Quest for the Co-Pyrolysis Behavior of Rice Husk and Cresol Distillation Residue: Interaction, Gas Evolution and Kinetics

With the tremendous prosperity of industry, more and more hazardous waste is discharged from industrial production processes. Cresol distillation residue is a typical industrial hazardous waste that causes severe pollution without proper treatment. Herein, the co-pyrolysis of rice husk and cresol distillation residue was studied using thermogravimetry–mass spectrometry and kinetic studies. The Coats and Redfern method was employed to calculate the activation energy. The results indicated that the pyrolysis process of cresol distillation residue and RH/CDR (Rice Husk and Cresol Distillation Residue) blends can be divided into four stages and three stages for RH. The introduction of RH not only improved the thermo-stability of cresol distillation residue at a low temperature but also reduced the activation energy of the blends. The activation energy was the lowest when the proportion of rice husk in the blend was 60%. The main gaseous pyrolysis products included CH4, H2O, C2H2, CO2, C3H6 and H2. There existed an unusual combination of synergistic and inhibitive interactions between RH and cresol distillation residue, respectively, within different temperature ranges. The synergistic interaction decreased the reaction’s activation energy, whereas the inhibitive interaction reduced the emission of main gaseous products, such as CH4 and CO2. It was concluded that the addition of RH was conducive to improving the pyrolytic performance of cresol distillation residue and the resource utilization of cresol distillation residue

Control and Profile Setting of Reactive Distillation Column for Benzene Chloride Consecutive Reaction System

The purpose of this paper is to design and analyze the control structures of a consecutive reactive distillation process. On the basis of the optimal economic design, a systematic framework for the design of the decentralized control structure, controller parameter tuning, and setting profiles under uncertainty disturbances is proposed for benzene chloride production in a reactive distillation column. Its effectiveness and robustness are analyzed for disturbance resistance in terms of changes of the production rate and the feed composition. Simulations indicate that better control performance can be obtained by proper control loop pairing, tray location identification, and controller tuning. Furthermore, process performances are compared for the three different profile setting cases in the forms of one-step, multistep, and quadratic function changes of the product rate adjustment. The result shows that the process transient performance, such as overshoot, smoothness, and stability, can be greatly affected by the set-point transition form, indicating that it is necessary to study the relevant production rate set-point adjustment strategy

Comparison of Two Types of Control Structures for Benzene Chlorine Reactive Distillation Systems

The "neat" operation of the two-reactant reactive distillation column has better steady-state economics, while it presents a challenge for design, optimization, and control of the process. Based on the optimal economic design, the dual-composition control structure and dual-temperature control structure are designed respectively for the benzene chlorine consecutive reactive distillation process. The effectiveness and robustness are analyzed comparably for the disturbance resistance in terms of changes of production rate and feed composition. Results show that dual-temperature control with propose selection of tray temperatures and the optimal profile of the set point can provide better transient process performance than the composition control structure. (C) 2014 Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved

Sb(III)-resistance mechanisms of a novel bacterium from non-ferrous metal tailings

International audienceUnderstanding the mechanism(s) of microbial resistance to antimony (Sb) is critical in the bioremediation of Sb polluted environments. Here a novel bacterium (Acinetobacter sp. JH7) isolated from mine tailings decreased the Microtox toxicity of a Sb(III)-containing medium. DNA sequencing and physiological testing were employed for the identification and characterization of strain JH7. Following a batch experiment, Fourier transform infrared spectroscopy (FTIR) and antimony speciation analyses determined the adsorption and oxidation of antimony. Analyses of Sb(III) distribution revealed that extracellular polymeric substances and cell walls inhibited Sb(III) entry into JH7 cells. FTIR studies indicated that key functional groups including –OH, C–N, and C–O likely participated in Sb(III) biosorption. Isothermal and kinetic studies revealed that Sb(III) sorption to viable JH7 cells fitted the Langmuir model (R2 = 0.99) and could be described by pseudo-second order kinetics (R2 = 0.99). Furthermore, the increase of anti-oxidative enzymatic activity of JH7 enhanced the intracellular detoxification of Sb(III), which would indirectly contribute to the Sb(III) resistance ability of strain JH7. Our results indicate that biosorption and ROS oxidation of Sb(III) were likely responsible for the decreased toxicity of Sb. The greater understanding how Acinetobacter sp. JH7 lowers the environmental Sb(III) toxicity could provide a basis for future research and subsequent development of technologies for the remediation of Sb contaminated sites

Assessment of mumps-containing vaccine effectiveness during an outbreak: Importance to introduce the 2-dose schedule for China

Introduction: China has used 3 different mumps-containing vaccines (MuCV) since 1990: monovalent mumps vaccine, measles–mumps (MM) vaccine, and measles–mumps–rubella (MMR) vaccine, and one dose MuCV (using MMR at 18 months) has been included in the EPI since 2007. MuCV effectiveness has been of concern following large-scale mumps outbreaks. In 2015, an outbreak of mumps occurred in a primary school, which allow us assess vaccine effectiveness of different MuCVs. Method: All children in the school were studied as a retrospective cohort. Vaccination histories and case information were obtained from vaccination records and clinic/hospital logs. Parental questionnaires were used to confirm students' illnesses and calculate attack rate (AR). VE was assessed using the formula, VE = (AR in unvaccinated students- AR in the vaccinated students) / (AR in unvaccinated students). VEs of different type of MuCV were compared. Results: In total, 283 students were identified as clinical mumps among the 2370 students, and 1908 students were included for MuCV VE assessment. 213 (including 21 [8.9%] patients) were 2-dose MuCV recipients (AR: 9.9%), 1165 (including 123 [51.9%] patients) were 1-dose recipients (AR: 10.6%), and 530 (including 93 [39.2%] patients) were unvaccinated (AR: 17.5%). VE was 44% for 2 doses and 40% for one dose. For one-MuCV-dose students, estimated mumps VE was 63% for vaccinated within 3 years (between vaccination and this outbreak); 50% for vaccinated within 3 to 5 years; and 34% for vaccinated more than 5 years. Comparing VE by vaccine type and 5-year interval since vaccination, VE for MMR was 60%, which was consistently higher than VE for monovalent mumps vaccine (22%) and MM (2%). Conclusion: This outbreak was associated with low and declining 1-dose MuCV effectiveness. China's immunization program should evaluate the potential of a 2-dose MMR schedule to adequately control mumps

Structure Manipulation of Carbon Aerogels by Managing Solution Concentration of Precursor and Its Application for CO2 Capture

A series of carbon aerogels were synthesized by polycondensation of resorcinol and formaldehyde, and their structure was adjusted by managing solution concentration of precursors. Carbon aerogels were characterized by X-ray diffraction (XRD), Raman, Fourier transform infrared spectroscopy (FTIR), N2 adsorption/desorption and scanning electron microscope (SEM) technologies. It was found that the pore structure and morphology of carbon aerogels can be efficiently manipulated by managing solution concentration. The relative micropore volume of carbon aerogels, defined by Vmicro/Vtol, first increased and then decreased with the increase of solution concentration, leading to the same trend of CO2 adsorption capacity. Specifically, the CA-45 (the solution concentration of precursors is 45 wt%) sample had the highest CO2 adsorption capacity (83.71 cm3/g) and the highest selectivity of CO2/N2 (53) at 1 bar and 0 °C

Analysis of BDS-3 PPP-B2b Positioning and Time Transfer Service

With the completion of the BeiDou global navigation satellite system (BDS-3), the BeiDou Navigation Satellite System Signal In Space Interface Control Document Precise Point Positioning Service Signal PPP-B2b (Version 1.0) was officially announced, and BDS-3 officially broadcast PPP-B2b correction to broadcast ephemeris through geostationary earth orbit (GEO) satellites to provide precise point positioning services for users in the Asia–Pacific region. This study comprehensively analyzes the application of the PPP-B2b product to time transfer and positioning. On a daily basis, the PPP-B2b positioning accuracy after convergence is calculated using the four ionosphere-free (IF) combinations in static and simulated kinematic modes: BDS B1I/B3I, BDS B1C/B2a, BDS B1I/B3I + GPS, and BDS B1C/B2a + GPS. Observations of time laboratories including the National Time Service Center of the Chinese Academy of Sciences (NTSC) and the Telecommunication Laboratories (TL) are employed to conduct zero-baseline common clock difference (CCD) time comparison experiments and long-baseline time comparison experiments using the PPP-B2b product and the GBM product. The results indicate that the PPP-B2b position accuracy in static mode by only BDS is 1.5/2.7/3.9 cm, and by GPS + BDS is within 1.5/2.5/3.5 cm in North, East, and Up directions, respectively. Regarding simulated kinematic PPP-B2b, the average root mean square (RMS) values of the position errors in the North, East, and Up directions for the combination of BDS B1I/B3I + GPS and BDS B1I/B3I are 3.4/5.8/7.6 cm and 3.8/6.6/7.8 cm, respectively. Simultaneously, the average RMS values of position errors using BDS B1C/B2a + GPS and BDS B1C/B2a are 3.6/4.9/8.1 cm and 4/6.1/8.5 cm. In the time comparison study, the results of zero-baseline CCD using the PPP-B2b product and the GBM product are within the fluctuation range of 0.1 ns, respectively. Particularly, the long-baseline time comparison difference between results employing the PPP-B2b product and the GBM product is within the range of ±0.5 ns

Research on the Principle of a New Flexible Screw Conveyor and Its Power Consumption

A new screw conveyor with flexible discrete spiral blades is proposed to solve the problem of particle material gathering between the screw and the tube wall in the traditional screw conveyor. With a theoretical analysis, the power consumption model of the screw conveyor with flexible discrete spiral blades is built. Then, its practicability is verified by simulation and experimental testing. The simulation results show that the increase of the spiral angle will raise the transportation speed of the particles. The diameter of the flexible blades raises with the increase of the power consumption of the screw conveyor. The experimental testing verified the analysis and simulation results

Analysis of BDS-3 PPP-B2b Positioning and Time Transfer Service

With the completion of the BeiDou global navigation satellite system (BDS-3), the BeiDou Navigation Satellite System Signal In Space Interface Control Document Precise Point Positioning Service Signal PPP-B2b (Version 1.0) was officially announced, and BDS-3 officially broadcast PPP-B2b correction to broadcast ephemeris through geostationary earth orbit (GEO) satellites to provide precise point positioning services for users in the Asia–Pacific region. This study comprehensively analyzes the application of the PPP-B2b product to time transfer and positioning. On a daily basis, the PPP-B2b positioning accuracy after convergence is calculated using the four ionosphere-free (IF) combinations in static and simulated kinematic modes: BDS B1I/B3I, BDS B1C/B2a, BDS B1I/B3I + GPS, and BDS B1C/B2a + GPS. Observations of time laboratories including the National Time Service Center of the Chinese Academy of Sciences (NTSC) and the Telecommunication Laboratories (TL) are employed to conduct zero-baseline common clock difference (CCD) time comparison experiments and long-baseline time comparison experiments using the PPP-B2b product and the GBM product. The results indicate that the PPP-B2b position accuracy in static mode by only BDS is 1.5/2.7/3.9 cm, and by GPS + BDS is within 1.5/2.5/3.5 cm in North, East, and Up directions, respectively. Regarding simulated kinematic PPP-B2b, the average root mean square (RMS) values of the position errors in the North, East, and Up directions for the combination of BDS B1I/B3I + GPS and BDS B1I/B3I are 3.4/5.8/7.6 cm and 3.8/6.6/7.8 cm, respectively. Simultaneously, the average RMS values of position errors using BDS B1C/B2a + GPS and BDS B1C/B2a are 3.6/4.9/8.1 cm and 4/6.1/8.5 cm. In the time comparison study, the results of zero-baseline CCD using the PPP-B2b product and the GBM product are within the fluctuation range of 0.1 ns, respectively. Particularly, the long-baseline time comparison difference between results employing the PPP-B2b product and the GBM product is within the range of ±0.5 ns