Advances in Humidity Standards

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Validation of phosphor thermometry for industrial surface temperature measurements

Surface temperature measurements are required by the aerospace and automotive industries to guarantee high-quality products and optimize production processes. Accurate and reliable measurement of surface temperature is very challenging in an industrial environment. Surface contact probes are widely used but poorly characterized, while non-contact infrared thermometry is severely hampered by the unknown emissivity of the surface and by problems caused by stray radiation from the background. An alternative approach to the above techniques is phosphor thermometry, used here in a hybrid contact/non-contact approach. In this work, the development of a lifetime-based phosphor thermometer, its application to industrial surface temperature measurement and its validation are reported in a metrologically sound manner. The phosphor thermometer was initially calibrated by contact on a reference calibrator system at the Istituto Nazionale di Ricerca Metrologica to provide SI traceability to the measurements at the industrial level; the system was later validated by exploiting a metal phase-change method. The robustness of the approach against a strong radiative background was also investigated. A comprehensive uncertainty analysis was carried out, resulting in an expanded uncertainty (k  =  2) lower than 1.4 °C over the temperature range from the ambient to 450 °C. The phosphor-based thermometer was then tested at industrial manufacturing premises to measure the surface temperature of aluminium alloy billets during the pre-heating phase before forging. The phosphor-based approach was compared with radiation and contact thermometry in both static and dynamic measurement conditions. The experimental results proved that phosphor thermometry, besides being a valid alternative to conventional techniques, may offer better performance in an industrial setting

Development of a low-frost point generator operating at sub-atmospheric pressure

A low frost point generator (INRIM 03) operating at sub-atmospheric pressure has been designed and constructed at the Istituto Nazionale di Ricerca Metrologica (INRiM) as part of a calibration facility for upper-air sounding instruments. This new humidity generator covers the frost point temperature range between -99 °C and -20 °C and works at any controlled pressure between 200 hPa and 1100 hPa, achieving a complete saturation of the carrier gas (nitrogen) in a single passage through a stainless steel isothermal saturator. The generated humid gas contains a water vapour amount fraction between 14bold dot10-9 mol/mol and 5bold dot10-3 mol/mol. In this work the design of the generator is reported together with characterisation and performance evaluation tests. A preliminary validation of the INRIM 03 against one of the INRIM humidity standards in the common region is also included. Basing on experimental test results, an initial uncertainty evaluation of the generated frost-point temperature, Tfp, and water vapour amount fraction, xw, in the limited range down to -75 °C at atmospheric pressure is reported. For the frost-point temperature, the uncertainty budget yields a total expanded uncertainty (k=2) of less than 0.028 °C, while for the mole fraction the budget yields a total expanded uncertainty of less than 10-6 mol/mol

Photonic and Optomechanical Thermometry

Temperature is one of the most relevant physical quantities that affects almost all processes in nature. However, the realization of accurate temperature standards using current temperature references, like the triple point of water, is difficult due to the requirements on material purity and stability of the environment. In addition, in harsh environments, current temperature sensors with electrical readout, like platinum resistors, are difficult to implement, urging the development of optical temperature sensors. In 2018, the European consortium Photoquant, consisting of metrological institutes and academic partners, started investigating new temperature standards for self-calibrated, embedded optomechanical sensor applications, as well as optimised high resolution and high re- liability photonic sensors, to measure temperature at the nano and meso-scales and as a possible replacement for the standard platinum resistant thermometers. This article presents an overview of the results obtained with sensor prototypes that exploit photonic and optomechanical techniques for sensing temperatures over a large temperature range (5 K to 300 K). Different concepts are demon- strated, including ring resonators, ladder-like resonators and suspended membrane optomechanical thermometers, highlighting initial performance and challenges, like self-heating that need to be overcome to realize photonic and optomechanical thermometry applications.This work was carried out under the 17FUN05 PhotOQuanT project, which has received funding from the EMPIR program, co-financed by the Participating States and the European Union’s Horizon 2020 research and innovation progra

Towards improved humidity measurements at high temperatures and transient conditions

Humidity is a key parameter in controlling drying processes and ambient conditions in many industrial manufacturing, storage and test applications. Air humidity is routinely measured at temperatures above 100 °C and at conditions that are often challenging due to temporal and local variations. Calibrations of humidity sensors do not provide appropriate representativeness of measurement conditions because they are limited to temperatures below 100 °C and static conditions. A European metrology research project HIT (“Metrology for Humidity at High Temperatures and Transient conditions”) is developing improved humidity measurement and calibration techniques to temperatures up to 180 °C and non-static conditions. This paper summaries developments of the project: calibration and test facilities for industrial hygrometers, studies on humidity control in specific microbial transient processes and a new measurement approach for water activity measurements

Development of passive controlled atmosphere display cases for the conservation of cultural assets

This work expands the study of the conservation of organic specimens of historical and artistic interest, assessing both biological and physical-chemical conservation requirements, in order to arrive at the tangible solution, set out herein. The results of the experiment carried out on the prototype demonstrated the performance in terms of gas tightness achieved by the system, as well as the ability to maintain stable storage parameters for a very long period of time. During the course of the study, the chemical compounds emitted by the materials used in construction were taken into consideration, and the effect of the climatic variations present in museum exhibition areas, archives or churches on the physical properties was monitored. This study saw the development of two innovative patented technologies (IT-1398645 and IT-1425729) applied to the construction of two cases, designed to conserve and display the mummies of Rosalia Lombardo (1918-1920 AD) in Palermo, Italy and Princess Anna of Bavaria (1319 AD) in Kastl, Germany. (C) 2018 Elsevier Masson SAS. All rights reserved

MEDA HS : Relative humidity sensor for the Mars 2020 Perseverance rover

The Finnish Meteorological Institute (FMI) provides a relative humidity measurement sensor (HS) for NASA’s Mars 2020 rover. The sensor is a part of the Mars Environmental Dynamic Analyzer (MEDA), a suite of environmental sensors provided by Spain’s Centro de Astrobiolog´ıa. The main scientific goal of the humidity sensor is to measure the relative humidity of the Martian atmosphere near the surface and to complement previous Mars mission atmospheric measurements for a better understanding of Martian atmospheric conditions and the hydrological cycle. Relative humidity has been measured from the surface of Mars previously by Phoenix and Curiosity. Compared to the relative humidity sensor on board Curiosity, the MEDA HS is based on a new version of the polymeric capacitive humidity sensor heads developed by Vaisala. Calibration of humidity devices for Mars conditions is challenging and new methods have been developed for MEDA HS. Calibration and test campaigns have been performed at the FMI, at University of Michigan and the German Aerospace Center (DLR) in Berlin to achieve the best possible calibration. The accuracy of HS and uncertainty of the calibration has been also analysed in detail with VTT Technical Research Centre of Finland. Assessment of sensor performance after landing on Mars confirms that the calibration has been successful, and the HS is delivering high quality data for the science community

Towards improved humidity measurements at high temperatures and transient conditions

Humidity is a key parameter in controlling drying processes and ambient conditions in many industrial manufacturing, storage and test applications. Air humidity is routinely measured at temperatures above 100 °C and at conditions that are often challenging due to temporal and local variations. Calibrations of humidity sensors do not provide appropriate representativeness of measurement conditions because they are limited to temperatures below 100 °C and static conditions. A European metrology research project HIT (“Metrology for Humidity at High Temperatures and Transient conditions”) is developing improved humidity measurement and calibration techniques to temperatures up to 180 °C and non-static conditions. This paper summaries developments of the project: calibration and test facilities for industrial hygrometers, studies on humidity control in specific microbial transient processes and a new measurement approach for water activity measurements