11 research outputs found
The Characteristics of Seebeck Coefficient in Silicon Nanowires Manufactured by CMOS Compatible Process
Silicon nanowires are patterned down to 30 nm using complementary metal-oxide-semiconductor (CMOS) compatible process. The electrical conductivities of n-/p-leg nanowires are extracted with the variation of width. Using this structure, Seebeck coefficients are measured. The obtained maximum Seebeck coefficient values are 122 μV/K for p-leg and −94 μV/K for n-leg. The maximum attainable power factor is 0.74 mW/m K2 at room temperature
Pre-silicidation annealing effect on platinum-silicided Schottky barrier MOSFETs Pre-silicidation annealing effect on platinum-silicided Schottky barrier MOSFETs
Abstract We fabricated platinum-silicided p-type Schottky barrier MOSFETs (SB-MOSFETs) with 40 nm gate length on a silicon-on-insulator wafer. In order to improve the device performance, the devices were annealed at a temperature of 900 • C in a nitrogen environment prior to the platinum deposition for source/drain silicide formation. As a result, lowered threshold voltage of 1.2 V, subthreshold swing values of 110 mV and an enhanced on/off current ratio larger than 10 7 were obtained. This improvement is attributed to the reduction of the fixed oxide charge in the gate oxide during the annealing process
Precious-Metal-Free Electrocatalysts for Activation of Hydrogen Evolution with Nonmetallic Electron Donor: Chemical Composition Controllable Phosphorous Doped Vanadium Carbide MXene
The insufficient strategies to improve electronic transport, the poor intrinsic chemical activities, and limited active site densities are all factors inhibiting MXenes from their electrocatalytic applications in terms of hydrogen production. Herein, these limitations are overcome by tunable interfacial chemical doping with a nonmetallic electron donor, i.e., phosphorization through simple heat. treatment with triphenyl phosphine (TPP) as a phosphorous source in 2D vanadium carbide MXene. Through this process, substitution, and/or doping of phosphorous occurs at the basal plane with controllable chemical compositions (3.83-4.84 at%). Density functional theory (DFT) calculations demonstrate that the P-C bonding shows the lowest surface formation energy (Delta G(surf)) of 0.027 eV angstrom(-2) and Gibbs free energy (Delta G(H)) of -0.02 eV, whereas others such as P-oxide and P-V (phosphide) show highly positive Delta G(H). The P3-V2CTx treated at 500 degrees C shows the highest concentration of P-C bonds, and exhibits the lowest onset overpotential of-28 mV, Tafel slope of 74 mV dec(-1), and the smallest overpotential of-163 mV at 10 mA cm(-2) in 0.5 M H2SO4. The first strategy for electrocatalytically accelerating hydrogen evolution activity of V2CTx MXene by simple interfacial doping will open the possibility of manipulating the catalytic performance of various MXenes