852 research outputs found

    Nonequilibrium Steady States and MacLennan-Zubarev Ensembles in a Quantum Junction System

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    Based on a recent progress in nonequilibrium statistical mechanics of infinitely extended quantum systems, a nonequlibrium steady state (NESS) is constructed for a single-level quantum dot interacting with two free reservoirs under less general but more practically useful conditions than the previous works. As an example, a model of an Ahoronov-Bohm ring with a quantum dot is studied in detail. Then, NESS is shown to be regarded as a MacLennan-Zubarev ensemble. A formal relation between response and correlation at NESS is derived as well.Comment: submitted to Progress of Theoretical Physic

    MD simulation for H2 formation on amorphous ice

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    Culture as Context

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    The relationship between context and culture seems to result in certain patterns, forms, and linguistic or non-linguistic features. They are all packaged in a product called “text.” If we closely observe our own linguistic behavior, we can see how much all of these elements affect each other. From a discourse analytic perspective, culture is a necessary aspect to examine in order to infer what is truly occurring in a conversation. Gumperz (1982) suggests that no matter what the context is, “all verbal behavior is governed by social norms specifying participant roles, rights and duties vis-à-vis each other” (p.165). He warns us of the danger of misunderstanding the speaker’s intentions and meanings if we solely rely on our own cultural background to interpret the talk. For instance, Hill, Ide, Ikuta, Kawasaki and Ogino (1986) and Ide (2006) assert that a strict Japanese social code for politeness called “wakimae” (discernment) requires all Japanese speakers to comply with it without choice in their verbal activities. Japanese society emphasizes humility and one way this is realized is the use of the “non-acceptance” strategy in compliment responses

    Quantitative and qualitative saccharide analysis of North Atlantic brown seaweed by gas chromatography/mass spectrometry and infrared spectroscopy

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    Brown seaweeds contain a variety of saccharides which have potential industrial uses. The most abundant polysaccharide in brown seaweed is typically alginate, consisting of mannuronic (M) and guluronic acid (G). The ratio of these residues fundamentally determines the physicochemical properties of alginate. In the present study, gas chromatography/mass spectrometry (GC/MS) was used to give a detailed breakdown of the monosaccharide species in North Atlantic brown seaweeds. The anthrone method was used for determination of crystalline cellulose. The experimental data was used to calibrate multivariate prediction models for estimation of total carbohydrates, crystalline cellulose, total alginate and alginate M/G ratio directly in dried, brown seaweed using three types of infrared spectroscopy, using relative error (RE) as a measure of predictive accuracy. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) performed well for the estimation of total alginate (RE = 0.12, R2 = 0.82), and attenuated total reflectance (ATR) showed good prediction of M/G ratio (RE = 0.14, R2 = 0.86). Both DRIFTS, ATR and near infrared (NIR) were unable to predict crystalline cellulose and only DRIFTS performed better in determining total carbohydrates. Multivariate spectral analysis is a promising method for easy and rapid characterization of alginate and M/G ratio in seaweed

    Cold stress stimulates algae to produce value-added compounds

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    Two cold-tolerant microalgae, Chlorella vulgaris and Scenedesmus sp., were grown at 22 and 5 °C. At the lower temperature, the microalgae showed substantial biochemical and morphological changes. The soluble sugar profile in response to low-temperature cultivation was very different in the two strains. C. vulgaris increased both the sucrose and raffinose family oligosaccharides (RFOs) content at 5 °C while Scenedesmus sp. drastically reduced the sucrose content. Both strains increased the total fatty acid methyl ester (FAME) content when grown at 5 °C. However, the FAME profiles were very different: C. vulgaris mainly increased C18:1 and less so C18:3, while Scenedesmus sp. decreased C18:1 but greatly increased C18:3. The morphology of C. vulgaris changed slightly at the lower temperature, while Scenedesmus sp. showed substantial changes in the size and shape. Low temperature triggered the synthesis of unsaturated fatty acids that are essential for human nutrition
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