Linear hydrodynamics and viscoelasticity of nematic elastomers

We develop a continuum theory of linear viscoelastic response in oriented monodomain nematic elastomers. The expression for dissipation function is analogous to the Leslie-Ericksen version of anisotropic nematic viscosity; we propose the relations between the anisotropic rubber moduli and new viscous coefficients. A new dimensionless number is introduced, which describes the relative magnitude of viscous and rubber-elastic torques. In an elastic medium with an independently mobile internal degree of freedom, the nematic director with its own relaxation dynamics, the model shows a dramatic decrease in the dynamic modulus in certain deformation geometries. The degree to which the storage modulus does not altogether drop to zero is shown to be both dependent on frequency and to be proportional to the semi-softness, the non-ideality of a nematic network. We consider the most interesting geometry for the implementation of the theory, calculating the dynamic response to an imposed simple shear and making predictions for effective moduli and (exceptionally high) loss factors.Comment: Latex 2e or PDFlatex (4 EPS or JPG figures) - to appear in Euro.Phys.J.

Dynamic Soft Elasticity in Monodomain Nematic Elastomers

We study the linear dynamic mechanical response of monodomain nematic liquid crystalline elastomers under shear in the geometry that allows the director rotation. The aspects of time-temperature superposition are discussed at some length and Master Curves are obtained between the glassy state and the nematic transition temperature Tni. However, the time-temperature superposition did not work through the clearing point Tni, due to change from the ``soft-elasticity'' nematic regime to the ordinary isotropic rubber response. We focus on the low-frequency region of the Master Curves and establish the power-law dependence of the modulus G' ~ omega^a. This law agrees very well with the results of static stress relaxation, where each relaxation curve obeys the analogous power law G' ~ t^{-a} in the corresponding region of long times and temperatures.Comment: Latex, [epj]{svjour} style, 9 pages 11 figures submitted to Euro. Phys. J.

Tube Model for the Elasticity of Entangled Nematic Rubbers

Dense rubbery networks are highly entangled polymer systems, with significant topological restrictions for the mobility of neighbouring chains and crosslinks preventing the reptation constraint release. In a mean field approach, entanglements are treated within the famous reptation approach, since they effectively confine each individual chain in a tube-like geometry. We apply the classical ideas of reptation dynamics to calculate the effective rubber-elastic free energy of anisotropic networks, nematic liquid crystal elastomers, and present the first theory of entanglements for such a material.Comment: amended version (typos corrected, appendix extended

Cellular solid behaviour of liquid crystal colloids. 2. Mechanical properties

This paper presents the results of a rheological study of thermotropic nematic colloids aggregated into cellular structures. Small sterically stabilised PMMA particles dispersed in a liquid crystal matrix densely pack on cell interfaces, but reversibly mix with the matrix when the system is heated above Tni. We obtain a remarkably high elastic modulus, G'~10^5 Pa, which is a nearly linear function of particle concentration. A characteristic yield stress is required to disrupt the continuity of cellular structure and liquify the response. The colloid aggregation in a ``poor nematic'' MBBA has the same cellular morphology as in the ``good nematic'' 5CB, but the elastic strength is at least an order of magnitude lower. These findings are supported by theoretical arguments based on the high surface tension interfaces of a foam-like cellular system, taking into account the local melting of nematic liquid and the depletion locking of packed particles on interfaces.Comment: Latex 2e (EPJ style) EPS figures included (poor quality to comply with space limitations

Some properties of membranes in nematic solvents

The fluctuation spectrum of membranes in nematic solvents is altered by the boundary condition imposed on the bulk nematic director by the curved membrane. We discuss some properties of single and multi-membrane systems in nematic solvents, primarily based on the Berreman-de~Gennes model. We show that: membranes in nematic solvents are more rigid and less rough than in their isotropic counterparts; have a different Helfrich steric stabilization energy, proportional to $d^{-3}$, and hence a different compression modulus in the lamellar state; and can exhibit phase separation via unbinding during a quench into the nematic state. We also discuss the preparation and possible experimental effects of nematic-mediated surfactant membrane system