26 research outputs found
Liquid-liquid dispersions in intensified impinging-jets cells
The formation of dispersions of two immiscible liquids in a confined impinging-jets cell was studied experimentally. The jets of the liquids formed at two opposing channels and collided in a main channel, which was perpendicular to the previous two. Jet channels with diameters either 0.25 or 0.5 mm and main channels with diameters either 2 or 3 mm were used. The jet velocities varied from 0.17 to 6.2 m/s and the dispersed to continuous phase ratios varied from 0.05 to 0.28. Deionised water and kerosene (Exxsol D80: ρ = 795 kg/m3 and μ = 1.73 mPa s) were used as test fluids. Drop sizes were measured with high-speed imaging. It was found that the total velocity of the two jets was the main parameter that affected both the average drop size and the interfacial area, whilst the dispersed to continuous phase flow rate ratio was less significant. Both phases could become continuous depending on the phase flowrate ratio; drops were, however, larger in the organic continuous dispersions. The interfacial area produced with the impinging-jets cell was almost 3 times larger than in capillary contactors at similar conditions (umix = 0.024–0.19 m/s). The size of the main channel affected the drop size and smaller drops formed in the large channel compared to the small one. With increasing energy dissipation rate, ε, in the impingement zone, the Sauter mean diameter decreased following a relation of the form ∼ε−b. Apart from the lower velocities, the drop sizes did not change significantly at distances equal to 15 channel diameters downstream the impingement area
Intensified extraction of uranium(VI) in impinging-jets contactors
The mass transfer performance of confined impinging-jets (CIJs) contactors was investigated for metal separations. In particular, the extraction of uranium(VI) from aqueous nitric acid solutions (3 M) into 30% v/v TBP/Exxsol D80, relevant to spent nuclear fuel reprocessing, was studied for different cell geometries, i.e. main chamber size (D = 2 and 3.2 mm) and jet diameter (d j = 0.25 and 0.5 mm), and different operating conditions, i.e. residence time (τ = 1–9 s), total jet velocity (u tot = 2.6–8.6 m/s), and reactor length (L = 7–85 cm). For all conditions investigated, the aqueous phase was the dispersed one. Drop sizes were also measured with high-speed imaging. It was found that the extraction efficiency increased by increasing residence time for a constant total jet velocity regardless of the chamber size. At a constant residence time, higher extraction efficiency was achieved at high total jet velocities, which are associated with larger interfacial areas (smaller drops). The extraction efficiency reached 70% in most of the cases investigated in less than 2 s. In addition, high overall volumetric mass transfer coefficients (up to 1 s −1 ) were obtained at short residence times. Using regression analysis, a correlation for the overall volumetric mass transfer coefficient was developed from the experimental data with an average deviation of 9%
Studies of intensified small-scale processes for liquid-liquid separations in spent nuclear fuel reprocessing
The main contribution of the thesis is to study and develop small-scale processes for ionic liquid-based extractions that can intensify the liquid-liquid separations in the spent nuclear fuel reprocessing cycle. The industrial application of small scale processes requires that their hydrodynamics and mass transfer behaviour are well characterised and predicted. In addition, modelling methodologies are proposed to evaluate the applicability of the small scale extractors in reprocessing the large volumes of nuclear waste used in industrial scale. The first part of the work involves the study of the hydrodynamic behaviour of two-phase (ionic liquid-aqueous) flows. Flow pattern formations within channels have been identified for a wide range of operating conditions and were found to be strongly affected by channel size and material, fluid properties, and flow rates. The main patterns observed were plug flow, annular flow, and drop flow. Subsequently, the work focused on the investigation of the plug flow which has been found to enhance mass transfer because of circulation patterns that develop within the phases. Plug flow was thoroughly investigated in various channel sizes of different material mainly for TBP/ionic liquid (30% v/v) mixtures-nitric acid solutions, relevant to spent nuclear fuel reprocessing. Several hydrodynamic characteristics, such as plug length, plug velocity, film thickness, and pressure drop have been investigated for different ionic liquids, channel sizes, and phase flow rates. Results have been compared with literature, and new (or modified) correlations have been proposed for estimating the plug length, film thickness, and pressure drop. Furthermore, circulation patterns and mixing characteristics within aqueous plugs were investigated by means of μ-PIV (micro Particle Image Velocimetry). The mixing within a plug was locally quantified by the non-dimensional circulation time and the results were correlated with the mass transfer performance. Mixing within the plug was found to be affected by several parameters, but the most decisive one was the size of the channel; mixing was enhanced by decreasing the channel diameter. The last stage of the experimental part of this research involves studies of the extraction of dioxouranium(VI) ions from nitric acid solutions into TBP/IL mixtures (30%, v/v), relevant to spent nuclear fuel reprocessing in channels with sizes ranging from 0.5 to 2 mm ID. The effects of ionic liquid type, initial nitric acid concentration, and residence time on the extraction performance of the contactor were studied. Experimental mass transfer coefficients were compared against predictive models derived from the literature and good agreement was found with those for liquid-liquid contactors. Experimental results were also compared with extraction units already in operation in spent nuclear reprocessing plants. It was found that comparable amount of spent nuclear fuel (1045 tonnes per year) can be reprocessed and extraction of dioxouranium(VI) >99% can be achieved in 4 stages (cycles) with approximately 400 assemblies (one assembly consists of 6 channels of 2 mm internal diameter and 285 cm length). Finally, a numerical finite element model for the hydrodynamics and mass transfer was developed, and the results were compared with the experimental findings. The model used experimental data for the geometric characteristics of the plug flow and predicted reasonably well the experimentally measured extraction efficiencies (with a 11.3 % mean relative error)
Intensified biodiesel production from waste cooking oil and flow pattern evolution in small-scale reactors
In this paper, the transesterification reaction of waste cooking oil (WCO) with methanol using KOH as catalyst to produce biodiesel was performed in a micro-reactor (1 mm ID) using a cross-flow inlet configuration. The effects of different variables such as, methanol-to-oil molar ratio, temperature, catalyst concentration, and residence time on biodiesel yield, as well as the associated flow patterns during the transesterification reaction were investigated and the relationship between flow characteristics and mass transfer performance of the system was examined. The work reveals important aspects and the links between the hydrodynamic behaviour and the mass transfer performance of the intensified reactors. It was found that high yield (>90%) of biodiesel can be achieved in one-stage reaction using cross-flow micro-reactors for a wide range of conditions, i.e., methanol-to-oil molar ratio: 8–14, catalyst concentration: 1.4%–1.8% w/w, temperature: 55°C–60°C, and residence times: 55–75 s
Mixing patterns in water plugs during water/ionic liquid segmented flow in microchannels
Circulation patterns and mixing characteristics within water plugs in liquid/liquid segmented flow were investigated by means of micro-Particle Image Velocimetry. Experiments were carried out in a glass microchannel with circular cross-section of 100 μm radius using [C4mim][NTf2] ionic liquid as the carrier fluid. A T-junction was used as inlet, while mixture velocities varied from 0.0028 m/s to 0.0674 m/s. Two main circulation vortices were found within the plugs while at intermediate mixture velocities two additional secondary vortices appeared at the plug front. The mixing rate was locally quantified by means of the non-dimensional circulation time, which was calculated across the plug length. Consistently with the circulation patterns, the non-dimensional circulation time was found to have a profile along the direction of the flow that mirrors the shape of the plug, with a minimum at the axial location of the vortex cores (where the circulation velocity is maximum at the channel centre) while it tended to infinity towards the liquid/liquid interfaces. For all the experiments the minimum value of the circulation time fell within the range of 1.00–1.75. For increasing mixture velocities (i.e. increasing Ca) and sufficiently long plugs (εIL=0.4) a general decrease (i.e. higher mixing rate) of the circulation time minimum was found, although the behaviour was rather complex. On the other hand, the circulation velocity linearly increased as the Ca number (mixture velocity) increased
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Liquid - liquid flows in microchannels
This paper was presented at the 3rd Micro and Nano Flows Conference (MNF2011), which was held at the Makedonia Palace Hotel, Thessaloniki in Greece. The conference was organised by Brunel University and supported by the Italian Union of Thermofluiddynamics, Aristotle University of Thessaloniki, University of Thessaly, IPEM, the Process Intensification Network, the Institution of Mechanical Engineers, the Heat Transfer Society, HEXAG - the Heat Exchange Action Group, and the Energy Institute.In this work the flow patterns are investigated during the flow of an ionic liquid and deionized water mixture in a glass microchannel (0.2mm I.D) for two different inlet configurations (T- and Yjunction). The density, viscosity and surface tension of the ionic liquid [C4mim][NTf2] are 1420kg/m3 , 0.029Pa·s and 31.92mN/m respectively. The water phase has a density of 1000kg/m3, a viscosity of
0.001Pa·s and a surface tension of 73,69mN/m. In most of the patterns observed water was the continuous phase with the ionic liquid forming plugs or a mixture of plugs and drops within it. With the Y-junction and at high mixture velocities a separated pattern was observed with the two fluids flowing in parallel along the channel for the middle range of ionic liquid fractions, while water dispersed as drops was found at high ionic liquid fractions. Pressure drop was measured during regular plug flow which revealed that for the same ionic liquid superficial velocity the pressure drop was lower when it flowed in a mixture with water than when it was on its own in the channel. For a xonstant ionic liquid flow rate, pressure drop decreased as the ionic liquid fraction increased.The project is funded by the Engineering and Physical Sciences Research Council (EPSRC) and the Energy Institute at UCL
Intensified Liquid-Liquid Extraction Technologies in Small Channels: A Review
Solvent extraction is a key separation process in several industries. Mixer-settlers and agitated or pulsed columns are mainly used as liquid-liquid contactors. However, these units require large solvent inventories and long residence times, while flow fields are often not uniform and mixing is poor. These drawbacks can be overcome with process intensification approaches where small channel extractors are used instead. The reduced volumes of small units in association with the increased efficiencies facilitate the use of novel, often expensive, but more efficient and environmentally friendly solvents, such as ionic liquids. The small throughputs of intensified contactors, however, can limit their full usage in industrial applications, thus robust scale-up strategies need to be developed. This paper reviews promising intensified technologies for liquid-liquid extractions based on small channels. In particular, extractions in single channels and in confined impinging jets are considered. The increase in throughput via scale-out approaches with appropriate manifolds is discussed, based on the use of many channels in parallel. The combination of small channels and centrifugal forces is exploited in counter-current chromatography (CCC) systems where many mixing and settling steps are combined within the contactors. Scale up is possible via centrifugal partition chromatography (CPC) configurations
Scale-up studies for intensified production of biodiesel from used cooking oil
In this paper the effect of channel size on the transesterification of used cooking oil (UCO) with methanol using KOH as catalyst to produce biodiesel was investigated for capillaries with internal diameter ranging from 1 to 3 mm. A T-junction was used as the mixing zone of the two liquid phases. The effects of different parameters such as, internal diameter, methanol-to-oil molar ratio, reaction time, temperature, and catalyst concentration were investigated. Results showed that the conversion efficiency to biodiesel is increased by decreasing the channel size, whilst the interactions of the other variables are also discussed
Effect of channel size on mass transfer during liquid-liquid plug flow in small scale extractors
In this paper the effect of channel size on the mass transfer characteristics of liquid-liquid plug flow was investigated for capillaries with internal diameter ranging from 0.5 to 2 mm. The extraction of {UO2}2+ ions from nitric acid solutions into TBP/IL mixtures, relevant to spent nuclear fuel reprocessing, was studied for different residence times, dispersed phase fractions, and mixture velocities. It was found that extraction efficiencies increased as the channel size decreased. For a given channel length and for all channel sizes, an increase in mixture velocity decreased the extraction efficiency. The overall mass transfer coefficients (kLα) for all channels varied between 0.049 and 0.29 s-1 and decreased as the channel size increased. The evolution of the kLα along the extraction channel showed a decreasing trend for all the channel sizes. The experimentally obtained mass transfer coefficients were compared with existing models for liquid-liquid and gas-liquid segmented flows from the literature. The results showed good agreement with the empirical correlation proposed for a liquid-liquid system. A finite element model was developed that solved the velocity and concentration fields in the channel for both phases considering a unit cell (one plug and one slug) with periodic boundary conditions at the inlet and the outlet. The model used experimental data for the geometric characteristics of the plug flow and predicted reasonably well the experimentally measured extraction efficiencies (with mean relative error of 11 %)
Experimental and CFD scale-up studies for intensified actinide/ lanthanide separations
In this paper, systematic studies are performed to identify the parameters that influence the selective separation of actinides from a mixture with lanthanides in small channels. In particular, the separation of dioxouranium metal ions (UO2+2) from a binary U(VI)/Er(III) mixture in a nitric acid solution by an organic TBP/kerosene (Exxsol D80) phase, relevant to spent nuclear fuel reprocessing is investigated. The effects of parameters such as TBP concentration, organic-to-aqueous phase flow rate ratio, channel size, and residence time on mass transfer are evaluated, whilst the mass transfer performance in the extraction channels is further analysed using two important hydrodynamic features, i.e. plug formation time and interfacial area to volume ratio. Circular channels with diameters from 1 to 3 mm are used to investigate the effect of scale on the mass transfer characteristics. The importance of the mixing zone on mass transfer is also evaluated. A CFD model is proposed to simulate the mass transfer during plug flow. Using only one experimental point, once the plug has been formed, the model is able to predict extraction percentage with less than 4% difference compared to the experiments