Noise analysis for CCD-based ultraviolet and visible spectrophotometry

Full-text not yet available due to publisher embargo.We present the results of a detailed analysis of the noise behavior of two CCD spectrometers in common use, an AvaSpec-3648 CCD UV spectrometer and an Ocean Optics S2000 Vis spectrometer. Light sources used include a deuterium UV/Vis lamp and UV and visible LEDs. Common noise phenomena include source fluctuation noise, photoresponse nonuniformity, dark current noise, fixed pattern noise, and read noise. These were identified and characterized by varying light source, spectrometer settings, or temperature. A number of noise-limiting techniques are proposed, demonstrating a best-case spectroscopic noise equivalent absorbance of 3.5×10−4  AU for the AvaSpec-3648 and 5.6×10−4  AU for the Ocean Optics S2000 over a 30 s integration period. These techniques can be used on other CCD spectrometers to optimize performance

Formaldehyde sensor using non-dispersive UV spectroscopy at 340nm

Formaldehyde is a volatile organic compound that exists as a gas at room temperature. It is hazardous to human health causing irritation of the eyes, nose and throat, headaches, limited pulmonary function and is a potential human carcinogen. Sources include incomplete combustion, numerous modern building materials and vehicle fumes. Here we describe a simple method for detecting formaldehyde using low resolution non-dispersive UV absorption spectroscopy for the first time. A two channel system has been developed, making use of a strong absorption peak at 339nm and a neighbouring region of negligible absorption at 336nm as a reference. Using a modulated UV LED as a light source and narrowband filters to select the desired spectral bands, a simple detection system was constructed that was specifically targeted at formaldehyde. A minimum detectable absorbance of 4.5 × 10-5 AU was estimated (as ΔI/I0), corresponding to a limit of detection of approximately 6.6 ppm for a 195mm gas cell, with a response time of 20s. However, thermally-induced drift in the LED spectral output caused this to deteriorate over longer time periods to around 30 ppm or 2 × 10-4 A

A measurement strategy for non-dispersive ultra-violet detection of formaldehyde in indoor air: Spectral analysis and interferent gases

We have conducted an extensive review of published spectra in order to identify a region with potential for detection of formaldehyde in indoor air. 85 chemicals and chemical groups common to the indoor environment were identified, 32 of which had absorption spectra in the UV-vis region. Of these, 11 were found to overlap with the formaldehyde UV region. It was found that the region between 320 to 360 nm is relatively free from interference from indoor gases, with NO being the only major interferent. A method is proposed for a low resolution (3 nm) spectroscopic detection method, specifically targeted at formaldehyde absorption features at 327 nm with a reference at 334 nm. 32 ppb of NO was found to have a cross-sensitivity with equivalent magnitude to 100 ppb of formaldehyde. A second reference at 348 nm would reduce this cross-sensitivity.This work was funded by the Engineering and Physics Science Research Council (EPSRC) under grants GR/T18424, EP/P504880 and EP/H02252X. Enquiries for access to the data referred to in this article should be directed to [email protected]

Non-dispersive ultra-violet spectroscopic detection of formaldehyde gas for indoor environments

We describe a simple method for detecting formaldehyde using low resolution non-dispersive UV absorption spectroscopy. A two channel sensor was developed, making use of a strong absorption peak at 339 nm and a neighbouring region of negligible absorption at 336 nm as a reference. Using a modulated UV LED as a light source and narrow laser-line filters to select the desired spectral bands, a simple detection system was constructed specifically targeted at formaldehyde. By paying particular attention to sources of noise, a minimum detectable absorbance of 5×10 -5 AU was demonstrated with a 20 s averaging period (as ΔI/I0). The system was tested with formaldehyde finding a limit of detection of 4.3 ppm for a 195 mm gas cell. As a consequence of the low gas flow rates used in our test system, a time period of over 8 min was used in further tests, which increased the minimum detectable absorbance to 2×10 -4 AU, 17 ppm of formaldehyde. The increase was the result of thermal drift caused by unwanted temperature variation of the UV LED and the filters, resulting in a zero uncertainty estimated at 560 ppm °C -1 and 100ppm °C -1 respectively

A novel interferometric liquid refractometer

We describe a novel form of liquid refractometer in which the optical length of a cavity containing the liquid is monitored interferometrically

Ultrasonic sensing using Yb3+/Er3+-codoped distributed feedback fibre grating lasers

Yb3+/Er3+-codoped distributed feedback (YbEr-DFB) fibre grating lasers have been investigated for the detection of ultrasonic Lamb waves generated in an aluminium plate. Two sensor configurations have been investigated. A path-length-imbalanced readout Mach-Zehnder interferometer was used to measure the laser frequency shift induced by ultrasonic vibration. The resolution to out-of-plane displacement was 3 x 10(-15) m Hz(-1/2) for a continuous ultrasonic wave at a frequency of 470 kHz. Ultrasonic waves were also detected by directly monitoring the laser output power. This simplified configuration is useful for tone burst AE signals generated by a low energy impact

Characterization of the response of fibre Bragg gratings fabricated in stress and geometrically induced high birefringence fibres to temperature and transverse load.

The transverse load and temperature sensitivities of fibre Bragg gratings (FBGs) fabricated in a range of commercially available stress and geometrically induced high birefringent (HiBi) fibres have been experimentally investigated. The wavelength reflected by the FBG in each polarization eigenmode was measured independently and simultaneously using a custom designed interrogation system. The highest transverse load sensitivity, of 0.23 ± 0.02 nm/(N/mm), was obtained with HiBi FBGs fabricated in elliptically clad fibre. This was higher than for any other HiBi fibre, which, coupled with the small diameter of the fibre, makes it a good candidate for an embedded or surface mounted strain sensor. The highest temperature sensitivity of 16.5 ± 0.1 pm °C-1, approximately 27% greater than any other fibre type, was obtained with the HiBi FBG fabricated in Panda fibre. HiBi FBG sensors fabricated in D-clad fibre were the only ones to exhibit identical temperature sensitivities for the slow and fast axes (11.5 ± 0.1 pm

Railway track component condition monitoring using optical fibre Bragg grating sensors

The use of optical fibre Bragg grating (FBG) strain sensors to monitor the condition of safety critical rail components is investigated. Fishplates, switchblades and stretcher bars on the Stagecoach Supertram tramway in Sheffield in the UK have been instrumented with arrays of FBG sensors. The dynamic strain signatures induced by the passage of a tram over the instrumented components have been analysed to identify features indicative of changes in the condition of the components

Soil moisture content measurement using optical fiber long period gratings

The use of an optical fibre long period grating (LPG) as a soil moisture sensor is reported. Characterization of the device in both clay and sandy soils revealed a sensitivity to moisture levels in the range 10-50%, and the results were compared with the output from a Theta probe, the standard soil moisture sensor, which measures the impedance of the soil. © (2017) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only

In-line laser Doppler velocimeter using fibre-optic Bragg grating interferometric filters

An all fibre-based laser Doppler velocimetry system for the measurement of the predominantly on-axis component of velocity is presented. The technique employs Bragg grating-based Fabry-Perot interferometric filters custom-designed to suit the transduction of Doppler optical frequency shifts to intensity. The sensitivity of the in-fibre filters to strain is exploited to provide tuning of the filter relative to the centre wavelength of the laser and of the spectral shape of the filter, which in turn varies the velocity range, sensitivity and resolution. A phase-locking scheme incorporated to stabilize the filter is described together with a laser-wavelength stabilization system that locks to a Doppler-broadened absorption line of iodine vapour. An optical fibre-linked probe head is used to couple the laser beam at 514.5 nm to and from the measurement volume. The velocimeter is characterized by easuring the velocity of a rotating disc over ranges of +/-42 and +/-7 m s(-1) with a resolution of 0.2 m s(-1)