Polymer Membranes as Innovative Means of Quality Restoring for Wastewater Bearing Heavy Metals

The problem that has aroused the interest of this review refers to the harmful effect of heavy metals on water sources due to industrial development. In this respect, the review is aimed at achieving a literature survey on the outstanding results and advancements in membranes and membrane technologies for the advanced treatment of heavy metal-loaded wastewaters. Particular attention is given to synthetic polymer membranes, for which the proper choice of precursor material can provide cost benefits while ensuring good decontamination activity. Furthermore, it was also found that better removal efficiencies of heavy metals are achieved by combining the membrane properties with the adsorption properties of inorganic powders. The membrane processes of interest from the perspective of industrial applications are also discussed. A noteworthy conclusion is the fact that the main differences between membranes, which refer mainly to the definition and density of the pore structure, are the prime factors that affect the separation process of heavy metals. Literature studies reveal that applying UF/MF approaches prior to RO leads to a better purification performance

Hybrid Cryogels with Superabsorbent Properties as Promising Materials for Penicillin G Retention

This present study describes the investigation of new promising hybrid cryogels able to retain high amounts of antibiotics, specifically penicillin G, using chitosan or chitosan–biocellulose blends along with a naturally occurring clay, i.e., kaolin. In order to evaluate and optimize the stability of cryogels, three types of chitosan were used in this study, as follows: (i) commercial chitosan; (ii) chitosan prepared in the laboratory from commercial chitin; and (iii) chitosan prepared in the laboratory from shrimp shells. Biocellulose and kaolin, previously functionalized with an organosilane, were also investigated in terms of their potential to improve the stability of cryogels during prolonged submergence under water. The organophilization and incorporation of the clay into the polymer matrix were confirmed by different characterization techniques (such as FTIR, TGA, SEM), while their stability in time underwater was investigated by swelling measurements. As final proof of their superabsorbent behavior, the cryogels were tested for antibiotic adsorption in batch experiments, in which case cryogels based on chitosan extracted from shrimp shells seem to exhibit excellent adsorption properties for penicillin G

Retention of Ciprofloxacin and Carbamazepine from Aqueous Solutions Using Chitosan-Based Cryostructured Composites

Water pollution is becoming a great concern at the global level due to highly polluted effluents, which are charged year by year with increasing amounts of organic residues, dyes, pharmaceuticals and heavy metals. For some of these pollutants, the industrial treatment of wastewater is still relevant. Yet, in some cases, such as pharmaceuticals, specific treatment schemes are urgently required. Therefore, the present study describes the synthesis and evaluation of promising cryostructured composite adsorbents based on chitosan containing native minerals and two types of reinforcement materials (functionalized kaolin and synthetic silicate microparticles). The targeted pharmaceuticals refer to the ciprofloxacin (CIP) antibiotic and the carbamazepine (CBZ) drug, for which the current water treatment process seem to be less efficient, making them appear in exceedingly high concentrations, even in tap water. The study reveals first the progress made for improving the mechanical stability and resilience to water disintegration, as a function of pH, of chitosan-based cryostructures. Further on, a retention study shows that both pharmaceuticals are retained with high efficiency (up to 85.94% CIP and 86.38% CBZ) from diluted aqueous solutions