30 research outputs found
Filtration and Breakdown of Clay Clusters during Resin Transfer Molding of Nanoclay/Glass/Epoxy Composites
Dispersion of nanoclay clusters during resin transfer molding of nanoclay/glass/epoxy disks is investigated. In addition to a center-gated disk containing only 14% glass fibers, three nanocomposite disks are fabricated with the addition of 2, 5 or 10 wt% Cloisite® 25A nanoclay. The spatial distribution of nanoclay clusters along the radial axis of the nanocomposite disks are characterized at two length scales. Clusters larger than 1.5 μm are characterized by performing image analysis on the SEM micrographs whereas smaller nanoclay clusters are identified by wavelength dispersive spectrometry. Results obtained from image analysis indicate that nanoclay clusters are filtered out by as much as 50% in the flow direction by the glass fiber preforms. In addition, increasing nanoclay content led to higher filtration, suggesting that cluster formation is more prominent at higher nanoclay loadings. Cluster size distribution analyses revealed that the outer edges of the disks, on average, contain finer nanoclay particles. For instance, the outer edge of the nanocomposite with 2% clay contains 22% more small nanoclay clusters compared to center of the disk. Glass transition temperature, Tg, of four specimens obtained from each molded disks is characterized under oscillatory shear. Glass transition temperature of the samples are shown to increase with the nanoclay content, yielding a 40% higher Tg at 10% nanoclay loading compared to glass/epoxy composite without clay. Increasing glass transition temperature with increasing nanoclay content may be an indication of intercalation of nanoclay within the epoxy matrix.Yeshttps://us.sagepub.com/en-us/nam/manuscript-submission-guideline
Influence of constituents on thermal properties of polymethacrylate derivatives–clay materials
Effect of drawing on the molecular orientation, polymorphism, and properties of melt-spun nanocomposite fibers based on nylon 6 with polyhedral oligomeric silsesquioxane, montmorillonite, and their combination
In this work, binary and ternary nanocomposite systems based on nylon 6 with montmorillonite (MMT), polyhedral oligomeric silsesquioxane (POSS), and their combination were prepared using a melt-compounding process. In the transmission electron microscope (TEM) images, the MMT was found to be generally well dispersed in all materials resulting in its good chemical compatibility with nylon 6, affording intercalated disordered microstructures. On the other hand, the TEM images showed that POSS formed micron-size crystalline agglomerates possibly resulting from a lack in chemical compatibility with nylon 6. These nanocomposite systems were melt-spun into fibers, and the relevant structure-property relationships that occur during the cold drawing process was established by correlating the tensile properties to the changes in crystallinity, polymorphic crystal forms, and molecular orientation. The properties of the resulting fibers were found to be rather skewed and significantly affected by the polymer/nanoparticles interface. The agglomeration of POSS and POSS-MMT particles coupled with the weak nylon 6/POSS interface, reflected on the tensile properties of the nylon 6/POSS and nylon 6/MMT-POSS fibers which underperformed. Some nanocomposite fiber systems offered significant improvements in modulus without excessively compromising the extensibility of the fibers