Deep 15um AKARI observations in the CDFS: estimating dust luminosities for a MIR-selected sample and for Lyman Break Galaxies and the evolution of L(dust)/L(UV) with the redshift

Deep observations of the CDFS have been secured at 15um with AKARI/IRC infrared space telescope (ESA open time). From these observations, we define a sample of MIR-selected galaxies at 15um and we also obtain 15um flux densities for a sample of LBGs at z=1 already observed at 24um with Spitzer/MIPS. Number counts for the MIR-selected sample show a bump around a 15um flux density of 0.2mJy that can be attributed to galaxies at z>0.4 and at z>0.8 for the fainter part of the bump. This bump seems to be shifted as compared to other works and a possible origin can be the Cosmic variance. Thanks to this dataset, we have tested, on the two above samples at z=1, the validity of the conversions from monochromatic luminosities nu.f(nu) at a rest-frame wavelength of 8um by a comparison with total dust luminosities estimated from Spitzer rest-frame 12um data that we use as a reference. We find that the 8um dust luminosities are not all consistent and that some of them are better when compared to L(dust) evaluated from longer wavelength luminosities. We also find that the rest-frame 8um luminosities provide globally good estimates of L(dust). By comparing our data for the two samples to several libraries of SEDs, we find that models can explain the diversity of the observed f(24)/f(15) ratio quite reasonably for the MIR-selected sample and better for the LBG sample which are less dispersed than the MIR selection. However, when we analyse the luminosity dependence of this ratio, we find important discrepancies. Finally, we revisit the evolution of L(dust)/L(UV) ratio with the redshift z by re-calibrating previous L(dust) at z=2 based on our results and added new data points at higher redshifts. The decreasing trend is amplified as compared to the previous estimate.Comment: Paper accepted for publication in PAS

Low-Resolution Spectrum of the Diffuse Galactic Light and 3.3 um PAH emission with AKARI InfraRed Camera

We first obtained the spectrum of the diffuse Galactic light (DGL) at general interstellar space in 1.8-5.3 um wavelength region with the low-resolution prism spectroscopy mode of the AKARI Infra-Red Camera (IRC) NIR channel. The 3.3 um PAH band is detected in the DGL spectrum at Galactic latitude |b| < 15 deg, and its correlations with the Galactic dust and gas are confirmed. The correlation between the 3.3 um PAH band and the thermal emission from the Galactic dust is expressed not by a simple linear correlation but by a relation with extinction. Using this correlation, the spectral shape of DGL at optically thin region (5 deg < |b| < 15 deg) was derived as a template spectrum. Assuming that the spectral shape of this template spectrum is uniform at any position, DGL spectrum can be estimated by scaling this template spectrum using the correlation between the 3.3 um PAH band and the thermal emission from the Galactic dust.Comment: 7 pages, 5 figures, accepted by Publications of the Astronomical Society of Japan (PASJ

First photosensitized enantiodifferentiating isomerization by optically active sensitizer immobilized in zeolite supercages

Enantiodifferentiating photoisomerization of (Z)-cyclooctene sensitized by (R)- or (S)-1-methylheptyl benzoate immobilized in zeolite supercages afforded the respective enantiomer pair, (—)- and (+)-(E)-isomer (1E) in 5% enantiomeric excess, whilst racemic 1E was obtained upon homogeneous-phase photosensitization with the same antipodal sensitizer pair, thus demonstrating for the first time that chirally modified zeolites not only serve as supramolecular photosensitizing media but also enhance the original enantiodifferentiating ability of chiral photosensitizer