Evolution of Magnetism in Single-Crystal Honeycomb Iridates

We report the successful synthesis of single-crystals of the layered iridate, (Na$_{1-x}$Li$_{x}$)$_2$IrO$_3$, $0\leq x \leq 0.9$, and a thorough study of its structural, magnetic, thermal and transport properties. The new compound allows a controlled interpolation between Na$_2$IrO$_3$ and Li$_2$IrO$_3$, while maintaing the novel quantum magnetism of the honeycomb Ir$^{4+}$ planes. The measured phase diagram demonstrates a dramatic suppression of the N\'eel temperature, $T_N$, at intermediate $x$ suggesting that the magnetic order in Na$_2$IrO$_3$ and Li$_2$IrO$_3$ are distinct, and that at $x\approx 0.7$, the compound is close to a magnetically disordered phase that has been sought after in Na$_2$IrO$_3$ and Li$_2$IrO$_3$. By analyzing our magnetic data with a simple theoretical model we also show that the trigonal splitting, on the Ir$^{4+}$ ions changes sign from Na$_2$IrO$_3$ and Li$_2$IrO$_3$, and the honeycomb iridates are in the strong spin-orbit coupling regime, controlled by \jeff=1/2 moments.Comment: updated version with more dat

Coexisting charge and magnetic orders in the dimer-chain iridate Ba5AlIr2O11

We have synthesized and studied single-crystal Ba5AlIr2O11 that features dimer chains of two inequivalent octahedra occupied by tetravalent and pentavalent ions, respectively. Ba5AlIr2O11 is a Mott insulator that undergoes a subtle structural phase transition near 210 K and a magnetic transition at 4.5 K; the latter transition is surprisingly resistant to applied magnetic fields up to 12 T, but sensitive to modest applied pressure. All results indicate that the phase transition at 210 K signals an enhanced charge order that induces electrical dipoles and strong dielectric response near 210 K. It is clear that the strong covalency and spin-orbit interaction (SOI) suppress double exchange in Ir dimers and stabilize a novel magnetic state. The behavior of Ba5AlIr2O11 therefore provides unique insights into the physics of SOI along with strong covalency in competition with double exchange interactions of comparable strength.Comment: 6 figures, 20 pages. arXiv admin note: text overlap with arXiv:1505.0087

Resilience of critical structures, infrastructure, and communities

In recent years, the concept of resilience has been introduced to the field of engineering as it relates to disaster mitigation and management. However, the built environment is only one element that supports community functionality. Maintaining community functionality during and after a disaster, defined as resilience, is influenced by multiple components. This report summarizes the research activities of the first two years of an ongoing collaboration between the Politecnico di Torino and the University of California, Berkeley, in the field of disaster resilience. Chapter 1 focuses on the economic dimension of disaster resilience with an application to the San Francisco Bay Area; Chapter 2 analyzes the option of using base-isolation systems to improve the resilience of hospitals and school buildings; Chapter 3 investigates the possibility to adopt discrete event simulation models and a meta-model to measure the resilience of the emergency department of a hospital; Chapter 4 applies the meta-model developed in Chapter 3 to the hospital network in the San Francisco Bay Area, showing the potential of the model for design purposes Chapter 5 uses a questionnaire combined with factorial analysis to evaluate the resilience of a hospital; Chapter 6 applies the concept of agent-based models to analyze the performance of socio-technical networks during an emergency. Two applications are shown: a museum and a train station; Chapter 7 defines restoration fragility functions as tools to measure uncertainties in the restoration process; and Chapter 8 focuses on modeling infrastructure interdependencies using temporal networks at different spatial scales

Effect of Consecutive Cut and Vegetation Stage on Cncps Protein Fractions in Alfalfa (Medicago Sativa L.)

Crude protein (CP) of forages can be separated into fractions of differentiated abilities to provide available amino acids in the lower gut of ruminants. This knowledge is critical to develop feeding systems and to predict animal responses. The objective of this research was to asses whether CP concentrations and the relative proportion of CP fractions by CNCPS in alfalfa (Medicago sativa L.) cv K-28 were affected by different cuts and vegetation stages. Fraction B2, which represents true protein of intermediate ruminal degradation rate, was the largest single fraction in all cuts except in the third cut. Soluble fraction A was less than 400 g kg-1 CP in all cuts except in the third cut, while the unavailable fraction C ranged from 56 g kg-1 CP in the first cut to 134.8 g kg-1 CP in the fourth cut. The remaining fraction B3 (true protein of very low degradation rate) only represented less than 60 g kg-1 of total CP. Results showed that undegraded dietary protein represented a small proportion of total CP in alfalfa from the first to the fourth cut

Cardiopoietic programming of embryonic stem cells for tumor-free heart repair

Embryonic stem cells have the distinct potential for tissue regeneration, including cardiac repair. Their propensity for multilineage differentiation carries, however, the liability of neoplastic growth, impeding therapeutic application. Here, the tumorigenic threat associated with embryonic stem cell transplantation was suppressed by cardiac-restricted transgenic expression of the reprogramming cytokine TNF-α, enhancing the cardiogenic competence of recipient heart. The in vivo aptitude of TNF-α to promote cardiac differentiation was recapitulated in embryoid bodies in vitro. The procardiogenic action required an intact endoderm and was mediated by secreted cardio-inductive signals. Resolved TNF-α–induced endoderm-derived factors, combined in a cocktail, secured guided differentiation of embryonic stem cells in monolayers produce cardiac progenitors termed cardiopoietic cells. Characterized by a down-regulation of oncogenic markers, up-regulation, and nuclear translocation of cardiac transcription factors, this predetermined population yielded functional cardiomyocyte progeny. Recruited cardiopoietic cells delivered in infarcted hearts generated cardiomyocytes that proliferated into scar tissue, integrating with host myocardium for tumor-free repair. Thus, cardiopoietic programming establishes a strategy to hone stem cell pluripotency, offering a tumor-resistant approach for regeneration

Parental and familial factors influencing physical activity levels in early adolescence: a prospective study

Parental/familial factors are important determinants of the physical activity level (PAL) in children and adolescents, but studies rarely prospectively evaluate their relationships. This study aimed to evaluate the changes in physical activity levels among adolescents from Bosnia and Herzegovina over a two-year period and to determine parental/familial predictors of PAL in early adolescence. A total of 651 participants (50.3% females) were tested at baseline (beginning of high school education; 14 years old on average) and at follow-up (approximately 20 months later). The predictors included sociodemographic characteristics (age, gender) and parental/familial factors (socioeconomic status of the family, maternal and paternal education, conflict with parents, parental absence from home, parental questioning, and parental monitoring). Physical activity levels were evidenced by the Physical Activity Questionnaire for Adolescents (PAQ-A; criterion). Boys were more active than girls, both at baseline (t-test = 3.09, p < 0.001) and at follow-up (t-test = 3.4, p < 0.001). Physical activity level decreased over the observed two-year period (t-test = 16.89, p < 0.001), especially in boys, which is probably a consequence of drop-out from the sport in this period. Logistic regression evidenced parental education as a positive predictor of physical activity level at baseline (OR [95% CI]; 1.38 [1.15–170], 1.35 [1.10–1.65]), and at follow-up (1.35 [1.11–1.69], 1.29 [1.09–1.59], for maternal and paternal education, respectively). Parents with a higher level of education are probably more informed about the importance of physical activity on health status, and thus transfer this information to their children as well. The age from 14 to 16 years is likely a critical period for maintaining physical activity levels in boys, while further studies of a younger age are necessary to evaluate the dynamics of changes in physical activity levels for girls. For maintaining physical activity levels in adolescence, special attention should be paid to children whose parents are less educated, and to inform them of the benefits of an appropriate physical activity level and its necessity for maintaining proper health and growth

Aportes desde la gestión integral del recurso hídrico para la determinación de la capacidad de carga turística en destinos insulares. caso de estudio Islas de Providencia y Santa Catalina

Los procesos turísticos que no son adecuadamente planificados generan presión sobre los sistemas ambientales, generando conflictos, problemas y decisiones difíciles de abordar por su complejidad enmarcada en la relación sociedad-naturaleza. Es evidente que estos procesos además de atentar contra el patrimonio natural, representan una gran amenaza para el patrimonio social y cultural. De acuerdo con la Organización Mundial del Turismo, este sector presenta un crecimiento importante en los últimos años y se prevé, que siga creciendo en los próximos. Es necesario entonces, estudiar de qué manera se pueden gestionar los destinos turísticos para ofrecer servicios de calidad garantizando la sostenibilidad. Los Estudios de Capacidad de Carga Turística representan uno de los instrumentos de mayor importancia para lograr estos propósitos, donde a través de un proceso sistemático se analizan variables que tienen influencia directa sobre el territorio y la prestación de servicios turísticos, con el fin de determinar la cantidad de visitantes que puede recibir y/o atender un destino sin alterar de manera significativa sus dinámicas naturales, sociales y culturales

Lattice-Tuned Magnetism of Ru\u3csup\u3e4+\u3c/sup\u3e(4\u3cem\u3ed\u3c/em\u3e\u3csup\u3e4\u3c/sup\u3e) Ions in Single Crystals of the Layered Honeycomb Ruthenates Li\u3csub\u3e2\u3c/sub\u3eRuO\u3csub\u3e3\u3c/sub\u3e and Na\u3csub\u3e2\u3c/sub\u3eRuO\u3csub\u3e3\u3c/sub\u3e

We synthesize and study single crystals of the layered honeycomb lattice Mott insulators Na2RuO3 and Li2RuO3 with magnetic Ru4+(4d4) ions. The newly found Na2RuO3 features a nearly ideal honeycomb lattice and orders antiferromagnetically at 30 K. Single crystals of Li2RuO3 adopt a honeycomb lattice with either C2/m or more distorted P21/m below 300 K, depending on detailed synthesis conditions. We find that Li2RuO3 in both structures hosts a well-defined magnetic state, in contrast to the singlet ground state found in polycrystalline Li2RuO3. A phase diagram generated based on our results uncovers a new, direct correlation between the magnetic ground state and basal-plane distortions in the honeycomb ruthenates