Surface Properties of Poly(Hydroxyurethane)s Based on Five-Membered Bis-Cyclic Carbonate of Diglycidyl Ether of Bisphenol A

Poly(hydroxyurethane)s (PHU) are alternatives for conventional polyurethanes due to the use of bis-cyclic dicarbonates and diamines instead of harmful and toxic isocyanates. However, the surface properties of poly(hydroxyurethane)s are not well known. In this work, we focus on the analysis of the surface properties of poly(hydroxyurethane) coatings. Poly(hydroxyurethane)s were obtained by a catalyst-free method from commercially available carbonated diglycidyl ether of bisphenol A (Epidian 6 epoxy resins) and various diamines: ethylenediamine, trimethylenediamine, putrescine, hexamethylenediamine, 2,2,4(2,4,4)-trimethyl-1,6-hexanediamine, m-xylylenediamine, 1,8-diamino-3,6-dioxaoctane, 4,7,10-trioxa-1,13-tridecanediamine, and isophorone diamine, using a non-isocyanate route. The structures of the obtained polymers were confirmed by FT-IR, 1H NMR and 13C NMR spectroscopy, and thermogravimetric (TGA) and differential scanning calorimetry (DSC) analyses were performed. The rheological characteristic of the obtained polymers is presented. The static contact angles of water, diidomethane, and formamide, deposited on PHU coatings, were measured. From the measured contact angles, the surface free energy was calculated using two different approaches: Owens–Wendt and van Oss–Chaudhury–Good. Moreover, the wetting envelopes of PHU coatings were plotted, which enables the prediction of the wetting effect of various solvents. The results show that in the investigated coatings, a mainly dispersive interaction occurs

Surface Properties of Poly(Hydroxyurethane)s Based on Five-Membered Bis-Cyclic Carbonate of Diglycidyl Ether of Bisphenol A

Poly(hydroxyurethane)s (PHU) are alternatives for conventional polyurethanes due to the use of bis-cyclic dicarbonates and diamines instead of harmful and toxic isocyanates. However, the surface properties of poly(hydroxyurethane)s are not well known. In this work, we focus on the analysis of the surface properties of poly(hydroxyurethane) coatings. Poly(hydroxyurethane)s were obtained by a catalyst-free method from commercially available carbonated diglycidyl ether of bisphenol A (Epidian 6 epoxy resins) and various diamines: ethylenediamine, trimethylenediamine, putrescine, hexamethylenediamine, 2,2,4(2,4,4)-trimethyl-1,6-hexanediamine, m-xylylenediamine, 1,8-diamino-3,6-dioxaoctane, 4,7,10-trioxa-1,13-tridecanediamine, and isophorone diamine, using a non-isocyanate route. The structures of the obtained polymers were confirmed by FT-IR, 1H NMR and 13C NMR spectroscopy, and thermogravimetric (TGA) and differential scanning calorimetry (DSC) analyses were performed. The rheological characteristic of the obtained polymers is presented. The static contact angles of water, diidomethane, and formamide, deposited on PHU coatings, were measured. From the measured contact angles, the surface free energy was calculated using two different approaches: Owens–Wendt and van Oss–Chaudhury–Good. Moreover, the wetting envelopes of PHU coatings were plotted, which enables the prediction of the wetting effect of various solvents. The results show that in the investigated coatings, a mainly dispersive interaction occurs.</jats:p

Synthesis, characterization and reactivity of a six-membered cyclic glycerol carbonate bearing a free hydroxyl group

For the first time, synthesis of the simplest derivative of glycerol, a six-membered cyclic glycerol carbonate (5-hydroxy-1,3-dioxan-2-one), from glycerol is presented.</p

Application of PLA as a Binder in Molding and Core Sands

Rosnąca popularność polimerów biodegradowalnych, możliwości ich wytwarzania, przetwarzania i wykorzystania, stwarzają szansę opracowania nowych materiałów wiążących, do zastosowania w przemyśle odlewniczym. Nowe spoiwa biopolimerowe, spełniające wymagania z zakresu ochrony środowiska, mogą stanowić alternatywę dla dotychczas stosowanych spoiw do mas formierskich i rdzeniowych, w przypadku uzyskania wymaganych właściwości wytrzymałościowych i technologicznych. Prezentowane rozwiązanie, alternatywne do dotychczas opisywanych w literaturze, obejmujące badania mas otrzymywanych z piasków otaczanych spoiwem biodegradowanlym PLA, dotyczy optymalizacji właściwości wytrzymałościowych, w odniesieniu do procentowej zawartości biopolimeru, temperatury i czasu wytwarzania form i rdzeni metodą HOT-BOX. Uzyskane wyniki pozwalają sądzić, że biopolimery mogą być skutecznym zamiennikiem dotychczas stosowanych spoiw mas formierskich i rdzeniowych, a metoda wytwarzania z użyciem piasków otaczanych, może być równie skuteczna jak metody alternatywne.Currently moulding sand with biopolymers as a binding agent appears to be probably the most interesting achievement in the mould production from ecology point of view. New biopolymer materials offer the parameters comparable to those which have been in use up to now. Moulding sands with a biopolymer binder were produced. The moulding process of 2% PLA sandmix involving different fusion temperatures and times was studied and the results presented. The results of observations and ultimate tensile strength tests were offered. The obtained results point to the fact that the new sandmix moulding method offered similar results that obtained in the literature. The issue is viewed as requiring further research

Unexpected Method of High-Viscosity Shear Thickening Fluids Based on Polypropylene Glycols Development via Thermal Treatment

This study aimed to analyze the influence of the thermal treatment of shear thickening fluids, STFs, on their viscosity. For this purpose, shear thickening fluids based on polypropylene glycols PPG400 and PPG1000 and Aerosil&reg;200 were developed. The shear thickening behavior of obtained fluids was confirmed by using a parallel-plate rheometer. Next, thermogravimetric (TG) analyses were used to characterized thermal stability and weight loss of the STFs at a constant temperature. Finally, the thermal treatment of the STFs obtained was provided using the apparatus developed for this purpose. The received STFs exhibited a very high maximum viscosity up to 15 kPa. The rheology of the STFs measured after thermal treatment indicated that the proposed method allowed the development of STFs with a very high maximum viscosity. The maximum viscosity of the STFs increased twofold when thermal treatment of the STFs at elevated temperature for 210 min was performed. TG confirmed the convergence of the weight loss in the apparatus. Our results show that controlling the thermal treatment of STFs allows STFs to be obtained with high viscosity and a dilatation jump of the STFs by degradation of the liquid matrix

The Influence of UV Radiation Aging on Degradation of Shear Thickening Fluids

Shear thickening fluids (STFs) are innovative materials that can find applications in smart body armor. However, the usage of STFs is limited by the aging of these materials. This work aims to analyze the influence of UV radiation on the aging process of STFs. The investigation was done experimentally, and artificial aging was applied to investigate the impact of UV radiation on the properties of STFs. The shear-thickening properties of obtained STFs were confirmed by viscosity measurements. The STFs based on PPG425, PPG2700, and KE-P10 exhibited a very high maximum viscosity of up to 580.7 Pa·s and 3313 Pa·s for the STF425 and STF2700, respectively. The aging of the obtained STFs caused the liquid matrix degradation, causing damage to the STFs and their change from liquid into solid. Furthermore, the FT-IR, 1H NMR, and 13C NMR spectroscopies were used for the confirmation of the breakdown of STFs. The FT-IR spectroscopy revealed the appearance of carbonyl groups in STFs after aging. Moreover, 1H NMR and 13C NMR spectroscopy confirmed the formation of the typical groups containing carbonyl groups. Our results demonstrate that STFs are UV light-sensitive and may lose their properties during storage.</jats:p

The Influence of UV Radiation Aging on Degradation of Shear Thickening Fluids

Shear thickening fluids (STFs) are innovative materials that can find applications in smart body armor. However, the usage of STFs is limited by the aging of these materials. This work aims to analyze the influence of UV radiation on the aging process of STFs. The investigation was done experimentally, and artificial aging was applied to investigate the impact of UV radiation on the properties of STFs. The shear-thickening properties of obtained STFs were confirmed by viscosity measurements. The STFs based on PPG425, PPG2700, and KE-P10 exhibited a very high maximum viscosity of up to 580.7 Pa&middot;s and 3313 Pa&middot;s for the STF425 and STF2700, respectively. The aging of the obtained STFs caused the liquid matrix degradation, causing damage to the STFs and their change from liquid into solid. Furthermore, the FT-IR, 1H NMR, and 13C NMR spectroscopies were used for the confirmation of the breakdown of STFs. The FT-IR spectroscopy revealed the appearance of carbonyl groups in STFs after aging. Moreover, 1H NMR and 13C NMR spectroscopy confirmed the formation of the typical groups containing carbonyl groups. Our results demonstrate that STFs are UV light-sensitive and may lose their properties during storage