Determining ethylene group disorder levels in κ\kappa-(BEDT-TTF)2_2Cu[N(CN)2_2]Br

We present a detailed structural investigation of the organic superconductor $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br at temperatures $T$ from 9 to 300 K. Anomalies in the $T$ dependence of the lattice parameters are associated with a glass-like transition previously reported at $T_g$ = 77 K. From structure refinements at 9, 100 and 300 K, the orthorhombic crystalline symmetry, space group {\it Pnma}, is established at all temperatures. Further, we extract the $T$ dependence of the occupation factor of the eclipsed conformation of the terminal ethylene groups of the BEDT-TTF molecule. At 300 K, we find 67(2) %, with an increase to 97(3) % at 9 K. We conclude that the glass-like transition is not primarily caused by configurational freezing-out of the ethylene groups

Suppression of the soybean cyst nematode, Heterodera glycines, by short-term field cultivation and soil incorporation of mung bean.

© Koninklijke Brill NV, Leiden, 2021. This is the accepted manuscript version of an article which has been published in final form at https://doi.org/10.1163/15685411-bja10042Our previous study using pots reported that short-term growth of mung bean (Vigna radiata) may be useful to decrease the density of the soybean cyst nematode (SCN), Heterodera glycines, in soil. The objective of this study was to determine whether short-term growth of mung bean and its incorporation by ploughing decreased SCN density in infested fields. Firstly, we did pot experiments to evaluate the optimum temperature and moisture for hatching in soil. SCN hatching was stimulated at 25 and 30°C and not at 20°C; however, it was stimulated at alternating temperature conditions between 20 and 25°C. Soil moisture levels with pF 2.76 or less were required to stimulate SCN hatch in soil. Field experiments were done in Saitama, Kanagawa and Nara Prefectures, Japan. SCN density was reduced by nearly half even in control plots, in which mung bean was not cultivated and ploughed, in Saitama and Nara Prefectures. However, SCN density was reduced by nearly 80% or more in the three Prefectures, except for one plot in Kanagawa, and the soil temperature and moisture conditions were kept at around 20-30°C and at <pF 2.8. Increase in yield of green soybean by SCN control was estimated at 350 kg (1000 m)−2. Overall, the present study revealed that short-term field cultivation of mung bean and ploughing was a profitable method to decrease SCN density in infested fields and thereby to increase yield of green soybean.Peer reviewedFinal Accepted Versio

The role of snow in the thickening processes of lake ice at Lake Abashiri, Hokkaido, Japan

To clarify the properties of lake ice at mid-latitudes subject to moderate air temperature, heavy snow and abundant solar radiation even in winter, we conducted field observations at Lake Abashiri in Japan for three winters and developed a one-dimensional (1-D) thermo-dynamical ice growth model. Using this model with meteorological data-sets, we examined the role of snow in the ice thickening process, as well as the Lake Abashiri ice phenology (including the interannual trend) for the past 55 years to compare with high latitude lakes. The ice was composed of two distinct layers: a snow ice (SI) layer and a congelation ice layer. The SI layer occupied a much greater fraction of total ice thickness than that at high latitude lakes. In-situ observations served to demonstrate the validity of the model. Freeze-up and break-up dates supplied by satellite imagery enabled further model validation prior to the availability of field data (2000/01–2015/16). Based on both observations and numerical experiments, it was found that one important role of snow is to moderate the variability of ice thickness caused by changes in meteorological conditions. Furthermore, ice thickness is more sensitive to snow depth than air temperature. When applied to an extended 55-year period (1961/62–2015/16) for which local meteorological observations are available, the mean dates of freeze-up and break-up, ice cover duration and ice thickness in February were estimated to be 12 December (no significant trend), 17 April (−1.7 d/decade), 127 d (−2.4 d/decade) and 43 cm (−1.4 cm/decade). For this long-term period, while snow still played an important role in ice growth, the surface air temperature warming trend was found to be a strong factor influencing ice growth, as reported for the high latitude lakes