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    Charge Transfer Chemistry of Benzo[2,1- c

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    Molecular materials from 1,3,2-dithiazolyls. Solid-state structures and magnetic properties of 2,3-naphthalene and quinoxaline derivatives

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    In the solid state, at room temperature, the radicals 2,3-naphthalene-1,3,2-dithiazolyl (NDTA) and quinoxaline-1,3,2-dithiazolyl (QDTA) are not dimerized; discrete molecules of NDTA are packed in a herringbone fashion, while those of QDTA adopt a slipped π-stack motif; NDTA is essentially paramagnetic at ambient temperatures, with weak antiferromagnetism developing below 190 K; QDTA is diamagnetic at low temperature, but limited paramagnetism sets in above 120 K.
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