68 research outputs found

    Studies on heterocyclic analogs of azulene.VIII. Reaction of 2-alkoxycyclohepta[b]pyrroles with dimethyl acetylenedicarboxylate

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    2-Alkoxycyclohepta[b] pyrroles reacted with dimethyl acetylenedicarboxylate to give tetramethyl 2-alkoxy-3H-2a-azacyclopenta[ef]heptalene-3,4,5,6-tetracarboxylates in benzene and dialkyl 2-(2-alkoxycyclohepta[b]pyrrol-1-yl)fumarate in alcoholic solvents

    Cycloaddition of thiazolo[3,2-a]benzimidazole and imidazo[2,1-b]benzothiazole with methyl propiolate ; formation of thiazolo[3,2-a][1,5]benzodiazepine and [1,4]diazepino[7,1-b]benzothiazole

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    3-methylthiazolo[3,2-a]benzimidazole and 2-methylimidazo[2,1-b]benzothiazole, respectively, react with methyl propiolate to give 1:2-adducts which are characterized as methyl(Z)-11-(methoxycarbonyl)-3-methyl-10-thiazolo[3,2-a][1,5]benzodiazepinacrylate and methyl (z)-5-(methoxycarbonyl)-2-methyl-4-[1,4]diazepino[7,1-b]benzothiazolacrylate
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