234 research outputs found
NeuCEPT: Locally Discover Neural Networks' Mechanism via Critical Neurons Identification with Precision Guarantee
Despite recent studies on understanding deep neural networks (DNNs), there
exists numerous questions on how DNNs generate their predictions. Especially,
given similar predictions on different input samples, are the underlying
mechanisms generating those predictions the same? In this work, we propose
NeuCEPT, a method to locally discover critical neurons that play a major role
in the model's predictions and identify model's mechanisms in generating those
predictions. We first formulate a critical neurons identification problem as
maximizing a sequence of mutual-information objectives and provide a
theoretical framework to efficiently solve for critical neurons while keeping
the precision under control. NeuCEPT next heuristically learns different
model's mechanisms in an unsupervised manner. Our experimental results show
that neurons identified by NeuCEPT not only have strong influence on the
model's predictions but also hold meaningful information about model's
mechanisms.Comment: 6 main page
Corrosion protection of carbon steel by an epoxy resin containing organically modified clay
This study focusses on the use of montmorillonite clay (MMT) treated with an organic compound (aminotrimethylphosphonic acid (ATMP)) and dispersed in an epoxy resin to improve corrosion protection of carbon steel. X-ray diffraction was performed to verify that the individual silicate layers were separated and dispersed in the epoxy resin. Corrosion resistance of the coated steel was evaluated by electrochemical impedance spectroscopy (EIS) and local electrochemical impedance spectroscopy (LEIS). Three systems were tested: the epoxy clear-coat, the epoxy resin containing 2 wt.% clay and the epoxy resin containing 2 wt.% clay modified byATMP (ATMP-modified clay). From conventional EIS, it was shown that the incorporation of clay or ATMP-modified clay in the epoxy matrix significantly improved the barrier properties of the coating. The corrosion resistance of the carbon steel coated by the epoxy resin containing ATMP-modified clay was higher than that obtained for the system containing non-treated clay. Local electrochemical measurements performed on scratched samples revealed the inhibitive role of ATMP at the carbon steel/coating interface
Analytical Method for Predicting Lateral Facing Deflection of Geosynthetic-Reinforced Soil Abutment Walls
Geosynthetic-reinforced soil (GRS) walls have been recently used as bridge abutments to directly support spread footings on the reinforced soil mass. This application reduces the requirement for using traditional deep foundations, such as piles or drilled shafts, to support bridge beams. GRS abutment walls are generally subjected to high footing loads that are close to the wall facing. Although GRS abutment walls with modular block facing have been the subject of a number of studies, there are limited methods to predict the profile of the lateral facing deflections along the height of the GRS abutment walls. Lateral deflections along the facing of GRS walls are of significant importance and are difficult to predict. In practice, design engineers need numerical modeling or software to predict the deflection profile. The objectives of this study were to develop an analytical approach to estimate lateral deflections of the wall facing along the height of the GRS abutment walls. Two sets of equations were developed, and experimental test results were used for verification of the proposed analytical approach. There is agreement between the results from proposed approach and the measured data. The maximum lateral deflections predicted from the proposed equations are almost identical to the measured data. The facing lateral deflection profiles with depth are within close range of measured data. The proposed analytical equations for determining lateral deflections provide an effective and simple tool in design of the GRS abutment walls
Does rising import competition harm Vietnam’s local firm employment of the 2000s?
This study considers for the first time the role of rising import
competition on employment in Vietnam. Using a time differenced
and instrumental variables approach, our study shows that import
competition results in employment contraction. Firms operating
in industries that face greater import competition have reduced
employment. We also find strong evidence of a negative impact of
import competition for small and very small firms, as well as in the
period before Vietnam’s World Trade Organization (WTO) accession.
Our results also reveal that previous studies at the industry-level
can provide biased estimates because of not controlling for the
heterogeneity of firm characteristics
Incorporation of an indole-3 butyric acid modified clay in epoxy resin for corrosion protection of carbon steel
In the present work, indole-3 butyric acid (IBA) was inserted between montmorillonite clay platelets by cation exchange. The clay treated with the organic compound (IBA-modified clay) was then dispersed in an epoxy resin at a low concentration (2 wt.%). IBA was chosen to act both as an inhibitor and an adherence promoter. The effect of the IBA-modified clay on the microstructure and on the protective properties of the epoxy coating deposited on carbon steel was evaluated by a thermostimulated-current (TSC) method and by electrochemical impedance spectroscopy (EIS). The TSC measurements showed the specific action of
IBA-modified clay which decreased the molecular mobility of the polymer chain by comparison with the pure epoxy. Impedance measurements corroborated the role of the modified clay on the barrier properties of the coating which remained high as a function of exposure time in a 0.5 M NaCl solution. The corrosion resistance of the carbon steel coated with the epoxy resin containing IBA-modified clay was significantly higher than that obtained with the clear coat. Polarization curves plotted in the presence of an artificial
defect demonstrated the inhibitive role of IBA at the carbon steel/coating interface. The good adherence of the coating was seen during salt spray test
HIGH PROTECTION PERFORMANCE OF COATING SYSTEMS BASED ON ZINC RICH PRIMER AND FLUOROPOLYMER COATING
Coating systems based on zinc rich primer and fluoropolymer top coat were exposed for 8 years at different atmospheric stations in Vietnam: Hanoi, Ha Long and Nha Trang. For comparison the coating system with zinc rich primer and polyurethane topcoat was also tested. The degradations of coating systems were evaluated by gloss measurement and electrochemical impedance spectroscopy. The obtained results show that coating systems with zinc rich primer and top coatings based on fluoropolymer and polyurethane topcoats show very high weather resistance and corrosion protection performance, but the systems with fluoropolymer are better than coating system with polyurethane topcoat
Effect of cast iron microstructure on adherence of an epoxy protection
To study the influence of the microstructure of cast iron on the adhesion of an epoxy coating, ferritic, pearlitic and austempered samples were prepared in as-received, polished and oxidised states. A pull-off test (dry adhesion) was performed before immersing in water while the crosscut test was made after 24 days of exposition in distilled water (wet adhesion). X-rays were combined with optical microscopy (LOM) and scanning electron microscopy (SEM) for surface analysis. The adhesion of the epoxy coating on the cast iron surface firstly depends on the roughness of the surface; polished samples showed high adherence by comparison with asreceived samples. On the oxidised samples, the surface oxide significantly improves the adhesion of the coating in both dry and wet states for all three sample microstructure. The presence of carbide in the structure was observed to decrease adherenc
Polymer Brushes on Silica Nanostructures Prepared by Aminopropylsilatrane Click Chemistry: Superior Antifouling and Biofunctionality
In nanobiotechnology, the importance of controlling interactions between biological molecules and surfaces is paramount. In recent years, many devices based on nanostructured silicon materials have been presented, such as nanopores and nanochannels. However, there is still a clear lack of simple, reliable, and efficient protocols for preventing and controlling biomolecule adsorption in such structures. In this work, we show a simple method for passivation or selective biofunctionalization of silica, without the need for polymerization reactions or vapor-phase deposition. The surface is simply exposed stepwise to three different chemicals over the course of ∼1 h. First, the use of aminopropylsilatrane is used to create a monolayer of amines, yielding more uniform layers than conventional silanization protocols. Second, a cross-linker layer and click chemistry are used to make the surface reactive toward thiols. In the third step, thick and dense poly(ethylene glycol) brushes are prepared by a grafting-to approach. The modified surfaces are shown to be superior to existing options for silica modification, exhibiting ultralow fouling (a few ng/cm2) after exposure to crude serum. In addition, by including a fraction of biotinylated polymer end groups, the surface can be functionalized further. We show that avidin can be detected label-free from a serum solution with a selectivity (compared to nonspecific binding) of more than 98% without the need for a reference channel. Furthermore, we show that our method can passivate the interior of 150 nm
7 100 nm nanochannels in silica, showing complete elimination of adsorption of a sticky fluorescent protein. Additionally, our method is shown to be compatible with modifications of solid-state nanopores in 20 nm thin silicon nitride membranes and reduces the noise in the ion current. We consider these findings highly important for the broad field of nanobiotechnology, and we believe that our method will be very useful for a great variety of surface-based sensors and analytical devices
Synthesis of Flower-like Silver Nanostructures on Silicon and Their Application in Surface-enhanced Raman Scattering
To enhance the intensity of surface-enhanced Raman scattering (SERS), production of metal nanostructures with sharp points, lying side by side at the nanometer level plays an extremely important role. In this paper, we report on a manufacturing process in which the silver nanoparticles with the flower-like shape have been fabricated. Such silver nanoparticles have been fabricated by chemical deposition of silver particles on silicon wafers, using a solution of hydrofluoric acid (HF), silver nitrate (AgNO3) and ascorbic acid (AsA) in water, at room temperature. During the manufacturing we found that only when the concentrations of AgNO3 and AsA are appropriate, the flower-like silver nanoparticles will form. Note that while other authors mainly made flower-like silver nanoparticles in the form of suspensions, we have created flower-like silver nanoparticles with cabbage-shape on a silicon surface. The ensembles of flower-like silver nanoparticles above were used as SERS substrates to detect crystal violet (CV) in low concentrations and good results were obtained
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