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Superconductivity in single crystals of a quasi-one dimensional infinite chain cuprate SrCaCuO at 90 K
Although there is no complete theory of high temperature superconductivity,
the importance of CuO planes in cuprate superconductors is confirmed from
both theory and experiments. Strong Coulomb repulsion between electrons on the
CuO plane makes the resultant electron system highly correlated and a
difficult problem to solve since exact solutions of many-body Hamiltonian in
two dimensions do not exist. If however, superconductivity can arise in
structures having chains rather than planes and having a high critical
temperature, then the high temperature superconductivity problem could become
more tractable since exact solutions in one dimension do exist. In this paper,
we report the observation of bulk superconductivity in single crystals of a
cuprate SrCaCuO at very high critical temperature, T, of
90 K whose structure reveals the presence of infinite double chains of
Cu-O-Cu-O instead of CuO planes, thus, ensuring quasi-one dimensional
superconductivity. Bulk superconducting behaviour was observed in \textit{dc}
magnetisation, \textit{ac} susceptibility as well as resistance measurements.
The observation of bulk superconductivity in SrCaCuO having
chains of Cu-O-Cu-O rather than planes of CuO at a high T of 90 K is
expected to profoundly impact our understanding of high temperature
superconductivity.Comment: 15 pages, 4 figure