Electrophoretic Properties of Highly Charged Colloids: A Hybrid MD/LB Simulation Study

Using computer simulations, the electrophoretic motion of a positively charged colloid (macroion) in an electrolyte solution is studied in the framework of the primitive model. Hydrodynamic interactions are fully taken into account by applying a hybrid simulation scheme, where the charged ions (i.e. macroion and electrolyte), propagated via molecular dynamics (MD), are coupled to a Lattice Boltzmann (LB) fluid. In a recent experiment it was shown that, for multivalent salt ions, the mobility $\mu$ initially increases with charge density $\sigma$, reaches a maximum and then decreases with further increase of $\sigma$. The aim of the present work is to elucidate the behaviour of $\mu$ at high values of $\sigma$. Even for the case of monovalent microions, we find a decrease of $\mu$ with $\sigma$. A dynamic Stern layer is defined that includes all the counterions that move with the macroion while subject to an external electrical field. The number of counterions in the Stern layer, $q_0$, is a crucial parameter for the behavior of $\mu$ at high values of $\sigma$. In this case, the mobility $\mu$ depends primarily on the ratio $q_0/Q$ (with $Q$ the valency of the macroion). The previous contention that the increase in the distortion of the electric double layer (EDL) with increasing $\sigma$ leads to the lowering of $\mu$ does not hold for high $\sigma$. In fact, we show that the deformation of the EDL decreases with increase of $\sigma$. The role of hydrodynamic interactions is inferred from direct comparisons to Langevin simulations where the coupling to the LB fluid is switched off. Moreover, systems with divalent counterions are considered. In this case, at high values of $\sigma$ the phenomenon of charge inversion is found.Comment: accepted in J. Chem Phys., 10 pages, 9 figure

Reentrant phase transition in charged colloidal suspensions

We report the observation of a novel phase transition in dilute aqueous suspensions of polystyrene particles as a function of ionic impurity concentration C. The suspension phase separates into dense and rare phases only for a restricted range of C which depends on particle concentration n. The dense phase has liquidlike or crystalline order depending on n and C. Free energies of the homogeneous and the phase-separated states are calculated with an effective interparticle potential. The calculated phase diagram is in qualitative agreement with the present experimental results

Confocal laser scanning microscopy: applications in material science and technology

Confocal laser scanning microscope (CLSM) has great advantage over a conventional microscope because it rejects the light that does not come from the focal plane, enabling one to perform optical slicing and construction of three-dimensional (3D) images. Further its high axial resolution, sharp image quality and associated quantitative image analysis provide vital structural information in the mesoscopic range for the full 3D realization of the microstructure. Because of this unique feature, CLSM is now finding wider applications in the study of variety of materials and processes such as phase separation in binary polymer mixtures, fracture toughness in alloys, in determining residual strains in fibre-reinforced metal composites, and in microvisualization of corrosion. This paper reviews some of these recent applications and also discusses our results on colloidal dispersions. CLSM has been used to characterize the amorphous structure in highly-charged colloidal systems which have undergone gas-solid transition. CLSM images show presence of large voids deep inside the disordered suspensions. Frame averaged images reveal that the structural disorder is amorphous. The reasons for voids coexisting with dense amorphous regions and their implications on colloidal interactions are discussed. The article also reviews the use of fluorescence-CLSM in the investigation of novel materials of technological importance such as template-directed colloidal crystals with preferred orientations and multilayered structures with different crystal plane symmetries. Direct measurement of the interfacial curvatures for a bicontinuous polymer blend system as well as real space measurement of structure in phase separating polymer mixtures are now possible using CLSM. This paper reviews some of these results highlighting the unique advantages of confocal microscopy for better understanding of the microstructure and mechanistic aspects of various important phenomena in a large variety of materials

Detecting Higgs Boson Decay to Neutralinos at Hadron Supercolliders

We examine prospects for detecting the neutral Higgs bosons of minimal supersymmetric models (MSSM) when their decays into neutralino pairs are kinematically allowed. The best signature appears to be H_h,H_p\to\tz_2\tz_2\to 4\ell +\eslt. We argue that Standard Model contributions to this signature are negligible, and examine regions of MSSM parameter space where the four lepton mode should be observable at the Large Hadron Collider. The same signal can also come from continuum neutralino pair production. We propose a set of cuts to illustrate that the neutralino decay mode of the Higgs bosons provides a viable signal over a substantial range of model parameters, and show that it may be separable from continuum neutralino production if sufficient integrated luminosity can be accumulated.Comment: 15 pages (REVTEX), 7 figures available by regular mail, FSU-HEP-940204, UH-511-781-9

Trileptons from Chargino-Neutralino Production at the CERN Large Hadron Collider

We study direct production of charginos and neutralinos at the CERN Large Hadron Collider. We simulate all channels of chargino and neutralino production using ISAJET 7.07. The best mode for observing such processes appears to be pp\to\tw_1\tz_2\to 3\ell +\eslt. We evaluate signal expectations and background levels, and suggest cuts to optimize the signal. The trilepton mode should be viable provided m_{\tg}\alt 500-600~GeV; above this mass, the decay modes \tz_2\to\tz_1 Z and \tz_2\to H_{\ell}\tz_1 become dominant, spoiling the signal. In the first case, the leptonic branching fraction for $Z$ decay is small and additional background from $WZ$ is present, while in the second case, the trilepton signal is essentially absent. For smaller values of $m_{\tg}$, the trilepton signal should be visible above background, especially if $|\mu|\simeq m_{\tg}$ and m_{\tell}\ll m_{\tq}, in which case the leptonic decays of \tz_2 are enhanced. Distributions in dilepton mass $m(\ell\bar{\ell})$ can yield direct information on neutralino masses due to the distribution cutoff at m_{\tz_2}-m_{\tz_1}. Other distributions that may lead to an additional constraint amongst the chargino and neutralino masses are also examined.Comment: preprint nos. FSU-HEP-940310 and UH-511-786-94, 13 pages (REVTEX) plus 7 uuencoded figures attache