Effect of acidic aqueous alcohol solution on template sol-gel synthesis of phosphorescent hexagonal mesoporous silica film nanocomposite

Here novel mesoporous silica film nanocomposite with a hexagonal structure is successfully synthesized by using phosphorescent columnar assembly of a trinuclear gold(I) pyrazolate complex bearing amphiphilic side chains [Au3Pz3], formed via a weak Au^Au1 metallophilic interaction, as a functional template in the sol-gel synthesis. By controlling the molar ratios of alcohol to acid in an acidic aqueous alcohol solution, the sol-gel synthesis of columnar assembled [Au3Pz3] with a silica source can provide highly ordered hexagonal mesoporous silica film composite [Au3Pz3]/silicahex consisting one-dimensional molecular assembly in the nanoscopic channels. The as-fabricated silica film nanocomposite [Au3Pz3]/silicahex with red emission have phosphorescent properties with luminescence emission centered at 693nm (λext=276nm; Stokes shift, Δλ=417nm) and lifetime at 7.8jus (λext=266nm, λem=690nm)

Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex

Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au3Pz3] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylorthosilicate (TBOS) to [Au3Pz3] in an acidic aqueous alcohol solution from 60:1 to 20:1, highly ordered phosphorescent nanocomposites can be fabricated with hexagonal [Au3Pz3]/silicahex and lamellar [Au3Pz3]/silicalam silicates

A digital twin prototype to visualize heterogeneous seismic damage simulation results on web-GIS

Access to a wide range of information tailored to specific purposes, including extensive damage projections and statistics for target areas and the potential for individual building and dwelling damage predicted through simulations, enhances cities’ resilience against large-scale earthquakes. Recognizing the significance of this, we have developed a prototype of a digital twin capable of comprehensively visualizing various simulations on a web-based geographic information system (GIS) platform. This prototype employs three seismic damage simulators: the Integrated Earthquake Simulation for area damage, the wallstat for wooden houses, and the E-Simulator for a reinforced concrete building. A trial of earthquake damage simulations was conducted to assess this prototype’s efficacy, focusing on the damage incurred in Mashiki Town during the 2016 Kumamoto earthquake. The trial successfully verified the capability of the system to visualize and integrate various types of simulation data alongside records obtained from actual earthquake disasters. This paper provides an overview of the digital twin prototype. It reports on the trial’s results, focusing on the visualization and integration achieved through this trial