Investigating seawater intrusion in republic of South Africa’s heuningnes, Cape Agulhas using hydrogeochemistry and seawater fraction techniques

The Heuningnes Catchment in the Republic of South Africa was used as a case study in this research to describe the application of saltwater fraction/quantification and hydrogeochemistry methods to evaluate the extent of saline intrusion in the coastal aquifers. The argument of the research is that the presence of seawater incursion may be conclusively determined by combining the examination of the major ions, seawater fraction, stable isotopes of water, bromide, and geochemical modeling. Using stable isotopes of oxygen (18O) and deuterium (2H), major ions chemistry, seawater composition, and geochemical modeling, the genesis of salinity and mixing of different water masses were examined. Twenty-nine (29) samples of groundwater were examined. All samples showed water facies of the Na-Cl type, indicating a seawater-related origin. The significance of mixing in coastal aquifers under natural conditions was shown by the hydrogeochemical characteristics of key ions derived from ionic ratios, which demonstrated substantial adherence to mixing lines among endmembers for freshwater as well as saltwater (seawater)

Groundwater Recharge and Circulation in Dolomitic Aquifer Located in Semi-Arid Region: Evidence from the δ¹⁸O and δ²H Record, South Africa

Dolomitic aquifers are regarded as important groundwater storage sites in South Africa. Since these aquifers occur in a semi-arid climatic setting with low rainfall, often characterized by a torrential downpour and high potential evapotranspiration, the occurrence of active recharge is very limited (18O values of −3.95‰ to 3.32‰ and the δ2H values ranging from −11.0‰ to 27.7‰. On the other hand, the rainfall isotope results for δ18O fall between −16.11‰ and 5.38‰, while the δ2H values fall between −105.7‰ and 35.6‰. The most depleted Malapa springs contain δ18O of −5.64‰ and δ2H of −32.4‰. Based on the results, the mixing of water in the vadose zone could be considered as an indicator of the dominance of a slow-diffusive flow process in the aquifer as a result of poor fracture permeability. However, regional groundwater circulation through faults and dykes besides interconnected karst structures helps in generating highly productive karst springs in the region characterized by low rainfall

An Overview of Aquifer Physiognomies and the δ18O and δ2H Distribution in the South African Groundwaters

A comprehensive assessment of the stable isotope distribution in the groundwater systems of South Africa was conducted in relation to the diversity in the aquifer lithology and corresponding hydraulic characteristics. The stable isotopes of oxygen (18O) and hydrogen (2H) in groundwater show distinct spatial variation owing to the recharge source and possibly mixing effect in the aquifers with the existing water, where aquifers are characterized by diverse hydraulic conductivity and transmissivity values. When the shallow aquifer that receives direct recharge from rainfall shows a similar isotopic signature, it implies less mixing effect, while in the case of deep groundwater interaction between recharging water and the resident water intensifies, which could change the isotope signature. As aquifer depth increases the effect of mixing tends to be minimal. In most cases, the isotopic composition of recharging water shows depletion in the interior areas and western arid zones which is attributed to the depleted isotopic composition of the moisture source. The variations in the stable isotope composition of groundwater in the region are primarily controlled by the isotope composition of the rainfall, which shows variable isotope composition as it was observed from the local meteoric water lines, in addition to the evaporation, recharge and mixing effects

Time Series Analysis of Water Quality Factors Enhancing Harmful Algal Blooms (HABs): A Study Integrating In-Situ and Satellite Data, Vaal Dam, South Africa

The Vaal Dam catchment, which is the source of potable water for Gauteng province, is characterized by diverse human activities, and the dam encounters significant nutrient input from multiple sources within its catchment. As a result, there has been a rise in Harmful Algal Blooms (HABs) within the reservoir of the dam. In this study, we employed time series analysis on nutrient data to explore the relationship between HABs, using chlorophyll-a (Chl−a) as a proxy, and nutrient levels. Additionally, Chl−a data extracted from Landsat-8 satellite images was utilized to visualize the spatial distribution of HABs in the reservoir. Our findings revealed that HAB productivity in the Vaal Dam is influenced by the levels of total phosphorus (TP) and organic nitrogen (KJEL_N), which exhibited a positive correlation with chlorophyll-a (Chl−a) concentration. Long-term analysis of Chl−a in-situ data (1986–2022) collected at a specific point within the reservoir showed an average concentration of 11.25 μg/L. However, on certain stochastic dates, Chl−a concentration spiked to very high values, reaching a maximum of 452.8 μg/L, coinciding with elevated records of TP and KJEL_N concentrations on those dates, indicating their effect on productivity levels. The decadal time series and trend analysis demonstrated an increasing trend in Chl−a productivity over the studied period, rising from 4.75 μg/L in the first decade (1990–2000) to 10.51 μg/L in the second decade (2000–2010), and reaching 16.7 μg/L in the last decade (2010–2020). The rising averages of the decadal values were associated with increasing decadal averages of its driving factors, TP from 0.1043 to 0.1096 to 0.1119 mg/L for the three decades, respectively, and KJEL_N from 0.80 mg/L in the first decade to 1.14 mg/L in the last decade. Satellite data analysis during the last decade revealed that the spatial dynamics of HABs are influenced by the dam’s geometry and the levels of discharge from its two feeding rivers, with higher concentrations observed in meandering areas of the reservoir and within zones of restricted water circulation

In Situ Determination of Radioactivity Levels and Radiological Doses in and around the Gold Mine Tailing Dams, Gauteng Province, South Africa

The mining and processing of naturally occurring radioactive materials (NORMs) could result in elevated levels of natural radionuclides in the environment. The gold mining in the goldfields of the Witwatersrand Basin of South Africa has resulted in numerous tailing dams that have high concentrations of NORM bearing residue. The aim of this study was to evaluate the radioactivity levels in tailing dams, soils and rocks, and the consequential radiological exposure to the public in the gold mining areas of Gauteng Province, South Africa. The activity concentrations of 238U, 232Th, and 40K were assessed using a gamma ray spectrometer (RS-230), and the activity concentrations ranges in the mine tailings were 209.95–2578.68 Bq/kg, 19.49–108.00 Bq/kg, and 31.30–626.00 Bq/kg, respectively. The radionuclides show significant spatial variability in soils, with high activities recorded in soils located in close proximity to tailings although regionally, the soil radioactivity levels mainly depend on the chemistry of the underlying rocks. The estimated annual effective doses were higher than the recommended regulatory limit of 0.25 mSv/y in particular tailing dams and soil impacted by tailings. Therefore, to ensure the protection of people and the environment, further monitoring and regulatory control measures targeting these areas are required

Mapping groundwater recharge in Africa from ground observations and implications for water security

Groundwater forms the basis of water supplies across much of Africa and its development is rising as demand for secure water increases. Recharge rates are a key component for assessing groundwater development potential, but have not been mapped across Africa, other than from global models. Here we quantify long-term average (LTA) distributed groundwater recharge rates across Africa for the period 1970–2019 from 134 ground-based estimates and upscaled statistically. Natural diffuse and local focussed recharge, where this mechanism is widespread, are included but discrete leakage from large rivers, lakes or from irrigation are excluded. We find that measurable LTA recharge is found in most environments with average decadal recharge depths in arid and semi-arid areas of 60 mm (30–140 mm) and 200 mm (90–430 mm) respectively. A linear mixed model shows that at the scale of the African continent only LTA rainfall is related to LTA recharge—the inclusion of other climate and terrestrial factors do not improve the model. Kriging methods indicate spatial dependency to 900 km suggesting that factors other than LTA rainfall are important at local scales. We estimate that average decadal recharge in Africa is 15 000 km3 (4900–45 000 km3), approximately 2% of estimated groundwater storage across the continent, but is characterised by stark variability between high-storage/low-recharge sedimentary aquifers in North Africa, and low-storage/high-recharge weathered crystalline-rock aquifers across much of tropical Africa. African water security is greatly enhanced by this distribution, as many countries with low recharge possess substantial groundwater storage, whereas countries with low storage experience high, regular recharge. The dataset provides a first, ground-based approximation of the renewability of groundwater storage in Africa and can be used to refine and validate global and continental hydrological models while also providing a baseline against future change