31 research outputs found

    A New View of Hybridized Atomic Orbitals from N-dimensional World

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    By taking a birds-eye view from the n-dimensional world (or n-space), it was found that thež conventionally used sp, sp2, and sp3 hybridized atomic orbitals belong to the spn hybridization and their geometrical shapes correspond to n-simplexes, which are, respectively, the smallest geometrical objects in n-space. Similarly, sp, sp2d, and sp2d3 hybridizations are found to belong to the spndn–1 hybridization, whose geometrical shapes correspond to n-cross polytopes (obtained from 2n vertices equidistantly located on n rectangular coordinate axes). Another series of n-cube hybridization is also discussed, whose 3-space member is 8-coordinated cubic hybridization, sp3d3f. General analytical forms of the wavefunctions of these three series of hybridized atomic orbitals in n-space are obtained. The periodic table and related problems of atoms and molecules in n-space are discussed

    Spectroscopic Properties of Polycyclic Aromatic Compounds. Examination of Nitromethane as a Selective Fluorescence Quenching Agent for Alternant Polycyclic Aromatic Nitrogen Hetero-Atom Derivatives

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    Article on the spectroscopic properties of polycyclic aromatic compounds and an examination of nitromethane as a selective fluorescence quenching agent for alternant polycyclic aromatic nitrogen hetero-atom derivatives

    Theory of Light Absorption

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    Remembering Professor Takashi Shimozawa

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    A Novel Representation of the Angular Part of Atomic Orbitals.

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