85 research outputs found
Strain-induced creation and switching of anion vacancy layers in perovskite oxynitrides
Using strain to control oxynitride properties. 京都大学プレスリリース. 2020-12-01.原子空孔の配列を制御する新手法の発見. 京都大学プレスリリース. 2020-12-02.Perovskite oxides can host various anion-vacancy orders, which greatly change their properties, but the order pattern is still difficult to manipulate. Separately, lattice strain between thin film oxides and a substrate induces improved functions and novel states of matter, while little attention has been paid to changes in chemical composition. Here we combine these two aspects to achieve strain-induced creation and switching of anion-vacancy patterns in perovskite films. Epitaxial SrVO3 films are topochemically converted to anion-deficient oxynitrides by ammonia treatment, where the direction or periodicity of defect planes is altered depending on the substrate employed, unlike the known change in crystal orientation. First-principles calculations verified its biaxial strain effect. Like oxide heterostructures, the oxynitride has a superlattice of insulating and metallic blocks. Given the abundance of perovskite families, this study provides new opportunities to design superlattices by chemically modifying simple perovskite oxides with tunable anion-vacancy patterns through epitaxial lattice strain
Structure Analysis of Liquids and Disordered Materials Using Pulsed Neutron Diffraction and Total Scattering
Neutron scattering cross section of diamond nanoparticles
Due to their large coherent scattering cross section, diamond nanoparticles (DNPs) are considered as a promising candidate material for a new neutron reflector. For investigation of scattering cross sections of packed samples, we have developed a technique for mechanical compression of DNP powder. Application of 220 MPa allowed us to increase the bulk density from 0.40 g/cm3 to 1.1 g/cm3. The differential cross sections of uncompressed and packed samples were measured using the high-intensity total diffractometer instrument NOVA at J-PARC, covering transfer wavenumbers (q) from 0.6 to 100 nm−1. The q dependence for the compressed sample agreed with the theoretical expectation derived from the Born approximation applied to homogeneous spheres with inclusion of a hard-sphere model to account for the inter-particle structure, whereas the results obtained from the powder sample disagreed. This implies that the theoretical description does not well represent the mesoscopic structure of the DNP powder sample
Neutron scattering cross section of diamond nanoparticles
Due to their large coherent scattering cross section, diamond nanoparticles (DNPs) are considered as a promising candidate material for a new neutron reflector. For investigation of scattering cross sections of packed samples, we have developed a technique for mechanical compression of DNP powder. Application of 220 MPa allowed us to increase the bulk density from 0.40 g/cm3 to 1.1 g/cm3. The differential cross sections of uncompressed and packed samples were measured using the high-intensity total diffractometer instrument NOVA at J-PARC, covering transfer wavenumbers (q) from 0.6 to 100 nm−1. The q dependence for the compressed sample agreed with the theoretical expectation derived from the Born approximation applied to homogeneous spheres with inclusion of a hard-sphere model to account for the inter-particle structure, whereas the results obtained from the powder sample disagreed. This implies that the theoretical description does not well represent the mesoscopic structure of the DNP powder sample
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