Potential instability of gas hydrates along the chilean margin due to ocean warming

In the last few years, interest in the offshore Chilean margin has increased rapidly due to the presence of gas hydrates. We have modelled the gas hydrate stability zone off Chilean shores (from 33\ub0 S to 46\ub0 S) using a steady state approach to evaluate the effects of climate change on gas hydrate stability. Present day conditions were modelled using published literature and compared with available measurements. Then, we simulated the effects of climate change on gas hydrate stability in 50 and 100 years on the basis of Intergovernmental Panel on Climate Change and National Aeronautics and Space Administration forecasts. An increase in temperature might cause the dissociation of gas hydrate that could strongly affect gas hydrate stability. Moreover, we found that the high seismicity of this area could have a strong effect on gas hydrate stability. Clearly, the Chilean margin should be considered as a natural laboratory for understanding the relationship between gas hydrate systems and complex natural phenomena, such as climate change, slope stability and earthquakes

Basal and Frontal Accretion Processes versus BSR Characteristics along the Chilean Margin

Multichannel seismic reflection data recorded between Itata (36°S) and Coyhaique offshores (43°S) were processed to obtain seismic images. Analysis of the seismic profiles revealed that weak and discontinuous bottom simulating reflectors were associated to basal accretion processes, while strong and continuous bottom simulating reflectors were associated to frontal accretion processes. This can be explained considering that during basal accretion processes, extensional tectonic movements due to uplifting can favour fluid escapes giving origin to weaker and most discontinuous bottom simulating reflectors. During frontal accretion processes (folding and thrusting), high fluid circulation and stable tectonic conditions however can be responsible of stronger and most continuous bottom simulating reflectors. Along the Arauco-Valdivia offshores, steep accretionary prisms, normal faults, slope basins, and thicker underplated sediment bed were associated to basal accretion, while along the Itata, Chiloe and Coyhaique offshores, small accretionary prisms, folding, and thinner underplated sediment bed were associated to frontal accretion

Observation of the Main Natural Parameters Influencing the Formation of Gas Hydrates

Chemical composition in seawater of marine sediments, as well as the physical properties and chemical composition of soils, influence the phase behavior of natural gas hydrate by disturbing the hydrogen bond network in the water-rich phase before hydrate formation. In this article, some marine sediments samples, collected in National Antarctic Museum in Trieste, were analyzed and properties such as pH, conductivity, salinity, and concentration of main elements of water present in the sediments are reported. The results, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) and ion chromatography (IC) analysis, show that the more abundant cation is sodium and, present in smaller quantities, but not negligible, are calcium, potassium, and magnesium, while the more abundant anion is chloride and sulfate is also appreciable. These results were successively used to determine the thermodynamic parameters and the effect on salinity of water on hydrates’ formation. Then, hydrate formation was experimentally tested using a small-scale apparatus, in the presence of two different porous media: a pure silica sand and a silica-based natural sand, coming from the Mediterranean seafloor. The results proved how the presence of further compounds, rather than silicon, as well as the heterogeneous grainsize and porosity, made this sand a weak thermodynamic and a strong kinetic inhibitor for the hydrate formation process

A crustal seismic profile across Sicily

A crustal reflection seismic profile, more than 100 km long, was recorded across central Sicily, from the Tyrrhenian shore to the Sicily Channel, to understand the deep structures and the collision mechanisms between Europe and Africa and the subsequent geodynamic evolution. The profile was acquired using explosive sources and 240 active channels recorded by a Sercel 408-XL, 24 bits A/D converter, with a 12 km spread and a 24-fold coverage. The data were processed following a non-conventional procedure in order to preserve the relative amplitudes of the reflections and to better investigate the Sicily deep structures down to the Moho. The main highlighted structures are the dramatic flexure of the Iblean crust, the huge, deeper than expected, trough of Caltanissetta consisting of deep seated thrusts and nappes, and the imbricate thrust system of rigid bodies characterizing the northern Maghrebian chain. We designed an ad hoc acquisition and processing in order to highlight these main geological features in the seismic stacked section. Moreover, the deepest parts of the Caltanissetta trough are imaged for the first time, and its bottom is now fixed at more than 7 s TWT. The giant crustal wedge flexuring the Iblean foreland and the Moho geometries are examinated

Multifrequency Studies of the Peculiar Quasar 4C +21.35 During the 2010 Flaring Activity

The discovery of Very High Energy (VHE; E > 100 GeV) γ-ray emission from 4C +21.35 (PKS 1222+216) by MAGIC on 2010 June 17, triggered by the high activity detected by the Fermi Large Area Telescope (LAT) in high energy (HE) γ-rays, poses intriguing questions on the location of the γ-ray emitting region in this flat spectrum radio quasar (FSRQ). We present multifrequency data of 4C +21.35 collected from radio to VHE during 2010 for investigating the properties of this source and discussing a possible emission model. The first hint of detection at VHE was observed by MAGIC on 2010 May 3, soon after a γ-ray flaring activity detected by Fermi-LAT and peaking on April 29. The same emission mechanism may therefore be responsible for both the HE and VHE emission during the 2010 flaring episodes. Two optical peaks were detected on 2010 April 20 and June 30, close in time but not simultaneous with the two γ-ray peaks, while no clear correlation was observed between the X-ray and γ-ray emission. An increasing flux density was observed in radio and mm bands from the beginning of 2009, in accordance with the increasing γ-ray activity observed by Fermi-LAT, and peaking on 2011 January 27 at 230 GHz. We model the spectral energy distributions (SEDs) of 4C +21.35 for the two periods of the VHE detection and a quiescent state with a one-zone model considering the emission from a very compact region outside the broad line region. The three SEDs could be fit with a combination of synchrotron self-Compton and external Compton emission of seed photons from a dust torus, changing only the electron distribution parameters among the SEDs. The fit of the optical/UV part of the spectrum for 2010 April 29 seems to favor an inner disk radius of 3 gravitational radii, a value expected for a maximally prograde rotating Kerr black hole

Multifrequency studies of the peculiar quasar 4C+21.35 during the 2010 flaring activity

The discovery of rapidly variable Very High Energy ( VHE; E &gt; 100 GeV). - ray emission from 4C + 21.35 ( PKS 1222+ 216) by MAGIC on 2010 June 17, triggered by the high activity detected by the Fermi Large Area Telescope ( LAT) in high energy ( HE; E &gt; 100 MeV). - rays, poses intriguing questions on the location of the. - ray emitting region in this flat spectrum radio quasar. We present multifrequency data of 4C + 21.35 collected from centimeter to VHE during 2010 to investigate the properties of this source and discuss a possible emission model. The first hint of detection at VHE was observed by MAGIC on 2010 May 3, soon after a gamma- ray flare detected by Fermi-LAT that peaked on April 29. The same emission mechanism may therefore be responsible for both the HE and VHE emission during the 2010 flaring episodes. Two optical peaks were detected on 2010 April 20 and June 30, close in time but not simultaneous with the two gamma- ray peaks, while no clear connection was observed between the X-ray and gamma- ray emission. An increasing flux density was observed in radio and mm bands from the beginning of 2009, in accordance with the increasing gamma- ray activity observed by Fermi-LAT, and peaking on 2011 January 27 in the mm regime ( 230 GHz). We model the spectral energy distributions ( SEDs) of 4C + 21.35 for the two periods of the VHE detection and a quiescent state, using a one-zone model with the emission coming from a very compact region outside the broad line region. The three SEDs can be fit with a combination of synchrotron self-Compton and external Compton emission of seed photons from a dust torus, changing only the electron distribution parameters between the epochs. The fit of the optical/UV part of the spectrum for 2010 April 29 seems to favor an inner disk radius of &lt; six gravitational radii, as one would expect from a prograde-rotating Kerr black hole.</p