52 research outputs found
Measurement of the local Jahn-Teller distortion in LaMnO_3.006
The atomic pair distribution function (PDF) of stoichiometric LaMnO_3 has
been measured. This has been fit with a structural model to extract the local
Jahn-Teller distortion for an ideal Mn(3+)O_6 octahedron. These results are
compared to Rietveld refinements of the same data which give the average
structure. Since the local structure is being measured in the PDF there is no
assumption of long-range orbital order and the real, local, Jahn-Teller
distortion is measured directly. We find good agreement both with published
crystallographic results and our own Rietveld refinements suggesting that in an
accurately stoichiometric material there is long range orbital order as
expected. The local Jahn-Teller distortion has 2 short, 2 medium and 2 long
bonds.Comment: 5 pages, 3 postscript figures, minor change
Estimates of electronic interaction parameters for LaO compounds (=Ti-Ni) from ab-initio approaches
We have analyzed the ab-initio local density approximation band structure
calculations for the family of perovskite oxides, LaO with =Ti-Ni
within a parametrized nearest neighbor tight-binding model and extracted
various interaction strengths. We study the systematics in these interaction
parameters across the transition metal series and discuss the relevance of
these in a many-body description of these oxides. The results obtained here
compare well with estimates of these parameters obtained via analysis of
electron spectroscopic results in conjunction with the Anderson impurity model.
The dependence of the hopping interaction strength, t, is found to be
approximately .Comment: 18 pages; 1 tex file+9 postscript files (appeared in Phys Rev B Oct
15,1996
COVALENCY EFFECTS IN MAGNETIC INTERACTIONS
On présente une revue des interactions magnétiques dans le but de dégager les informations sur la covalence qui peuvent en être déduites. Les interactions hyperfines sur des ligands, les champs hyperfins dans les métaux mesurés par spectrométrie Mössbauer et diffraction neutronique sont présentées en détail, en insistant sur la dernière approche qui est la plus productive en ce domaine. Les informations déjà recueillies sont confrontées aux connaissances en chimie et on essaie de dégager les axes intéressants pour de futures études.Magnetic interactions, categorised into ligand based, metal based and neutron diffraction, are reviewed with regard to the information they give on covalency. The ligand hyperfine interaction, the metal hyperfine field measured by the Mössbauer effect and neutron diffraction measurements are mentioned in some detail, with particular emphasis on the latter as being the most productive experimental technique in this field. The information already gathered is assessed with reference to chemical knowledge, and useful avenues for future investigation are suggested
Stoichionetric silver β-alumina studued at 25, 300 and 550 C by neutron powder diffraction
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