AF regime where the
transport shows strong localization at low temperatures, and this means the
system is not a real insulator with a clear gap even though it still keeps long
range AF order.Comment: 4 pages, 4 figures, accepted for publication in Journal of Physics:
Conference Series (LT25 proceeding
Phase control of La2CuO4 in thin-film synthesis
The lanthanum copper oxide, La2CuO4, which is an end member of the prototype
high-Tc superconductors (La,Sr)2CuO4 and (La,Ba)2CuO4, crystallizes in the
"K2NiF4" structure in high-temperature bulk synthesis. The crystal chemistry,
however, predicts that La2CuO4 is at the borderline of the K2NiF4 stability and
that it can crystallize in the Nd2CuO4 structure at low synthesis temperatures.
In this article we demonstrate that low-temperature thin-film synthesis
actually crystallizes La2CuO4 in the Nd2CuO4 structure. We also show that the
phase control of "K2NiF4"-type La2CuO4 versus "Nd2CuO4"-type La2CuO4 can be
achieved by varying the synthesis temperature and using different substrates.Comment: 4 pages, 5 figures, submitted to PRB, revte
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