A general theorem on the divergence of vortex beams

The propagation and divergence properties of beams carrying orbital angular momentum (OAM) play a crucial role in many applications. Here we present a general study on the divergence of optical beams with OAM. We show that the mean absolute value of the OAM imposes a lower bound on the value of the beam divergence. We discuss our results for two different definitions of the divergence, the so called rms or encircled-energy. The bound on the rms divergence can be expressed as a generalized uncertainty principle, with applications in long-range communication, microscopy and 2D quantum systems.Comment: RevTex, published versio

Mycobacterium tuberculosis Drives Expansion of Low-Density Neutrophils Equipped With Regulatory Activities

In human tuberculosis (TB) neutrophils represent the most commonly infected phagocyte but their role in protection and pathology is highly contradictory. Moreover, a subset of low-density neutrophils (LDNs) has been identified in TB, but their functions remain unclear. Here, we have analyzed total neutrophils and their low-density and normal-density (NDNs) subsets in patients with active TB disease, in terms of frequency, phenotype, functional features, and gene expression signature. Full-blood counts from Healthy Donors (H.D.), Latent TB infected, active TB, and cured TB patients were performed. Frequency, phenotype, burst activity, and suppressor T cell activity of the two different subsets were assessed by flow cytometry while NETosis and phagocytosis were evaluated by confocal microscopy. Expression analysis was performed by using the semi-quantitative RT-PCR array technology. Elevated numbers of total neutrophils and a high neutrophil/lymphocyte ratio distinguished patients with active TB from all the other groups. PBMCs of patients with active TB disease contained elevated percentages of LDNs compared with those of H.D., with an increased expression of CD66b, CD33, CD15, and CD16 compared to NDNs. Transcriptomic analysis of LDNs and NDNs purified from the peripheral blood of TB patients identified 12 genes differentially expressed: CCL5, CCR5, CD4, IL10, LYZ, and STAT4 were upregulated, while CXCL8, IFNAR1, NFKB1A, STAT1, TICAM1, and TNF were downregulated in LDNs, as compared to NDNs. Differently than NDNs, LDNs failed to phagocyte live Mycobacterium tuberculosis (M. tuberculosis) bacilli, to make oxidative burst and NETosis, but caused significant suppression of antigen-specific and polyclonal T cell proliferation which was partially mediated by IL-10. These insights add a little dowel of knowledge in understanding the pathogenesis of human TB

The Nuclear Ten Micron Emission of Spiral Galaxies

We examine the 10\m\ emission of the central regions of 281 spiral galaxies, after having compiled all ground-based, small-aperture ($\sim$5") broad-band photometric observations at \l$\sim$10\m\ (N magnitudes) published in the literature. We evaluate the compactness of the $\sim$10\m\ emission of galaxy nuclei by comparing these small-beam measures with the large-beam IRAS 12\m\ fluxes. In the analysis of different subsets of objects, we apply survival analysis techniques in order to exploit the information contained in ``censored'' data (i.e., upper limits on the fluxes). Seyferts are found to contain the most powerful nuclear sources of mid-infrared emission, which in $\sim$1/3 of cases provide the bulk of the emission of the entire galaxy; thus, mid-infrared emission in the outer disc regions is not uncommon in Seyferts. The 10\m\ emission of Seyferts appears to be unrelated to their X-ray emission. HII region-like nuclei are stronger mid-infrared sources than normal nuclei and LINER nuclei (whose level of emission is not distinguishable from that of normal nuclei). Interacting objects have, on average, greater 10\m\ luminosities than non-interacting ones and exhibit more compact emission. Early-type spirals have stronger and more compact 10\m\ emission than late-type ones. Barred spirals are brighter at $\sim$10\m\ than unbarred systems, essentially because they more frequently contain HII region-like nuclei. The results of our detailed comparison between the behaviour of various categories of objects stress that the 10\m\ emission of spiral nuclei is closely linked to the (predominantly non-thermal synchrotron) radioComment: 20 pages, Latex, SISSA preprint, 8 figures and 4 tables available upon reques

Lignin degradation efficiency of chemical pre-treatments on banana rachis destined to bioethanol production

Valuable biomass conversion processes are highly dependent on the use of effective pretreatments for lignocellulose degradation and enzymes for saccharification. Among the nowadays available treatments, chemical delignification represents a promising alternative to physical-mechanical treatments. Banana is one of the most important fruit crops around the world. After harvesting, it generates large amounts of rachis, a lignocellulosic residue, that could be used for second generation ethanol production, via saccharification and fermentation. In the present study, eight chemical pretreatments for lignin degradation (organosolv based on organic solvents, sodium hypochlorite, hypochlorous acid, hydrogen peroxide, alkaline hydrogen peroxide, and some combinations thereof) have been tested on banana rachis and the effects evaluated in terms of lignin removal, material losses, and chemical composition of pretreated material. Pretreatment based on lignin oxidation have demonstrated to reach the highest delignification yield, also in terms of monosaccharides recovery. In fact, all the delignified samples were then saccharified with enzymes (cellulase and beta-glucosidase) and hydrolysis efficiency was evaluated in terms of final sugars recovery before fermentation. Analysis of Fourier transform infrared spectra (FTIR) has been carried out on treated samples, in order to better understand the structural effects of delignification on lignocellulose. Active chlorine oxidations, hypochlorous acid in particular, were the best effective for lignin removal obtaining in the meanwhile the most promising cellulose-to-glucose conversion

A Thermochromic Liquid Crystals Image Analysis technique to investigate temperature polarization in spacer-filled channels for Membrane Distillation

The analysis of flow fields and temperature distributions is of paramount importance in the development and optimization of new spacer-filled channel geometries for Membrane Distillation modules. The literature reports only few studies on the experimental characterization of such channels and, to the authors’ knowledge, none of them presents local information concerning the temperature distribution on the membrane surface. In the present work, a non-intrusive experimental technique named TLC-IA-TP is presented: it is based on the use of Thermochromic Liquid Crystals (TLCs) and digital Image Analysis (IA) and it is applied here for the first time to the analysis of Temperature Polarization (TP) in spacer-filled channels typically adopted in thermally-driven membrane separation processes. In particular, this technique allows the local distribution of convective heat transfer coefficients to be determined, thus providing (i) useful indications on strengths and weaknesses of some spacer arrangements and (ii) valuable benchmark data for Computational Fluid Dynamics (CFD) studies. For the purpose of the present work, the technique’s fundamentals are presented, along with a comprehensive assessment of the technique’s accuracy. Results of some preliminary measurements on commercial spacers are also reported

Ignition and reaction mechanism of Co-Al and Nb-Al intermetallic compounds prepared by combustion synthesis

The ignition and propagation mechanism of the self-propagating high-temperature synthesis of several cobalt and niobium aluminides was investigated. Two propagation mechanisms were identified depending on the stoichiometry of the starting mixture. Al-rich compositions propagate through a dissolution-precipitation mechanism while Al-poor mixtures require solid state diffusion. The ignition temperatures were measured by means of microthermocouples in quasi-adiabatic conditions through experiments carried out in thermal explosion mode. Ignition temperatures were found to be characteristic of each system and to depend strongly on reactants particle size. Ignition energies for all compositions were evaluated through a mathematical model

Chemical analyses of extremely degraded wood using analytical pyrolysis and inductively coupled plasma atomic emission spectroscopy

Alum-treated archaeological woods from the Oseberg collection, excavated and treated in the early 1900s demonstrate an extreme deterioration, only discovered in the past decade. This research was aimed at understanding the characteristics of the naturally aged material through chemical analyses of both organic and inorganic components, in order to provide information for the preservation/conservation of these precious objects. Analytical pyrolysis-gas chromatography/mass spectrometry with in situ silylation using hexamethyldisilazane (Py(HMDS)-GC/MS) and inductively coupled plasma-atomic emission spectroscopy (ICP-AES) were used to investigate a set of samples of alum-treated archaeological wood and untreated archaeological wood. Sound woods of the same species were also analysed in order to compare the results. Results from Py(HMDS)-GC/MS analyses of alum-treated woods from Oseberg showed an extreme depletion of carbohydrates and a highly deteriorated lignin network. The majority of the lignin had undergone oxidation reactions, illustrated by high relative amounts of acidic pyrolysis products. In particular, p-hydroxy-benzoic acid was detected for the first time as a degradation product of archaeological wood. Results from ICP-AES showed variable concentrations of aluminium and potassium from the alum treatment, as well as iron, copper, zinc and calcium. The extent of oxidation observed by Py(HMDS)-GC/MS appeared to correlate with relative amounts of iron and calcium in the samples, which may suggest that degradation promoted by iron compounds is inhibited in the presence of calcium compounds. The results obtained for a sample of archaeological wood treated with alum salts five years ago showed that chemical deterioration of lignin had already begun, mainly involving depolymerisation reactions, though only a slight increase in oxidation was evident. In addition to increased insight into potential deterioration reactions, occurring in a complex material such as alum-treated archaeological wood, it was possible to relate the degree of chemical degradation of the Oseberg woods to their visual condition (observed with the naked eye). © 2015 Elsevier B.V