3 research outputs found
Self-similar shear-thickening behavior in CTAB/NaSal surfactant solutions
The effect of salt concentration Cs on the critical shear rate required for
the onset of shear thickening and apparent relaxation time of the
shear-thickened phase, has been investigated systematically for dilute
CTAB/NaSal solutions. Experimental data suggest a self-similar behavior of the
critical shear rate and relaxation time as functions of Cs. Specifically, the
former ~ Cs^(-6) whereas the latter ~ Cs^(6) such that an effective Weissenberg
number for the onset of the shear thickened phase is only weakly dependent on
Cs. A procedure has been developed to collapse the apparent shear viscosity
versus shear rate data obtained for various values of Cs into a single master
curve. The effect of Cs on the elastic modulus and mesh size of the
shear-induced gel phase for different surfactant concentrations is discussed.
Experiments performed using different flow cells (Couette and cone-and-plate)
show that the critical shear rate, relaxation time and the maximum viscosity
attained are geometry-independent. The elastic modulus of the gel phase
inferred indirectly by employing simplified hydrodynamic instability analysis
of a sheared gel-fluid interface is in qualitative agreement with that
predicted for an entangled phase of living polymers. A qualitative mechanism
that combines the effect of Cs on average micelle length and Debye parameter
with shear-induced configurational changes of rod-like micelles is proposed to
rationalize the self-similarity of SIS formation.Comment: 27 pages, 17 figure