The Infra‐Red Absorption Spectrum of Methyl Alcohol

Using a grating spectrometer having a KBr foreprism the spectrum of methyl alcohol vapor was studied in the region from 2.5 to 26μ. This molecule has bands at 3683, 2978, 2845, 2054, 1477, 1455, 1340, 1034.18 cm—1 and a very broad band extending from 860 to beyond 380 cm—1. These bands are typical perpendicular and parallel bands and indicate that the molecule is only slightly asymmetric.From the fine structure of the 1034.18 cm—1 parallel band and from certain assumptions about the structure of the molecule the two largest moments of inertia, A and B, were found to be 35.18 and 33.83×10—40 g cm2, respectively. It was not possible to measure C directly but it was estimated to be approximately 6.8×10—40 g cm2.The low frequency band is probably due to the vibration of the hydroxyl hydrogen atom perpendicular to the O☒H bond and perpendicular to the figure axis of the molecule. The presence of this band indicates that the hydroxyl group is not free to rotate, at least in the ground state. There is evidence of rotation in the structure of the band near the high frequency edge. The spacing increases toward high frequencies and finally there is a group of lines having a spacing of about 40 cm—1 between 600 and 860 cm—1. Since these lines are very weak and occur at such high frequencies it appears that free rotation exists only in states of high excitation. A quantitative study of free rotation in a symmetric molecule has been made. This investigation indicates that in a first approximation free rotation should give rise to groups of lines having a spacing of about 40 cm—1 between each group.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70345/2/JCPSA6-6-9-553-1.pd

Zener Tunneling Between Landau Orbits in a High-Mobility Two-Dimensional Electron Gas

Magnetotransport in a laterally confined two-dimensional electron gas (2DEG) can exhibit modified scattering channels owing to a tilted Hall potential. Transitions of electrons between Landau levels with shifted guiding centers can be accomplished through a Zener tunneling mechanism, and make a significant contribution to the magnetoresistance. A remarkable oscillation effect in weak field magnetoresistance has been observed in high-mobility 2DEGs in GaAs-AlGa$_{0.3}$As$_{0.7}$ heterostructures, and can be well explained by the Zener mechanism.Comment: 5 pages, 4 figures. Text slightly shortened, figures resize

Pion-Muon Asymmetry Revisited

Long ago an unexpected and unexplainable phenomena was observed. The distribution of muons from positive pion decay at rest was anisotropic with an excess in the backward direction relative to the direction of the proton beam from which the pions were created. Although this effect was observed by several different groups with pions produced by different means, the result was not accepted by the physics community, because it is in direct conflict with a large set of other experiments indicating that the pion is a pseudoscalar particle. It is possible to satisfy both sets of experiments if helicity-zero vector particles exist and the pion is such a particle. Helicity-zero vector particles have direction but no net spin. For the neutral pion to be a vector particle requires an additional modification to conventional theory as discussed herein. An experiment is proposed which can prove that the asymmetry in the distribution of muons from pion decay is a genuine physical effect because the asymmetry can be modified in a controllable manner. A positive result will also prove that the pion is NOT a pseudoscalar particle.Comment: 9 pages, 3 figure

Modelling and Simulation of Disc Brake Contact Analysis and Squeal

Predicting disc brake squeal by means of the complex eigenvalue method has been a popular approach in the brake research community owing to its advantages over the dynamic transient method. The positive real parts of the complex eigenvalue reflect the degree of instability of the brake system and are thought to indicate the likelihood of squeal occurrence. This paper studies the disc brake squeal using a detailed 3-dimensional finite element (FE) model of a real disc brake. A number of structural modifications for suppressing unstable vibration are simulated. Influence of contact pressure distribution on squeal propensity is also investigated. A plausible modification that results in reduced positive real parts of the eigenvalues is proposed