20 research outputs found

    CHIRAL CYCLIC AMIDINES

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    Cyclic amidines are prepared in 3 steps from an aromatic aldehyde, isobutyraldehyde, and urea. The amidines 1 and 2 are readily resolved using chiral cyclic phosphoric acids

    SATURATION OF THE HYPERPOLARIZABILITY OF OLIGOTHIOPHENES

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    The observation is reported of satn. with chain length of the 2nd hyperpolarizability of a series of long defined conjugated oligothiophenes. This satn. occurs at the same length as that of the band gap and of the polarizability, and is attributed to a satn. of the effective conjugation length. Solvatochromic and thermochromic measurements indicate that conformational effects play a role. [on SciFinder (R)
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