32 research outputs found
A heat pump at a molecular scale controlled by a mechanical force
We show that a mesoscopic system such as Feynman's ratchet may operate as a
heat pump, and clarify a underlying physical picture. We consider a system of a
particle moving along an asymmetric periodic structure . When put into a
contact with two distinct heat baths of equal temperature, the system transfers
heat between two baths as the particle is dragged. We examine Onsager relation
for the heat flow and the particle flow, and show that the reciprocity
coefficient is a product of the characteristic heat and the diffusion constant
of the particle. The characteristic heat is the heat transfer between the baths
associated with a barrier-overcoming process. Because of the correlation
between the heat flow and the particle flow, the system can work as a heat pump
when the particle is dragged. This pump is particularly effective at molecular
scales where the energy barrier is of the order of the thermal energy.Comment: 7 pages, 5 figures; revise
Hidden heat transfer in equilibrium states implies directed motion in nonequilibrium states
We study a class of heat engines including Feynman's ratchet, which exhibits
a directed motion of a particle in nonequilibrium steady states maintained by
two heat baths. We measure heat transfer from each heat bath separately, and
average them using a careful procedure that reveals the nature of the heat
transfer associated with directed steps of the particle. Remarkably we find
that steps are associated with nonvanishing heat transfer even in equilibrium,
and there is a quantitative relation between this ``hidden heat transfer'' and
the directed motion of the particle. This relation is clearly understood in
terms of the ``principle of heat transfer enhancement'', which is expected to
apply to a large class of highly nonequilibrium systems.Comment: 4 pages, 4 figures; revise
An expression for stationary distribution in nonequilibrium steady state
We study the nonequilibrium steady state realized in a general stochastic
system attached to multiple heat baths and/or driven by an external force.
Starting from the detailed fluctuation theorem we derive concise and suggestive
expressions for the corresponding stationary distribution which are correct up
to the second order in thermodynamic forces. The probability of a microstate
is proportional to where
is the excess entropy change.
Here is the difference between two kinds of conditioned
path ensemble averages of excess heat transfer from the -th heat bath whose
inverse temperature is . Our expression may be verified experimentally
in nonequilibrium states realized, for example, in mesoscopic systems.Comment: 4 pages, 2 figure
Entropy and Nonlinear Nonequilibrium Thermodynamic Relation for Heat Conducting Steady States
Among various possible routes to extend entropy and thermodynamics to
nonequilibrium steady states (NESS), we take the one which is guided by
operational thermodynamics and the Clausius relation. In our previous study, we
derived the extended Clausius relation for NESS, where the heat in the original
relation is replaced by its "renormalized" counterpart called the excess heat,
and the Gibbs-Shannon expression for the entropy by a new symmetrized
Gibbs-Shannon-like expression. Here we concentrate on Markov processes
describing heat conducting systems, and develop a new method for deriving
thermodynamic relations. We first present a new simpler derivation of the
extended Clausius relation, and clarify its close relation with the linear
response theory. We then derive a new improved extended Clausius relation with
a "nonlinear nonequilibrium" contribution which is written as a correlation
between work and heat. We argue that the "nonlinear nonequilibrium"
contribution is unavoidable, and is determined uniquely once we accept the
(very natural) definition of the excess heat. Moreover it turns out that to
operationally determine the difference in the nonequilibrium entropy to the
second order in the temperature difference, one may only use the previous
Clausius relation without a nonlinear term or must use the new relation,
depending on the operation (i.e., the path in the parameter space). This
peculiar "twist" may be a clue to a better understanding of thermodynamics and
statistical mechanics of NESS.Comment: 31 pages, 4 figure