The role of international trade on environmental efficiency

Cataloged from PDF version of article.The relationship between trade and environmental conditions receives considerable attention whenever countries are in the process of negotiating trade agreements. In this paper using a non-parametric non-stochastic production frontier approach, we first develop an environmental efficiency index for a sample of high income and low and middle income countries and then examine the role of trade on the changes in environmental efficiency. The paper shows that, in addition to the per capita income which exhibits an environmental Kuznets type relationship, trade-related variables such as trade composition, the share of polluting exports and openness of a country are important determinants of environmental efficiency. (C) 2001 Elsevier Science B.V. All rights reserved. JEL classifications: Q32; Q25; F43

Searching for a Kuznets curve in environmental efficiency using kernel estimation

Cataloged from PDF version of article.The paper constructs environmental efficiency indexes for a sample consisting of high- and low-income countries using nonparametric production frontier techniques and then establishes an environmental Kuznets relationship for environmental efficiency by Nadaraya-Watson kernel estimation methodology. (C) 2000 Elsevier Science S.A. All rights reserved. JEL classification: Q25; Q32

Catching-up and innovation in high and low income countries

Cataloged from PDF version of article.The study utilizes a variant of the Malmquist Productivity Index computed by nonparametric linear programming techniques to empirically investigate the catching-up hypothesis for a group of high- and low-income countries. The results show that the countries with low initial per capita income levels catch up at a faster rate while countries with relatively high income depend more on technological progress for their productivity increases

FMR Study of Co/Ti Bilayer Thin Films

. We focused on the interaction between two ferromagnetic cobalt layers through a non-magnetic titanium layer. The magnetic properties of the structure were characterized by ferromagnetic resonance technique (FMR). The data were collected as a function of non-magnetic titanium layer thickness. Co/Ti multilayer (Ti (50 {\AA})/Co(45 {\AA})/Ti(2-40 {\AA})/Co(40 {\AA})/Ti(100 {\AA}))films were grown onto naturally oxidized p-type single crystal Si (100) substrate at UHV condition with magnetron sputtering system at room temperature. The thickness of Ti spacer layer ranges from 2 to 40 {\AA} with 2 {\AA} steps. We did not observe usual optic and acoustic modes; instead we had two broad overlapped peaks for the films ranged from 6 {\AA} to 40 {\AA}. One interesting result was the high anisotropic resonance field values for these films. Exchange coupling between ferromagnetic layers causes shift on resonance field values but these shifts in our samples were much larger than expected. This large anisotropic behavior is not clear at the moment. Our theoretical model was not able to determine a value for the exchange coupling parameter. One reason can be the close thickness values for Co sublayers. The other reason can be the Ti non-magnetic layer. If titanium did not grow layer by layer on cobalt, the cobalt ferromagnetic layers may behave as a single layer. As a result one cannot observe exchange interaction between ferromagnetic layers through non-magnetic spacer.Comment: 6 pages, 5 figure

Electrode Fixation with Bone Cement or Stimloc (R) in Deep Brain Stimulation Surgery: A Comparative Study

AIM: To examine the postoperative outcomes of electrode fixation using bone cement and Stimloc?? in patients with Parkinson???s MATERIAL and METHODS: Between 2016 and 2018, permanent electrode fixation was performed in 30 patients with PD, of which 15 received bone cement and the remaining 15 received Stimloc??. Data regarding preoperative Unified Parkinson???s Disease Rating Scale (UPDRS) III scores, levodopa equivalent daily dose (LEDD) values, surgery duration, and the fixation technique used were recorded. Brain computed tomography was performed for early postoperative evaluation of pneumocephalus and possible hematoma as well as for the determination of migration 1 year postoperatively. UPDRS III scores and LEDD values were re-evaluated 1 year postoperatively; surgery duration, clinical effectiveness, and complication rates were compared between the two fixation techniques. RESULTS: A statistically significant difference in application time was observed between the two techniques (bone cement: 21 min, Stimloc??: 6 min). After 1 year from surgery, 0.92- and 0.88-mm migrations were observed in the bone cement and Stimloc?? groups, respectively. A significant correlation between migration and the pneumocephalus volume was observed in both groups. No differences were observed between the groups regarding infection, migration, pneumocephalus volume, wound erosion, and CONCLUSION: Stimloc?? is preferred over bone cement for electrode fixation in DBS surgeries as it is associated with shorter application duration; this increases patient comfort and tolerance during awake surgery. Clinical efficacy and complication rates associated with both techniques are similar

Environmental efficiency in carbon dioxide emissions in the OECD: A non-parametric approach

The role of the environment is an important issue in the policy-making and hence, the accurate assessment of the environmental conditions is vital. In this paper, an environmental efficiency index is developed for the OECD countries using non-parametric techniques. The approach adopted is based on the assumption that there is just one production process behind the production of both goods and pollution emissions. The index derived in this work measures the extent of the required output sacrifice, due to the transformation of the production process, from one where all outputs are strongly disposable to the one which is characterized by weak disposability of pollutants. Using this index, we first conduct cross-section comparisons on the state of each country's production process in its treatment of pollution emissions. We then trace each country's modification of their production processes overtime. The results indicate that if the disposability for CO2 emissions were strictly restricted as the result of an environmental regulation, the total value of output loss to the OECD countries as a whole would correspond to 3.7, 4.8 and 3.5% of the total OECD GDP for 1980, 1985 and 1990, respectively. © 2000 Academic Press

DFT, ADMET, molecular docking and molecular dynamics studies of pyridoxal

We report in silico studies of pyridoxal, which is of interest both as a precursor for further functionalization due to the presence of the aldehyde functionality, as well as a bioactive compound. So far, the crystal structure of pyridoxal has not been reported and, thus, we have optimized its structure both under water solvation and in gas phase using the DFT calculations. Under water solvation conditions the optimized structure of pyridoxal is 7.62 kcal/mol more favorable in comparison to that in gas phase. The DFT calculations were also applied to verify optical and electronic properties of the optimized structure of pyridoxal in water. The HOMO and LUMO were revealed to subtract a set of descriptors of the so-called global chemical reactivity as well as to probe pyridoxal as a potential corrosion inhibitor for some important metals used in implants. The title compound exhibits the best electron charge transfer from the molecule to the surface of Ni and Co. Some biological properties of pyridoxal were evaluated using the respective on-line tools. Molecular docking was additionally applied to study interaction of pyridoxal with some SARS-CoV-2 proteins as well as one of the monkeypox proteins. It was established that the title compound is active against all the applied proteins with the most efficient interaction with nonstructural protein 15 (endoribonuclease) and Omicron Spike protein of SARS-CoV-2. Pyridoxal was found to be also active against the studied monkeypox protein. Interaction of pyridoxal with nonstructural protein 15 (endoribonuclease) was further studied using molecular dynamics simulation. © 2023 Indian Chemical SocietyThe numerical calculations were partially performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA resources)

Topological crystalline insulator states in Pb(1-x)Sn(x)Se

Topological insulators are a novel class of quantum materials in which time-reversal symmetry, relativistic (spin-orbit) effects and an inverted band structure result in electronic metallic states on the surfaces of bulk crystals. These helical states exhibit a Dirac-like energy dispersion across the bulk bandgap, and they are topologically protected. Recent theoretical proposals have suggested the existence of topological crystalline insulators, a novel class of topological insulators in which crystalline symmetry replaces the role of time-reversal symmetry in topological protection [1,2]. In this study, we show that the narrow-gap semiconductor Pb(1-x)Sn(x)Se is a topological crystalline insulator for x=0.23. Temperature-dependent magnetotransport measurements and angle-resolved photoelectron spectroscopy demonstrate that the material undergoes a temperature-driven topological phase transition from a trivial insulator to a topological crystalline insulator. These experimental findings add a new class to the family of topological insulators. We expect these results to be the beginning of both a considerable body of additional research on topological crystalline insulators as well as detailed studies of topological phase transitions.Comment: v2: published revised manuscript (6 pages, 3 figures) and supplementary information (5 pages, 8 figures

Synchronization of multi-phase oscillators: An Axelrod-inspired model

Inspired by Axelrod's model of culture dissemination, we introduce and analyze a model for a population of coupled oscillators where different levels of synchronization can be assimilated to different degrees of cultural organization. The state of each oscillator is represented by a set of phases, and the interaction --which occurs between homologous phases-- is weighted by a decreasing function of the distance between individual states. Both ordered arrays and random networks are considered. We find that the transition between synchronization and incoherent behaviour is mediated by a clustering regime with rich organizational structure, where some of the phases of a given oscillator can be synchronized to a certain cluster, while its other phases are synchronized to different clusters.Comment: 6 pages, 5 figure